4.7 Article

Study on the desulfurization performance of calcium-based desulfurizer and NaHCO3 desulfurizer

期刊

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
卷 30, 期 8, 页码 20357-20368

出版社

SPRINGER HEIDELBERG
DOI: 10.1007/s11356-022-22980-3

关键词

Dry desulfurization; NaHCO3 desulfurizer; Calcium desulfurizer; Desulfurization efficiency; Energy consumption

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The commonly used calcium desulfurizers have low efficiency, while NaHCO3 desulfurizers are expensive and difficult to handle. A new high-performance calcium desulfurizer was found, which has high desulfurization efficiency, wider applicable temperatures, and low preparation cost, showing significant potential for development in flue gas desulfurization.
The commonly used calcium desulfurizers have low desulfurization efficiency. NaHCO3 desulfurizers can meet the requirements of desulfurization efficiency, but the high price and the difficulty in handling desulfurization products make dry flue desulfurization technology quite difficult to realize the large-scale application. Preliminary research found a new calcium desulfurizer, to understand its performance, comparing investigation into the desulfurization performance of different calcium desulfurizer and NaHCO3 desulfurizer. The results showed that with the high-performance calcium desulfurizer, conventional NaHCO3 desulfurizer, and ultrafine NaHCO3 desulfurizer, the operating time with 100% desulfurization efficiency is 25,200, 21,600, and 6000 s, when the flue temperature of 373.15-573.15 K, the break-through temperature is 533.15, 473.15, and 373.15 K, expand the use range of desulfurizer flue gas temperature. Regarding the desulfurizer per unit mass, the production costs of ultrafine NaHCO3 desulfurizer are 5.36 times higher than calcium desulfurizer. Compared with NaHCO3 desulfurizer, high-performance calcium desulfurizer is characterized by several advantages, including high desulfurization efficiency, wider applicable temperatures, and low preparation cost, allowing for significant development potential in flue gas desulfurization.

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