☆ 4.7 Review

A review of recent advances in electrode materials and applications for flow-electrode desalination systems

DESALINATION (2022)

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Article Engineering, Environmental

Zinc-based energy storage with functionalized carbon nanotube/polyaniline nanocomposite cathodes

Xu Li et al.

Summary: This study synthesized functionalized carbon nanotube/polyaniline nanocomposites and applied them as cathode materials for zinc-based energy storage systems, achieving high capacity, good rate performance, and long cycle life. This work is expected to provide new ideas for high-performance and flexible zinc-based energy storage systems.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Chemical

Carbon nanotubes/activated carbon hybrid as a high-performance suspension electrode for the electrochemical desalination of wastewater

Kuan-Yu Chen et al.

Summary: In this study, the performance of flow-electrode capacitive deionization (FCDI) for wastewater desalination was significantly improved by adding carbon nanotubes (CNTs). The addition of CNTs led to a higher salt removal rate and improved charge transfer. Increasing the initial salt concentration also resulted in a higher salt removal rate but decreased charge efficiency. Overall, adding CNTs proved to be an effective way to enhance the performance of FCDI for sustainable wastewater desalination.

DESALINATION (2022)

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Article Chemistry, Physical

Rational design of Prussian blue analogues as conversion anodes for lithium-ion batteries with high capacity and long cycle life

Yun Tang et al.

Summary: In this study, low-cost KxMn[Fe(CN)(6)](y)square(1-y).nH(2)O with diverse H2O content and structure were harvested via controlling the crystallization rate. It was found that weaker Mn-N bond prepared at a faster crystallization rate is more conducive to the fast electrochemical kinetics of the reversible conversion paths, leading to superior Li-storage performances.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

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Article Environmental Sciences

Effective fluoride removal from brackish groundwaters by flow-electrode capacitive deionization (FCDI) under a continuous-flow mode

Huan Jiang et al.

Summary: This study demonstrated the effectiveness of utilizing flow-electrode capacitive deionization (FCDI) for treating fluoride-contaminated brackish groundwater. The study found that short-circuited closed-cycle (SCC) mode was the most advantageous operational mode. Factors such as current density, hydraulic residence time (HRT), activated carbon loading, and feed concentration of coexisting NaCl were found to affect the removal of F- and Cl-. F- was preferentially removed from the treated water compared with Cl-, and the removal efficiencies of both ions decreased with increasing feed concentration of coexisting NaCl.

SCIENCE OF THE TOTAL ENVIRONMENT (2022)

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Article Engineering, Chemical

Effective inspissation of uranium(VI) from radioactive wastewater using flow electrode capacitive deionization

Jian Zhou et al.

Summary: The effectiveness of flow electrode capacitive deionization (FCDI) as a method to concentrate radioactive wastewater has been assessed for the first time in this study. The results showed that uranium (U) can accumulate into the electrolyte and on activated carbon in the flow electrode, with a removal efficiency of over 99% during each cycle. Analysis of XPS revealed the migration route and valence change of U in the flow electrode, explaining its high adsorption capacity in FCDI. Long-term experiments demonstrated that the low concentration feed water could be concentrated by 47 times, achieving a final concentration of 2843 mg L-1 U. Under optimized conditions, FCDI achieved a charge efficiency of 86% and a low energy consumption of 2.03 mg J(-1). Overall, FCDI shows promise as a method for treating radioactive wastewater, with high removal rate, excellent concentration effect, and low energy consumption.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

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Article Engineering, Environmental

Perfect divalent cation selectivity with capacitive deionization

Rana Uwayid et al.

Summary: Capacitive deionization (CDI) is an emerging membraneless water desalination technology that achieves ion separation by electrostatic adsorption on charged electrode plates. Sulfonated activated carbon electrodes enable perfect divalent cation selectivity in CDI, with significant removal of divalent cations and zero removal of monovalent cations. This technology offers high efficiency, low cost, and low energy consumption.

WATER RESEARCH (2022)

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Article Engineering, Environmental

Efficient bicarbonate removal and recovery of ammonium bicarbonate as CO2 utilization using flow-electrode capacitive deionization

Sanghwi Han et al.

Summary: This study proposes an innovative FCDI system for efficient removal of HCO3- and enrichment of NH4HCO3 from synthetic swine wastewater. At optimal operating conditions, the system can achieve high-purity concentrated solution of NH4HCO3 in 30 hours.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Chemical

Enhanced capacitive deionization using a biochar-integrated novel flow-electrode

Jihun Lim et al.

Summary: This study investigates the performance of a capacitive deionization system using a flow-electrode composed of biochar and activated carbon. The results show that the system performance is enhanced by approximately 1.83-fold when using the composite flow-electrode compared to activated carbon alone. The biochar has superior electrical efficiency, leading to reduced solution and charge transfer resistances and improved deionization efficiency. Using the optimal operational conditions, the FCDI process achieves outstanding performance in desalination and removal of heavy-metal lead ions.

DESALINATION (2022)

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Article Engineering, Chemical

Investigation of fine activated carbon as a viable flow electrode in capacitive deionization

Gbenro Folaranmi et al.

Summary: This study used a dry milling method to reduce the particle size of the carbon flow electrode, improving the performance of flow capacitive deionization. Fine activated carbon showed better desalination performance compared to pristine activated carbon, attributed to its smaller particle size, which reduced particle aggregation and facilitated ion migration and contact with carbon pores.

