4.2 Article

Electrochemical In Situ/operando Spectroscopy and Microscopy Part 2: Battery Applications

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Multidisciplinary Sciences

Hollow-core optical fibre sensors for operando Raman spectroscopy investigation of Li-ion battery liquid electrolytes

Ermanno Miele et al.

Summary: New analytical tools are urgently needed to identify chemical degradation and failure mechanisms in Li-ion batteries. In this study, an operando Raman spectroscopy method based on hollow-core optical fibres was developed to monitor the chemistry of liquid electrolytes during battery cycling. Analysis of spectroscopy measurements revealed changes in electrolyte additives and solvents ratio with respect to cell voltage, indicating the potential to track lithium-ion solvation dynamics.

NATURE COMMUNICATIONS (2022)

Article Chemistry, Physical

Ion dynamics of the LixMn2O4 cathode in thin-film solid-state batteries revealed by in situ Raman spectroscopy

Naoaki Kuwata et al.

Summary: In this study, in situ Raman spectroscopy was used to investigate the structural changes of LixMn2O4 in thin-film batteries. The results show that the Raman intensity of LixMn2O4 exhibits hysteresis during charging and discharging when observed from the front surface configuration, while only small hysteresis is observed when measured from the back surface.

SOLID STATE IONICS (2022)

Editorial Material Electrochemistry

The 66th special feature Novel Aspects and Approaches to Experimental Methods for Electrochemistry

Hirohisa Yamada et al.

Summary: The Kansai Branch of the Electrochemical Society of Japan has published a collection of papers, serving as a commentary to the 51st Electrochemistry Workshop. This publication is motivated by the wide publicity of domestic seminars through on-demand events triggered by COVID-19. The preface includes the significance of the publication and introduces the lecturers as part of the special future for Novel Aspects and Approaches to Experimental Methods for Electrochemistry.

ELECTROCHEMISTRY (2022)

Review Chemistry, Physical

Multiscale and hierarchical reaction mechanism in a lithium-ion battery

Yuki Orikasa et al.

Summary: The key to improving the performance of lithium-ion batteries lies in understanding the temporal and spatial hierarchical structure of the battery. This review discusses the hierarchical reaction mechanism of lithium-ion batteries, the operando measurement technique for analysis, the reaction at the electrode-electrolyte interface, and the nonequilibrium structural changes caused by the two-phase reaction in the active material. The understanding of the hierarchical reaction mechanism will provide valuable insights for the design of lithium-ion batteries and future battery technologies.

CHEMICAL PHYSICS REVIEWS (2022)

Article Chemistry, Physical

Solid Electrolyte Interphase Instability in Operating Lithium-Ion Batteries Unraveled by Enhanced-Raman Spectroscopy

Antonin Gajan et al.

Summary: The study found that by optimizing operational conditions and designing near-infrared active amplifiers, it is possible to track the dynamic changes in composition of the electrode/electrolyte interface in lithium-sodium ion batteries, uncovering the source of irreversible capacity in tin electrodes.

ACS ENERGY LETTERS (2021)

Article Electrochemistry

Improved Operando Raman Cell Configuration for Commercially-Sourced Electrodes in Alkali-Ion Batteries

Timothy E. Rosser et al.

Summary: Operando Raman spectroscopy is a well-established technique for monitoring chemical changes in alkali-ion cells, but its application to commercial electrodes has been limited by cell design constraints. An improved configuration is introduced for reliable operando Raman spectroscopy on commercial battery electrodes, along with a general methodological framework for validation.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2021)

Article Electrochemistry

Operando Analysis of Interphase Dynamics in Anode-Free Solid-State Batteries with Sulfide Electrolytes

Andrew L. Davis et al.

Summary: This study investigates the application of sulfide solid electrolytes in Li metal solid-state batteries using a suite of operando analytical techniques. It reveals that the electrically insulating nature of the solid electrolyte interphase (SEI) facilitates Li metal nucleation and plating, while an electronically conducting SEI suppresses the onset of Li plating.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2021)

Article Chemistry, Physical

Rate Limitations in Composite Solid-State Battery Electrodes: Revealing Heterogeneity with Operando Microscopy

Andrew L. Davis et al.

