Characterizing spatiotemporal variations of polycyclic aromatic hydrocarbons in Taihu Lake, China

In this study, we analyzed the concentration distributions of 20 polycyclic aromatic hydrocarbons (PAHs) in 41 water samples which were collected from the northern part of Taihu Lake during 4 field campaigns (201511, 201606, 201702 and 201709). The concentrations were determined with GC-MS, and their spatial and seasonal distribution characteristics were interpreted. The results show that 2-ring PAHs present considerably higher concentrations in warm seasons than cold seasons, but the concentrations of the other higher-ring PAHs are rather stable in warm and cold seasons. The distribution patterns of these PAHs might be mainly attributed to ambient temperature effects on the PAH solubility in the water body. Meanwhile, the spatial distributions of the PAH concentrations in cold seasons were rather various in the sampling area, while the distributions in the warm seasons were homogeneous. The different distributions could result from the water recharge from the Yangtze River during cold seasons, which diluted PAH concentrations in the northeastern part of the lake. Furthermore, via literature review on PAH concentrations in water body, PAHs are in a wide range of levels and their patterns are different among the studies, which should be more effected by local factors instead of general PAH properties. The results from this study also present special characteristics of PAHs in Taihu Lake, which exhibit more insight on PAHs existence in water bodies.

Automated summary

This study analyzed the concentration distribution of 20 polycyclic aromatic hydrocarbons (PAHs) in water samples collected from Taihu Lake. The results showed seasonal and spatial variations in the concentrations, with higher concentrations of 2-ring PAHs in warm seasons and stable concentrations of higher-ring PAHs across seasons. The distribution patterns were mainly influenced by ambient temperature and water recharge from the Yangtze River during cold seasons. Additionally, the literature review revealed that PAH concentrations in water bodies vary widely, suggesting the importance of local factors.