DESALINATION (2022)

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Article Engineering, Chemical

Carbon aerogel electrode for excellent dephosphorization via flow capacitive deionization

Fei Yu et al.

Summary: In this study, a new carbon aerogel (CA) with high specific surface area and conductivity was synthesized via an electric heating furnace drying method. The CA exhibited a faster dephosphorization rate and lower energy consumption in flow-electrode capacitive deionization (FCDI) compared to activated carbon (AC), demonstrating its potential as an electrode material for phosphorus recovery.

DESALINATION (2022)

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Article Environmental Sciences

Metal-organic framework derived carbon nanoarchitectures for highly efficient flow-electrode CDI desalination

Liang Luo et al.

Summary: Flow-electrode capacitive deionization (FCDI) has shown robust desalination performance. In this study, ZIF-8 derived nanocarbon materials were prepared as electrode materials for FCDI desalination, exhibiting excellent desalination rates due to their high conductivity, large specific surface area, and well-developed pores.

ENVIRONMENTAL RESEARCH (2022)

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Review Chemistry, Physical

Dimensionality, Function and Performance of Carbon Materials in Energy Storage Devices

Jing Xiao et al.

Summary: This review emphasizes the importance of dimensionality manipulation in functional carbon materials for optimizing electrochemical energy storage devices. It highlights how dimensionality manipulation can improve performance in kinetics, electron transfer, mechanical stability, and thermal dissipation.

ADVANCED ENERGY MATERIALS (2022)

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Article Engineering, Environmental

Highly efficient removal of Cu-organic chelate complexes by flow-electrode capacitive deionization-self enhanced oxidation (FCDI-SEO): Dissociation, migration and degradation

Haoyu Yin et al.

Summary: In this study, a FCDI-SEO system was used to efficiently remove EDTA-Cu and CA-Cu complexes from wastewaters. The results showed that stable EDTA-Cu migrated as chelated Cu to the anode chamber, while CA-Cu dissociated and migrated as free Cu2+ to the cathode chamber. The short-circuited closed-cycle mode exhibited similar Cu removal efficiency but higher energy efficiency compared to the isolated closed-cycle mode.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Enhanced Desalination Performance by a Novel Archimedes Spiral Flow Channel for Flow-Electrode Capacitive Deionization

Xinyuan Zhang et al.

Summary: This study improves the desalination performance of traditional FCDI devices by enhancing the flow quality and introducing the Archimedes spiral flow channel model. The stable desalination performance and high salt removal efficiency are demonstrated.

ACS ES&T ENGINEERING (2022)

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Review Chemistry, Multidisciplinary

Structure and Properties of Prussian Blue Analogues in Energy Storage and Conversion Applications

Haocong Yi et al.

Summary: This review discusses the structure/property correlations and optimization strategies of Prussian blue analogue (PBA) materials as host frameworks for various charge-carrier ions in energy storage/conversion applications. The prospects for further applications of PBA materials in different types of batteries are summarized, with extra attention given to the selection of anode materials and electrolytes for practical implementation. This work aims to provide a comprehensive understanding of PBA materials and to guide future research and development of PBA electrodes.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Environmental Sciences

Adsorptive removal of Sr2+ and Cs+ from aqueous solution by capacitive deionization

Xiaojing Liu et al.

Summary: The electro-assisted adsorptive removal of Sr2+ and Cs+ ions from aqueous solution by capacitive deionization using activated carbon cloth as electrode was studied. The removal efficiency decreased as the initial concentration of ions increased, but increased with higher applied voltage. The CDI process is beneficial for removing high valence ions with ion-exchange and charge interaction mechanisms.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2021)

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Article Engineering, Chemical

Enhanced salt removal performance of flow electrode capacitive deionization with high cell operational potential

Yuncheol Ha et al.

Summary: Capacitive deionization (CDI) is a promising technology for salt ion removal from saline water. The use of flow electrode enhances salt removal performance, and increasing the operational potential difference can improve desalination efficiency and salt removal rate.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

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Article Nanoscience & Nanotechnology

Enhanced Salt Removal Performance Using Graphene-Modified Sodium Vanadium Fluorophosphate in Flow Electrode Capacitive Deionization

Yiran Sun et al.

Summary: Using NVOPF@rGO as the cathode and activated carbon as the anode, better electrode dispersibility and stability, lower internal resistance, higher desalination rate, and lower energy consumption were achieved in FCDI compared to an activated carbon-activated carbon system. The study adjusted the electrode concentration, electrode flow rate, and operation voltage to achieve an average salt adsorption rate of 5.32 μg·cm(-2)·min(-1).

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Engineering, Environmental

Significantly enhanced desalination performance of flow-electrode capacitive deionization via cathodic iodide redox couple and its great potential in treatment of iodide-containing saline wastewater

Kunyue Luo et al.

Summary: The study introduced KI3 into the cathodic flow-electrode to enhance FCDI desalination performance with stable salt electrosorption and desorption behavior. Despite potential risks of iodide leakage, the system shows great application prospects in treating iodide-containing saline wastewater.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Engineering, Chemical

Enhanced desalination performance in asymmetric flow electrode capacitive deionization with nickel hexacyanoferrate and activated carbon electrodes

Yang Xu et al.

