The excellent photocatalytic NO removal performance relates to the synergistic effect between the prepositive NaOH solution and the g-C3N4 photocatalysis

Photocatalysis technology is used to remove the low concentration NO in recent years. However, the effect of this process is not very satisfactory. In this study, it was found that the prepositive NaOH solution could significantly improve the photocatalytic NO removal activity of g-C3N4. The apparent quantum yield of g-C3N4 in the NO removal process was increased 3.5 times by the prepositive NaOH solution. The reason is that there was a synergistic effect formed between the prepositive NaOH solution and the photocatalytic NO removal process. The prepositive NaOH solution not only could increase the humidity and pH value in the photocatalytic unit, but also could improve the adsorption ability of g-C3N4 for the H2O, NO, and O-2. Moreover, the prepositive NaOH solution reduced the difficulty of the photogenerated carriers' transport and the center dot OH generation. This study provided a new idea for the removal of low-concentration NOx.

Automated summary

It was found that the prepositive NaOH solution can significantly improve the photocatalytic NO removal activity of g-C3N4, by increasing humidity and pH value, enhancing adsorption ability, reducing difficulty, and forming synergistic effect.