4.6 Article

Ideal-dilute-incompressible solutions

期刊

ELECTROCHIMICA ACTA
卷 426, 期 -, 页码 -

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2022.140781

关键词

Dilute solutions; Electrolyte solutions; Ideal solutions; Incompressibility; Steric effects

资金

  1. National Sci- ence Foundation [OISE-1545857]

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Solutions are important components of natural and technological systems. We argue that in addition to the classical hypotheses of ideality and diluteness, solutions must also be incompressible and have small volumetric fractions of solutes. We propose the name "ideal-dilute-incompressible solutions" for this new cornerstone of solution theory.
Solutions are crucial components of natural and technological systems. Two of the classical hypotheses in so-lution theory are those of ideality and diluteness, which are used in the literature to assign to the solutes an activity equal to that of perfect gases and derive Fick's law of diffusion. Here, we argue that these hypotheses are not sufficient for these purposes. Two more hypotheses are missing: the solution must be incompressible and the volumetric fractions of solutes must be small. We propose to name this new cornerstone of solution theory ideal -dilute-incompressible solutions.

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