Summary: This study found that asymmetric FCDI has better desalination performance, and the contributions of capacitance and charge neutralization are significantly different for nickel hexacyanoferrate and activated carbon electrodes.

DESALINATION (2021)

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Article Engineering, Chemical

Anion-/cationic compounds enhance the dispersion of flow electrodes to obtain high capacitive deionization performance

Henan Huang et al.

Summary: The use of anion/cationic compounds in activated carbon as a flow electrode can improve conductivity and efficiency, leading to a more effective desalination process.

DESALINATION (2021)

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Article Electrochemistry

RGO wrapped tungsten trioxide hydrate on CNT-modified carbon Cloth as self-supported high-rate lithium-ion battery electrode

Yifan Lin et al.

Summary: In this study, tungsten trioxide hydrate was partially wrapped by reduced graphene oxide sheets to form flower-like structures and loaded on carbon nanotube-modified carbon cloth to create a self-supported electrode with hierarchical structures. The synthesized material offered abundant internal and surface channels for lithium ions and increased conductivity through inter-valence charge transfer. The hierarchical structure promoted charge transfer and shortened diffusion length, while the use of binders was avoided to inhibit side reactions during cycling.

ELECTROCHIMICA ACTA (2021)

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Article Chemistry, Physical

Enhanced Desalination Performance of a Flow-Electrode Capacitive Deionization System by Adding Vanadium Redox Couples and Carbon Nanotubes

Zhoulu Wang et al.

Summary: The paper discusses the use of flow carbon nanotubes and vanadium redox couples in FCDI technology to achieve energy-saving desalination. The study demonstrates the potential for high efficiency, low-energy desalination under certain conditions.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

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Article Engineering, Chemical

Formic acid recovery from EDTA wastewater using coupled ozonation and flow-electrode capacitive deionization (Ozo/FCDI): Performance assessment at high cell voltage

Longqian Xu et al.

Summary: This study proposed a promising approach for formic acid (FA) recovery from EDTA wastewater by coupling ozonation and flow-electrode capacitive deionization (Ozo/FCDI). The results demonstrated the superiority of the FCDI process compared to electrodialysis, with high FA productivity achieved and low energy consumption. These findings suggest new opportunities and challenges for the recovery of organic compounds in the Ozo/FCDI system.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

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Article Green & Sustainable Science & Technology

Effective and continuous removal of Cr(VI) from brackish wastewater by flow-electrode capacitive deionization (FCDI)

Yi Dong et al.

Summary: This study demonstrated the effectiveness of utilizing flow-electrode capacitive deionization (FCDI) for continuous removal of Cr(VI) from brackish wastewaters, highlighting the preferential removal of Cr(VI) compared to Cl- and the varying removal behaviors between Cr(VI) and Cl-. Results also indicated the favorable impact of factors such as current density, HRT, activated carbon loading, and initial pH on the removal of Cr(VI). Additionally, inhibitory effects of different coexisting anions, especially carbonate species, were identified.

JOURNAL OF CLEANER PRODUCTION (2021)

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Review Engineering, Environmental

Recent progress on metal-organic framework-derived porous carbon and its composite for pollutant adsorption from liquid phase

Fei Yu et al.

Summary: In recent years, metal-organic framework materials (MOFs) have been widely used in various applications due to their adjustable composition, diverse structures, and controllable pore size. MOF-derived porous carbon materials inherit these advantages and can be applied to environmental pollutant adsorption. This study reviews the preparation methods and research progress of MOF-derived porous carbon adsorbents for organic and inorganic pollutants adsorption, and discusses the factors affecting their adsorption properties.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Engineering, Environmental

Phosphate selective recovery by magnetic iron oxide impregnated carbon flow-electrode capacitive deionization (FCDI)

Changyong Zhang et al.

Summary: FCDI, utilizing magnetic carbon electrodes, demonstrates efficient P adsorption and selective recovery, paving the way for effective phosphorus recovery technologies.

WATER RESEARCH (2021)

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Article Engineering, Environmental

Scale-up desalination: Membrane-current collector assembly in flow-electrode capacitive deionization system

Longqian Xu et al.

Summary: This study introduces an innovative MCC-FCDI system for salt removal from seawater/wastewater, which allows for scale-up desalination with lower infrastructure investment, device size, and energy cost. The system enables simultaneous operation of multiple modules, showing improved desalination performance and substantial ion adsorption capacity. Overall, MCC-FCDI is a promising desalination system for scale-up applications, providing new reference and guidance for device design.

WATER RESEARCH (2021)

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Article Engineering, Environmental

Development of sulfonated-carbon nanotubes/graphene three-dimensional conductive spongy framework with ion-selective effect as cathode in high-performance lithium-sulfur batteries

Min Li et al.

Summary: The newly designed NG/CNTs-SO3- three-dimensional electrode effectively improves the performance of lithium-sulfur batteries by enhancing cycling stability and rate capability through the formation of a continuous ion-electronic conductive network and accelerating redox reaction kinetics.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Engineering, Chemical

Electrochemical desalination coupled with energy recovery and storage

Umesh Ghimire et al.

Summary: This paper presents a dual-purpose Zinc vertical bar ferricyanide desalination battery for simultaneous desalination and energy storage operations. Experimental results confirm that the battery can achieve high desalination rates and be used for processing high salinity water.

