期刊
EUROPEAN POLYMER JOURNAL
卷 178, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2022.111493
关键词
Reversed micelles; Semifluorinated alternating copolymer; Reversible addition-fragmentation chain transfer (RAFT); macro-RAFT agent; Polymerization-induced self-assembly
资金
- National Natural Science Foundation of China [21971178, 21674071]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
In this study, a mild and facile method for preparing reversed micelles with high solid content was established using a semifluorinated macro-RAFT agent and the PISA strategy. The reversed micelles had a main-chain-type semifluorinated alternating copolymer as the shell and a hydrophilic polymer as the core. This method opens up a new way for designing novel functional synthetic fluorinated nanomaterials.
In this work, based on the semifluorinated macro-RAFT (reversible addition-fragmentation chain transfer) agent and polymerization-induced self-assembly (PISA) strategy, we established a mild and facile method to prepare reversed micelles up to 40 wt% of solid content with main-chain-type semifluorinated alternating copolymer as shell and hydrophilic polymer as core for the first time. The fluorinated macro-RAFT agent was synthesized by combination of step transfer-addition & radical-termination (START) polymerization and post-modification method. The reversed micelles were generated by the PISA of N,N-dimethacrylamide (DMA) in the presence of the fluorinated macro-RAFT agent in the non-polar solvent toluene at 70 ?, and fluorinated reversed micelles can be fixed in the presence of crosslinker ethyleneglycol dimethacrylate (EGDMA). This strategy will facilitate to open a new way in designing novel functional synthetic fluorinated nanomaterials.
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