Summary: The study found that the rate capability of composite electrodes in solid-state batteries is often limited, with factors including electrostatic potential and solid-state diffusion. Model systems of graphite/Li6PS5Cl composite electrodes can help researchers understand these limiting factors.

ACS ENERGY LETTERS (2021)

Review Green & Sustainable Science & Technology

Operando Characterization Techniques for All-Solid-State Lithium-Ion Batteries

Florian Strauss et al.

Summary: Lithium-ion batteries are widely used due to their high energy and power densities, while solid-state batteries offer potential improvements in energy density and safety. In situ techniques have advanced the understanding of battery performance and are crucial for the study of solid-state batteries.

ADVANCED ENERGY AND SUSTAINABILITY RESEARCH (2021)

Article Chemistry, Physical

In Situ Monitoring of Lithium Metal Anodes and Their Solid Electrolyte Interphases by Transmission Electron Microscopy

Chih-Yao Chen et al.

Summary: This study introduces a methodology for observing the relationship between the morphology of lithium metal anodes and the chemistry of the solid electrolyte interphase. The coexistence of LiF and Li3N in the SEI layer is found to prevent dendrite formation during lithium deposition, allowing for the visualization of individual lithium deposits with different microstructures. These findings have potential implications for future energy storage devices.

SMALL STRUCTURES (2021)

Article Chemistry, Physical

A critical discussion on the analysis of buried interfaces in Li solid-state batteries. Ex situ and in situ/operando studies

Isidoro Lopez et al.

Summary: The study of interfacial electro-chemo-mechanical phenomena in Li solid-state batteries is crucial for developing efficient and stable systems. Accessing buried interfaces and obtaining reliable structural and chemical information is a challenging aspect in the field, with a critical discussion on various methodologies provided in this perspective. Development of strategies to probe buried interfaces has enabled progress in in situ and operando measurements.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Review Chemistry, Multidisciplinary

Status and prospect of in situ and operando characterization of solid-state batteries

Marm B. Dixit et al.

Summary: This paper highlights the importance of solid-state batteries in achieving electrification of the transportation sector, while also discussing challenges such as electro-chemo-mechanical degradation affecting performance metrics. Characterizing and understanding the solid|solid interfaces in solid-state batteries is crucial for designing high energy density, durable solid-state batteries.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Article Materials Science, Multidisciplinary

Operando analysis of graphite intercalation compounds with fluoride-containing polyatomic anions in aqueous solutions

Yuta Ito et al.

Summary: The study investigated the feasibility of using fluoride-containing polyatomic anions in the formation of graphite intercalation compounds (GICs) in aqueous solutions. It was found that anions containing a C2F5 moiety intercalated only in the surface region of graphite, while those containing a CF3 moiety exhibited different behaviors, with SO3CF3- showing greater reversibility and larger stage-number in the formation of GICs compared to N(SO2CF3)(2)(-).

MATERIALS ADVANCES (2021)

Article Electrochemistry

Solvated Lithium Ion Intercalation Behavior of Graphitized Carbon Nanospheres

Shohei Maruyama et al.

ELECTROCHEMISTRY (2020)

Article Chemistry, Physical

Direct Operando Observation of Double Layer Charging and Early Solid Electrolyte Interphase Formation in Li-Ion Battery Electrolytes

Nataliia Mozhzhukhina et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2020)

Article Chemistry, Physical

Mechanistic understanding of Li dendrites growth by in- situ/operando imaging techniques

Tara Foroozan et al.

JOURNAL OF POWER SOURCES (2020)

Article Materials Science, Multidisciplinary

Lithium-ion battery performance enhanced by the combination of Si thin flake anodes and binary ionic liquid systems

Kei Hosoya et al.

MATERIALS ADVANCES (2020)

Article Chemistry, Physical

Reaction uniformity visualized by Raman imaging in the composite electrode layers of all-solid-state lithium batteries

Misae Otoyama et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2020)

Article Chemistry, Physical

Mechanical failure of garnet electrolytes during Li electrodeposition observed by in-operando microscopy

William Manalastas et al.