DESALINATION (2021)

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Review Engineering, Chemical

Improving the feasibility and applicability of flow-electrode capacitive deionization (FCDI): Review of process optimization and energy efficiency

Yong-Uk Shin et al.

Summary: Flow-electrode capacitive deionization (FCDI) is a new electrochemical desalination technology that overcomes limitations of traditional CDI processes by using stationary carbon electrodes and ion exchange membranes, with ion electrosorption as the main separation mechanism. The unique feature of continuous ion/salt separation and avoidance of electrode saturation constraints sets FCDI apart. This paper reviews recent advancements in FCDI, discusses feasibility and potential applications for saline water/wastewater treatment, and explores factors influencing performance and energy efficiency.

DESALINATION (2021)

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Review Engineering, Environmental

Flow Electrode Capacitive Deionization (FCDI): Recent Developments, Environmental Applications, and Future Perspectives

Changyong Zhang et al.

Summary: With the increasing severity of global water scarcity, scientific activities are focusing on advancing brackish water desalination and wastewater remediation technologies. Flow-electrode capacitive deionization (FCDI) has emerged as a promising approach, driven by the potential for energy-efficient production of high-quality fresh water. This review provides an overview of current advances in FCDI technology, emphasizing design, operational modes, characterizations, and environmental applications, while also highlighting challenges in full-scale application and future outlook.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2021)

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Article Engineering, Environmental

Phosphate recovery as vivianite using a flow-electrode capacitive desalination (FCDI) and fluidized bed crystallization (FBC) coupled system

Changyong Zhang et al.

Summary: Efficient removal and recovery of phosphate from wastewater is crucial for environmental and economic benefits. Recent efforts have focused on harvesting phosphate as vivianite, a potential slow-release fertilizer and precursor for lithium iron phosphate production. A novel process involving flow-electrode capacitive deionization (FCDI) and fluidized bed crystallization (FBC) has shown promising results in P concentration and immobilization. The study provides a pathway for sustainable phosphorus recovery from rich wastewaters.

WATER RESEARCH (2021)

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Article Engineering, Chemical

High-performance desalination of three-dimensional nitrogen-doped carbon framework reinforced Prussian blue in capacitive deionization

Ao Gong et al.

Summary: By embedding iron-based Prussian blue (FeHCF) in a three-dimensional nitrogen-doped carbon framework (3DNC), the synergistic effect of both composites enhances the electrochemical performance for capacitive deionization. The FeHCF@3DNC electrode shows high desalination capacity and excellent cycling stability with lower energy consumption compared to other materials. XPS analysis confirms the major role of Fe3+/Fe2+ couple in the desalination and regeneration processes.

DESALINATION (2021)

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Article Chemistry, Physical

Effects of carbon black on the electrochemical performances of SiOx anode for lithium-ion capacitors

Xianzhong Sun et al.

Summary: The study on the effects of carbon conductive additive on SiOx anode revealed that carbon black showed a synergetic effect with SiOx particles in enhancing the rate capability and cycling stability of the anode.

JOURNAL OF POWER SOURCES (2021)

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Article Chemistry, Multidisciplinary

Efficient PEDOT Electrode Architecture for Continuous Redox-Flow Desalination

Karthick Ramalingam et al.

Summary: By electrochemically decorating conducting polymer PEDOT on a graphite foil, the energy consumption of RFD is reduced and the salt removal rate is increased significantly, leading to excellent cycling stability.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

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Article Chemistry, Physical

Carbon-based slurry electrodes for energy storage and power supply systems

Monjur Mourshed et al.

Summary: The electrochemical energy storage using slurry flow electrodes, particularly with carbon-based materials, is recognized as having potential applications in energy storage and power supply. This study comprehensively reviews the capacitive charge storage techniques, carbon particle properties, and electrochemical properties of slurry flow electrodes. It also highlights key challenges and research gaps for future studies to enhance the performance of carbon-based electrodes towards commercialization.

ENERGY STORAGE MATERIALS (2021)

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Article Chemistry, Physical

Redox-catalysis flow electrode desalination in an organic solvent

Qiang Wei et al.

Summary: The study proposes using organic redox flow electrode in FCDI to achieve efficient desalination and low energy consumption. By adjusting the electrolyte and adding specific carbon nanomaterials, the highest desalination rate in capacitive deionization systems to date was achieved.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Physical

Carbon nanofiber@ZIF-8 derived carbon nanosheet composites with a core-shell structure boosting capacitive deionization performance

Xinyi Gong et al.

Summary: This work focused on the development of hierarchical porous carbon-carbon composites as electrode materials for capacitive deionization. By tailoring the composition and porosity of the composite, a large desalination capacity and high desalination rate were achieved. The engineered material exhibited excellent capacitive deionization performance for various ionic solutions, representing a significant advancement in electrode development for deionization applications.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Environmental Sciences

Selective Recovery of Phosphorus from Synthetic Urine Using Flow-Electrode Capacitive Deionization (FCDI)-Based Technology

Longqian Xu et al.

Summary: This study successfully achieved the selective separation of high-purity phosphate (P) from synthetic urine containing a high concentration of Cl- by adjusting the charging and discharging processes of a flow-electrode capacitive deionization (FCDI) unit.

ACS ES&T WATER (2021)

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Article Engineering, Environmental

Enhanced Charge Efficiency and Electrode Separation Utilizing Magnetic Carbon in Flow Electrode Capacitive Deionization

Junjun Ma et al.

