期刊
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
卷 30, 期 28, 页码 71957-71969出版社
SPRINGER HEIDELBERG
DOI: 10.1007/s11356-022-22746-x
关键词
Nanocomposite; NiO; Cr2O3; Nanosize cracks; Microsize cracks; Photocatalytic; Degradation
In this study, nanocomposite NiO/Cr2O3 was synthesized using a simple chemical reduction method and characterized using various advanced analytical techniques. The synthesized NiO/Cr2O3 nanocomposite exhibited significant photocatalytic activity under sunlight irradiation for the degradation of organic dyes. The photocatalytic efficiency of the nanocomposite was found to be high, and it also showed reusability and stability. This synthesized nanocomposite has potential applications in environmental remediation.
In this paper, nanocomposite NiO/Cr2O3 has been synthesized by a simple chemical reduction method to study its photocatalytic activity under sunlight irradiation. Various advanced analytical techniques including powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive spectroscopy (EDS), elemental mapping, Fourier transform infrared spectroscopy (FTIR), and UV-visible spectroscopy have been utilized to characterize the synthesized NiO/Cr2O3 nanocomposite. SEM images show the sheet-shaped morphology of NiO/Cr2O3 nanocomposite. These sheets have a rough surface with nano to micro size cracks. These cracks play important role in the enhancement of photocatalytic activity by increasing surface active sites for the adsorption of dye molecules on the surface of the photocatalyst. The organic dyes crystal violet (CV) and methylene blue (MB) have been chosen to study the photocatalytic behavior of NiO/Cr2O3 nanocomposite under sunlight irradiation. The photocatalytic efficiency of NiO/Cr2O3 nanocomposite has been obtained 88.47% and 93.63% against crystal violet and methylene blue respectively. The results of the photocatalytic kinetics exhibit that degradation rate constant value for crystal violet dye is higher as compared to methylene blue dye. Obtained kinetic results indicate that synthesized nanocomposite acts as an efficient photocatalyst for the degradation of both crystal violet dye and methylene blue dye. NiO/Cr2O3 nanocomposite also exhibited reusability and stability for photocatalytic degradation of both organic dyes. Photoelectrochemical measurements as photocurrent, electrochemical impedance spectroscopy (EIS), and Mott-Schottky plot were also performed for synthesized NiO/Cr2O3 nanocomposite. Consequently, this synthesized NiO/Cr2O3 nanocomposite can be utilized for environmental remediation of harmful dyes.
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