期刊
ADVANCED FUNCTIONAL MATERIALS
卷 26, 期 7, 页码 1098-1103出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201504312
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资金
- follow-up Program for Professor of Special Appointment in Shanghai (Eastern Scholar)
- National Natural Science Foundation of China [51271105, 51201095]
- Shanghai Municipal Government [13YZ012, 15520720600]
- Innovative Research Team [IRT13078]
Metal-organic frameworks (MOFs) and relative structures with uniform micro/mesoporous structures have shown important applications in various fi elds. This paper reports the synthesis of unprecedented mesoporous NixCo3-xO4 nanorods with tuned composition from the Co/Ni bimetallic MOF precursor. The Co/Ni-MOFs are prepared by a one-step facile microwaveassisted solvothermal method rather than surface metallic cation exchange on the preformed one-metal MOF template, therefore displaying very uniform distribution of two species and high structural integrity. The obtained mesoporous Ni0.3Co2.7O4 nanorod delivers a larger-than-theoretical reversible capacity of 1410 mAh g(-1) after 200 repetitive cycles at a small current of 100 mA g(-1) with an excellent high-rate capability for lithium-ion batteries. Large reversible capacities of 812 and 656 mAh g(-1) can also be retained after 500 cycles at large currents of 2 and 5 A g(-1), respectively. These outstanding electrochemical performances of the ternary metal oxide have been mainly attributed to its interconnected nanoparticle-integrated mesoporous nanorod structure and the synergistic effect of two active metal oxide components.
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