Summary: This study demonstrates a tailored FCDI process using magnetic activated carbons (MACs) that exhibit high charge efficiency and energy efficiency, along with excellent magnetic separation efficiency and stability. The use of MACs provides a safe and contactless separation method for fluidized electrodes in the FCDI system, improving operational and maintenance aspects in practical applications.

ACS ES&T ENGINEERING (2021)

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Article Engineering, Environmental

Cost Comparison of Capacitive Deionization and Reverse Osmosis for Brackish Water Desalination

Xitong Liu et al.

Summary: The study found that the economic viability of CDI technology largely depends on component lifespan, with lifespans longer than 1 year needed to reduce brackish water desalination costs relative to RO. Sensitivity analyses indicate that CDI processes are unlikely to be cost-competitive against RO for feedwater concentrations greater than 2 g/L.

ACS ES&T ENGINEERING (2021)

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Article Chemistry, Physical

A membrane-less desalination battery with ultrahigh energy efficiency

Lu Guo et al.

Summary: Seawater desalination is crucial for sustainable water resources, and a novel membrane-less desalination battery using NiCo MOF@BP composite and Ag@rGO electrodes has shown great potential with high stability, efficiency, and low energy consumption, paving the way for future developments in desalination batteries.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Multidisciplinary

Energy storage and generation through desalination using flow-electrodes capacitive deionization

Hyunseung Lim et al.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2020)

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Article Chemistry, Physical

A hybrid system of capacitive deionization and redox flow battery for continuous desalination and energy storage

Byeongkyu Kim et al.

JOURNAL OF POWER SOURCES (2020)

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Article Chemistry, Multidisciplinary

Dual-Zinc Electrode Electrochemical Desalination

Jinhong Dai et al.

CHEMSUSCHEM (2020)

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Article Engineering, Environmental

Carbon Black Flow Electrode Enhanced Electrochemical Desalination Using Single-Cycle Operation

Junjun Ma et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2020)

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Article Chemistry, Physical

Role of ion exchange membranes and capacitive electrodes in membrane capacitive deionization (MCDI) for CO2 capture

L. Legrand et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2020)

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Article Engineering, Environmental

Flow-electrode capacitive deionization (FCDI) scale-up using a membrane stack configuration

Jinxing Ma et al.

WATER RESEARCH (2020)

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Article Nanoscience & Nanotechnology

MXene/Activated-Carbon Hybrid Capacitive Deionization for Permselective Ion Removal at Low and High Salinity

Mohammad Torkamanzadeh et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Multidisciplinary

Integrated Saltwater Desalination and Energy Storage through a pH Neutral Aqueous Organic Redox Flow Battery

Camden Debruler et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Engineering, Chemical

Feasibility study of reverse osmosis-flow capacitive deionization (RO-FCDI) for energy-efficient desalination using seawater as the flow-electrode aqueous electrolyte

Hyun Jun Chung et al.

DESALINATION (2020)

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Article Engineering, Chemical

Lithium extraction from brine in an ionic selective desalination battery

Xiaoyu Zhao et al.

DESALINATION (2020)

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Article Electrochemistry

Inverted hybrid-capacitive deionization with polyaniline nanotubes doped activated carbon as an anode

Pengfei Nie et al.

ELECTROCHIMICA ACTA (2020)

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Article Engineering, Environmental

Pseudocapacitive Behaviors of Polypyrrole Grafted Activated Carbon and MnO2 Electrodes to Enable Fast and Efficient Membrane-Free Capacitive Deionization

Guangcai Tan et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2020)

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Article Engineering, Chemical

Enhanced desalination performance utilizing sulfonated carbon nanotube in the flow-electrode capacitive deionization process

Yanmeng Cai et al.

SEPARATION AND PURIFICATION TECHNOLOGY (2020)

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Article Engineering, Chemical

Ammonia recovery from concentrated solution by designing novel stacked FCDI cell

Kuo Fang et al.

SEPARATION AND PURIFICATION TECHNOLOGY (2020)

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Article Engineering, Chemical

Hydrophilic MoS2/polydopamine (PDA) nanocomposites as the electrode for enhanced capacitive deionization

Qingmiao Wang et al.

SEPARATION AND PURIFICATION TECHNOLOGY (2020)

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Article Environmental Sciences

Springing for Safe Water: Drinking Water Quality and Source Selection in Central Appalachian Communities

Hannah Patton et al.

WATER (2020)

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Review Chemistry, Multidisciplinary

Exploration of Energy Storage Materials for Water Desalination via Next-Generation Capacitive Deionization

Wenhui Shi et al.

FRONTIERS IN CHEMISTRY (2020)

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Article Nanoscience & Nanotechnology

Modification of Cation-Exchange Membranes with Polyelectrolyte Multilayers to Tune Ion Selectivity in Capacitive Deionization

Sevil Sahin et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Multidisciplinary

Enabling Superior Sodium Capture for Efficient Water Desalination by a Tubular Polyaniline Decorated with Prussian Blue Nanocrystals

Wenhui Shi et al.