JOURNAL OF POWER SOURCES (2019)

Article Chemistry, Physical

Quantitative Elucidation of the Non-Equilibrium Phase Transition in LiFePO4 via the Intermediate Phase

Takahiro Yoshinari et al.

CHEMISTRY OF MATERIALS (2019)

Review Chemistry, Physical

Commercialization of Lithium Battery Technologies for Electric Vehicles

Xiaoqiao Zeng et al.

ADVANCED ENERGY MATERIALS (2019)

Article Electrochemistry

Electrochemical intercalation of bis(fluorosulfonyl)amide anions into graphite from aqueous solutions

Yasuyuki Kondo et al.

ELECTROCHEMISTRY COMMUNICATIONS (2019)

Article Chemistry, Physical

Kerr gated Raman spectroscopy of LiPF6 salt and LiPF6-based organic carbonate electrolyte for Li-ion batteries

Laura Cabo-Fernandez et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2019)

Article Electrochemistry

In Situ Raman Spectroscopy on Silicon Nanowire Anodes Integrated in Lithium Ion Batteries

Andreas Krause et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2019)

Article Chemistry, Physical

Elucidation of LixNi0.8Co0.15Al0.05O2 Redox Chemistry by Operando Raman Spectroscopy

Eibar Flores et al.

CHEMISTRY OF MATERIALS (2018)

Article Electrochemistry

Electrochemical Behavior of Graphitized Carbon Nanospheres in a Propylene Carbonate-Based Electrolyte Solution

Shohei Maruyama et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2018)

Article Chemistry, Physical

Lithium-ion intercalation and deintercalation behaviors of graphitized carbon nanospheres

Shohei Maruyama et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

Article Chemistry, Physical

The Chemistry of Electrolyte Reduction on Silicon Electrodes Revealed by in Situ ATR-FTIR Spectroscopy

Feifei Shi et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2017)

Article Chemistry, Physical

Effect of Potential Profile on Battery Capacity Decrease during Continuous Cycling

Koji Kitada et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2017)

Article Electrochemistry

Passivation Layer Formation of Magnesium Metal Negative Electrodes for Rechargeable Magnesium Batteries

Hiroko Kuwata et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2017)

Article Nanoscience & Nanotechnology

Visualization of Si Anode Reactions in Coin-Type Cells via Operando Scanning Electron Microscopy

Chih-Yao Chen et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

Article Chemistry, Multidisciplinary

Acceptor-type hydroxide graphite intercalation compounds electrochemically formed in high ionic strength solutions

Kohei Miyazaki et al.

CHEMICAL COMMUNICATIONS (2017)

Article Chemistry, Physical

Hidden Two-Step Phase Transition and Competing Reaction Pathways in LiFePO4

Yukinori Koyama et al.

CHEMISTRY OF MATERIALS (2017)

Article Electrochemistry

Electrochemical Intercalation of Bis(fluorosulfonyl)amide Anion into Graphite

Tomokazu Fukutsuka et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2016)

Article Chemistry, Physical

In situ Raman investigation of electrolyte solutions in the vicinity of graphite negative electrodes

Hee-Youb Song et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2016)

Article Electrochemistry

In-operando FTIR Spectroscopy for Composite Electrodes of Lithium-ion Batteries

Masaki Matsui et al.

ELECTROCHEMISTRY (2015)

Article Electrochemistry

Development of In Situ Cross-Sectional Raman Imaging of LiCoO2 Cathode for Li-ion Battery

Hitoshi Fukumitsu et al.

ELECTROCHEMISTRY (2015)

Article Chemistry, Physical

Effects of Solute-Solvent Hydrogen Bonding on Nonaqueous Electrolyte Structure

Kjell W. Schroder et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2015)

Article Physics, Multidisciplinary

Electronic structure and lattice dynamics of LixCoO2 single crystals

H. L. Liu et al.

NEW JOURNAL OF PHYSICS (2015)

Article Instruments & Instrumentation

Compton scattering imaging of a working battery using synchrotron high-energy X-rays

Masayoshi Itou et al.

JOURNAL OF SYNCHROTRON RADIATION (2015)

Article Electrochemistry

Raman Microscopy of Lithium-Manganese-Rich Transition Metal Oxide Cathodes

Rose E. Ruther et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2015)

Article Chemistry, Physical

Spectroscopic X-ray Diffraction for Microfocus Inspection of Li-Ion Batteries

Haruno Murayama et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2014)

Article Chemistry, Multidisciplinary

In Situ Observation of Random Solid Solution Zone in LiFePO4 Electrode

Junjie Niu et al.

NANO LETTERS (2014)

Article Chemistry, Physical

Transient Phase Change in Two Phase Reaction between LiFePO4 and FePO4 under Battery Operation

Yuki Orikasa et al.

CHEMISTRY OF MATERIALS (2013)

Article Electrochemistry

Phase Transition Analysis between LiFePO4 and FePO4 by In-Situ Time-Resolved X-ray Absorption and X-ray Diffraction

Yuki Orikasa et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2013)

Article Electrochemistry

Visualization of the State-of-Charge Distribution in a LiCoO2 Cathode by In Situ Raman Imaging

Toshio Nishi et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2013)

Article Electrochemistry

Study of the LiMn1.5Ni0.5O4/Electrolyte Interface at Room Temperature and 60 degrees C

Hugues Duncan et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2011)

Article Electrochemistry

Electrolyte Reactions with the Surface of High Voltage LiNi0.5Mn1.5O4 Cathodes for Lithium-Ion Batteries

Li Yang et al.

ELECTROCHEMICAL AND SOLID STATE LETTERS (2010)

Article Chemistry, Physical

Visualization of Charge Distribution in a Lithium Battery Electrode

Jun Liu et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2010)

Article Electrochemistry

Surface Layer Formation and Stripping Process on LiMn2O4 and LiNi1/2Mn3/2O4 Thin Film Electrodes

Masaki Matsui et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2010)

Article Electrochemistry

Study of the Cathode-Electrolyte Interface of LiMn1.5Ni0.5O4 Synthesized by a Sol-Gel Method for Li-Ion Batteries

Hugues Duncan et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2010)

Article Electrochemistry

An Electrochemical Cell for Operando Study of Lithium Batteries Using Synchrotron Radiation

J. B. Leriche et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2010)

Article Multidisciplinary Sciences

Shell-isolated nanoparticle-enhanced Raman spectroscopy

Jian Feng Li et al.

NATURE (2010)

Article Chemistry, Physical

Measuring the degree of stacking order in graphite by Raman spectroscopy

L. G. Cancado et al.

CARBON (2008)

Article Chemistry, Physical

Dynamic behavior of surface film on LiCoO2 thin film electrode

Masaki Matsui et al.

JOURNAL OF POWER SOURCES (2008)

Article Chemistry, Physical

Investigating the solid electrolyte interphase using binder-free graphite electrodes

S. -H. Kang et al.

JOURNAL OF POWER SOURCES (2008)

Article Multidisciplinary Sciences

Building better batteries

M. Armand et al.

NATURE (2008)

Article Electrochemistry

The cathode-electrolyte interface in the Li-ion battery

K Edström et al.

ELECTROCHIMICA ACTA (2004)

Article Chemistry, Physical

MicroRaman spectroscopy on LiMn2O4:: warnings on laser-induced thermal decomposition

A Paolone et al.

SOLID STATE IONICS (2004)

Article Biochemical Research Methods

In-situ FTIR investigations on the reduction of vinylene electrolyte additives suitable for use in lithium-ion batteries

HJ Santner et al.

ANALYTICAL AND BIOANALYTICAL CHEMISTRY (2004)

Article Chemistry, Analytical

The study of the anodic stability of alkyl carbonate solutions by in situ FTIR spectroscopy, EQCM, NMR and MS

M Moshkovich et al.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2001)

Article Electrochemistry

Spectroelectrochemical studies on highly polarized LiCoO2 electrode in organic solutions

T Itoh et al.

ELECTROCHEMISTRY COMMUNICATIONS (2000)