ADVANCED MATERIALS (2020)

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Article Engineering, Environmental

Desalination behavior and performance of flow-electrode capacitive deionization under various operational modes

Kunyue Luo et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Engineering, Environmental

pH Dependence of Phosphorus Speciation and Transport in Flow-Electrode Capacitive Deionization

Yanhong Bian et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2020)

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Article Engineering, Environmental

Pseudocapacitive deionization of uranium(VI) with WO3/C electrode

Jian Zhou et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Engineering, Environmental

Selective Ammonium Removal from Synthetic Wastewater by Flow-Electrode Capacitive Deionization Using a Novel K2Ti2O5-Activated Carbon Mixture Electrode

Lin Lin et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2020)

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Article Chemistry, Multidisciplinary

Improved Desalination Performance of Flow- and Fixed-Capacitive Deionization using Redox-Active Quinone

Nguyen Anh Thu Tran et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

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Article Chemistry, Multidisciplinary

Enhanced Desalination Performance of Capacitive Deionization Using Nanoporous Carbon Derived from ZIF-67 Metal Organic Frameworks and CNTs

Ngo Minh Phuoc et al.

NANOMATERIALS (2020)

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Article Chemistry, Physical

Low energy consumption flow capacitive deionization with a combination of redox couples and carbon slurry

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CARBON (2020)

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Article Engineering, Environmental

Low energy consumption and mechanism study of redox flow desalination

Fuming Chen et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Sulfonated nickel phthalocyanine redox flow cell for high-performance electrochemical water desalination

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DESALINATION (2020)

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Can flow-electrode capacitive deionization become a new in-situ soil remediation technology for heavy metal removal?

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JOURNAL OF HAZARDOUS MATERIALS (2020)

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A review on free-standing electrodes for energy-effective desalination: Recent advances and perspectives in capacitive deionization

Sareh Vafakhah et al.

DESALINATION (2020)

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Treatment of acidic wastewater via fluoride ions removal by SiO2 particles followed by phosphate ions recovery using flow-electrode capacitive deionization

Alon Epshtein et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Continuous Electrochemical Desalination via a Viologen Redox Flow Reaction

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JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2020)

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Techno-economic analysis of capacitive and intercalative water deionization

Michael Metzger et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

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Porous nitrogen-doped MXene-based electrodes for capacitive deionization

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ENERGY STORAGE MATERIALS (2020)

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A Desalination Battery Combining Cu3[Fe(CN)6]2 as a Na-Storage Electrode and Bi as a Cl-Storage Electrode Enabling Membrane-Free Desalination

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CHEMISTRY OF MATERIALS (2019)

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Comparison of faradaic reactions in flow-through and flow-by capacitive deionization (CDI) systems

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ELECTROCHIMICA ACTA (2019)

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Flow-Electrode CDI Removes the Uncharged Ca-UO2-CO3 Ternary Complex from Brackish Potable Groundwater: Complex Dissociation, Transport, and Sorption

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ENVIRONMENTAL SCIENCE & TECHNOLOGY (2019)

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Flow-electrode capacitive deionization with highly enhanced salt removal performance utilizing high-aspect ratio functionalized carbon nanotubes

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Ammonia-Rich Solution Production from Wastewaters Using Chemical-Free Flow-Electrode Capacitive Deionization

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Concurrent Nitrogen and Phosphorus Recovery Using Flow-Electrode Capacitive Deionization

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Diffusion-free Grotthuss topochemistry for high-rate and long-life proton batteries

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NATURE ENERGY (2019)

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Energy recovery from the flow-electrode capacitive deionization

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A Redox-Shuttled Electrochemical Method for Energy-Efficient Separation of Salt from Water

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Electrosorption of uranium(VI) by highly porous phosphate-functionalized graphene hydrogel

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JOURNAL OF CLEANER PRODUCTION (2019)

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High-Desalination Performance via Redox Couple Reaction in the Multichannel Capacitive Deionization System

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Advances in modification of commercial activated carbon for enhancement of CO2 capture

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Highly-dispersed Fe2O3@C electrode materials for Pb2+ removal by capacitive deionization

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CARBON (2019)

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Superiority of a novel flow-electrode capacitive deionization (FCDI) based on a battery material at high applied voltage

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DESALINATION (2019)

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Electrical energy from CO2 emissions by direct gas feeding in capacitive cells

L. Legrand et al.

ELECTROCHIMICA ACTA (2019)

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Technoeconomic Analysis of Brackish Water Capacitive Deionization: Navigating Tradeoffs between Performance, Lifetime, and Material Costs

Steven Hand et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2019)

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Integrated Flow-Electrode Capacitive Deionization and Microfiltration System for Continuous and Energy-Efficient Brackish Water Desalination

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Water Recovery Rate in Short-Circuited Closed-Cycle Operation of Flow-Electrode Capacitive Deionization (FCDI)

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Carbon nanotube- and graphene-based nanomaterials and applications in high-voltage supercapacitor: A review

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CARBON (2019)

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Applications of capacitive deionization: Desalination, softening, selective removal, and energy efficiency

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DESALINATION (2019)

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Enhanced Water Desalination by Increasing the Electroconductivity of Carbon Powders for High-Performance Flow-Electrode Capacitive Deionization

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Removal of heavy metal ions from wastewater by capacitive deionization using polypyrrole/chitosan composite electrode

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Highly compact, free- standing porous electrodes from polymer- derived nanoporous carbons for efficient electrochemical capacitive deionization

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An organic flow desalination battery

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ENERGY STORAGE MATERIALS (2019)

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Continuous desalination with a metal-free redox-mediator

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High-Rate and High-Voltage Aqueous Rechargeable Zinc Ammonium Hybrid Battery from Selective Cation Intercalation Cathode

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A review of modification of carbon electrode material in capacitive deionization

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RSC ADVANCES (2019)

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Carbon electrodes for capacitive technologies

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ENERGY STORAGE MATERIALS (2019)

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Superelastic Hybrid CNT/Graphene Fibers for Wearable Energy Storage

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Capacitive Membrane Stripping for Ammonia Recovery (CapAmm) from Dilute Wastewaters

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ENVIRONMENTAL SCIENCE & TECHNOLOGY LETTERS (2018)

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Membrane-spacer assembly for flow-electrode capacitive deionization

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APPLIED SURFACE SCIENCE (2018)

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Recovering ammonia from municipal wastewater by flow-electrode capacitive deionization

Kuo Fang et al.

CHEMICAL ENGINEERING JOURNAL (2018)

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Synergistic conversion and removal of total Cr from aqueous solution by photocatalysis and capacitive deionization

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CHEMICAL ENGINEERING JOURNAL (2018)

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Lithium capturing from geothermal water by hybrid capacitive deionization

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DESALINATION (2018)

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A direct comparison of flow-by and flow-through capacitive deionization

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DESALINATION (2018)

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Influence of Feed-Electrode Concentration Differences in Flow-Electrode Systems for Capacitive Deionization

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INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2018)

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Analysis of capacitive and electrodialytic contributions to water desalination by flow-electrode CDI

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Faradaic reactions in capacitive deionization (CDI) - problems and possibilities: A review

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WATER RESEARCH (2018)

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Removal of Hardness from Water Samples by a Carbonation Process with a Closed Pressure Reactor

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Electrochemical Desalination of Seawater and Hypersaline Brines with Coupled Electricity Storage

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ACS ENERGY LETTERS (2018)

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Confined Redox Reactions of Iodide in Carbon Nanopores for Fast and Energy-Efficient Desalination of Brackish Water and Seawater

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CHEMSUSCHEM (2018)

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Short-Circuited Closed-Cycle Operation of Flow-Electrode CDI for Brackish Water Softening

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ENVIRONMENTAL SCIENCE & TECHNOLOGY (2018)

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Coupling desalination and energy storage with redox flow electrodes

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NANOSCALE (2018)

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Energy Recovery and Process Design in Continuous Flow Electrode Capacitive Deionization Processes

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ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

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Ammonium Removal from Domestic Wastewater Using Selective Battery Electrodes

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ENVIRONMENTAL SCIENCE & TECHNOLOGY LETTERS (2018)

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Continuous Ammonia Recovery from Wastewaters Using an Integrated Capacitive Flow Electrode Membrane Stripping System

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ENVIRONMENTAL SCIENCE & TECHNOLOGY (2018)

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Article Engineering, Environmental

Integration of photovoltaic energy supply with membrane capacitive deionization (MCDI) for salt removal from brackish waters

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WATER RESEARCH (2018)

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Electrochemically-mediated selective capture of heavy metal chromium and arsenic oxyanions from water

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NATURE COMMUNICATIONS (2018)

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Lead Exposure in Low and Middle-Income Countries: Perspectives and Lessons on Patterns, Injustices, Economics, and Politics

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INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH (2018)

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NaTi2(PO4)3-Ag electrodes based desalination battery and energy recovery

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Ultrahigh Desalinization Performance of Asymmetric Flow-Electrode Capacitive Deionization Device with an Improved Operation Voltage of 1.8 V

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A novel three-dimensional desalination system utilizing honeycomb-shaped lattice structures for flow-electrode capacitive deionization

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Electrochemical characterization of electrolyte-filled porous carbon materials for electrosorption process

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JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2017)

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Bismuth as a New Chloride-Storage Electrode Enabling the Construction of a Practical High Capacity Desalination Battery

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Polydopamine Modified Activated Carbon for Capacitive Desalination

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JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2017)

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Plate-Shaped Graphite for Improved Performance of Flow-Electrode Capacitive Deionization

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A Prussian blue anode for high performance electrochemical deionization promoted by the faradaic mechanism

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NANOSCALE (2017)

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Recovery and recycling of lithium: A review

Basudev Swain

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Development of adsorption and electrosorption techniques for removal of organic and inorganic pollutants from wastewater using novel magnetite/porous graphene-based nanocomposites

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SEPARATION AND PURIFICATION TECHNOLOGY (2017)

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Comparison of Faradaic reactions in capacitive deionization (CDI) and membrane capacitive deionization (MCDI) water treatment processes

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WATER RESEARCH (2017)

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Carbon electrodes for capacitive deionization

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JOURNAL OF MATERIALS CHEMISTRY A (2017)

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Robust three-dimensional graphene skeleton encapsulated Na3V2O2(PO4)2F nanoparticles as a high-rate and long-life cathode of sodium-ion batteries

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NANO ENERGY (2017)

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Article Engineering, Environmental

Low Energy Desalination Using Battery Electrode Deionization

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ENVIRONMENTAL SCIENCE & TECHNOLOGY LETTERS (2017)

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Proceedings Paper Energy & Fuels

Hybrid capacitive deionization with anion-exchange membranes for lithium extraction

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INTERNATIONAL CONFERENCE ON ADVANCES IN ENERGY SYSTEMS AND ENVIRONMENTAL ENGINEERING (ASEE17) (2017)

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Analysis of the desalting performance of flow-electrode capacitive deionization under short-circuited closed cycle operation

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DESALINATION (2017)

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Nickel Hexacyanoferrate Electrodes for Continuous Cation Intercalation Desalination of Brackish Water

Slawomir Porada et al.

ELECTROCHIMICA ACTA (2017)

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Article Engineering, Chemical

Optimized desalination performance of high voltage flow-electrode capacitive deionization by adding carbon black in flow-electrode

Peng Liang et al.

DESALINATION (2017)

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Desalination of brackish water using capacitive deionization (CDI) technology

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DESALINATION AND WATER TREATMENT (2016)

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Dopamine as a Novel Electrolyte Additive for High-Voltage Lithium-Ion Batteries

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A Biodegradable Polydopamine-Derived Electrode Material for High-Capacity and Long-Life Lithium-Ion and Sodium-Ion Batteries

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Direct Capture of CO2 from Ambient Air

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CHEMICAL REVIEWS (2016)

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Capacitive deionization with Ca-alginate coated-carbon electrode for hardness control

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DESALINATION (2016)

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Na2FeP2O7 as a Novel Material for Hybrid Capacitive Deionization

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ELECTROCHIMICA ACTA (2016)

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Capacitive neutralization deionization with flow electrodes

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ELECTROCHIMICA ACTA (2016)

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Flow-Electrode Capacitive Deionization Using an Aqueous Electrolyte with a High Salt Concentration

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ENVIRONMENTAL SCIENCE & TECHNOLOGY (2016)

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Article Engineering, Environmental

Development of Redox-Active Flow Electrodes for High-Performance Capacitive Deionization

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ENVIRONMENTAL SCIENCE & TECHNOLOGY (2016)

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Article Engineering, Environmental

New Operational Modes to Increase Energy Efficiency in Capacitive Deionization Systems

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ENVIRONMENTAL SCIENCE & TECHNOLOGY (2016)

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Surface-modified spherical activated carbon for high carbon loading and its desalting performance in flow-electrode capacitive deionization

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RSC ADVANCES (2016)

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Article Chemistry, Multidisciplinary

Stack Design and Operation for Scaling Up the Capacity of Flow-Electrode Capacitive Deionization Technology

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ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2016)

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Article Chemistry, Physical

Fluidized bed electrodes with high carbon loading for water desalination by capacitive deionization

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JOURNAL OF MATERIALS CHEMISTRY A (2016)

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Article Electrochemistry

Single module flow-electrode capacitive deionization for continuous water desalination

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ELECTROCHEMISTRY COMMUNICATIONS (2015)

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Porous carbon derived from Metal-organic framework (MOF) for capacitive deionization electrode

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ELECTROCHIMICA ACTA (2015)

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Effect of Oxidation of Carbon Material on Suspension Electrodes for Flow Electrode Capacitive Deionization

Kelsey B. Hatzell et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2015)

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Article Electrochemistry

Mathematical Modeling of Electrochemical Flow Capacitors

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JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2015)

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Redox Electrolytes in Supercapacitors

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JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2015)

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Article Materials Science, Multidisciplinary

Electrochemical removal of lead ions using paper electrode of polyaniline/attapulgite composites

Shan Li et al.

SYNTHETIC METALS (2015)

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Article Chemistry, Physical

Copper hexacyanoferrate nanoparticles as cathode material for aqueous Al-ion batteries

S. Liu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2015)

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Review Chemistry, Multidisciplinary

Polydopamine and Its Derivative Materials: Synthesis and Promising Applications in Energy, Environmental, and Biomedical Fields

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CHEMICAL REVIEWS (2014)

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Review Engineering, Chemical

Application of Capacitive Deionisation in water desalination: A review

Faisal A. AlMarzooqi et al.

DESALINATION (2014)

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A short review on reverse osmosis pretreatment technologies

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DESALINATION (2014)

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Batch mode and continuous desalination of water using flowing carbon deionization (FCDI) technology

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ELECTROCHEMISTRY COMMUNICATIONS (2014)

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Article Chemistry, Multidisciplinary

Hybrid capacitive deionization to enhance the desalination performance of capacitive techniques

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ENERGY & ENVIRONMENTAL SCIENCE (2014)

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Review Metallurgy & Metallurgical Engineering

Extraction of lithium from primary and secondary sources by pre-treatment, leaching and separation: A comprehensive review

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HYDROMETALLURGY (2014)

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Hierarchical meso-macro structure porous carbon black as electrode materials in Li-air battery

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JOURNAL OF POWER SOURCES (2014)

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Carbon flow electrodes for continuous operation of capacitive deionization and capacitive mixing energy generation

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JOURNAL OF MATERIALS CHEMISTRY A (2014)

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Article Chemistry, Physical

Ion storage and energy recovery of a flow-electrode capacitive deionization process

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JOURNAL OF MATERIALS CHEMISTRY A (2014)

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Article Energy & Fuels

Lithium availability and future production outlooks

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APPLIED ENERGY (2013)

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The study of lead removal from aqueous solution using an electrochemical method with a stainless steel net electrode coated with single wall carbon nanotubes

YaoXing Liu et al.

CHEMICAL ENGINEERING JOURNAL (2013)

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Article Engineering, Chemical

A study of the long-term operation of capacitive deionisation in inland brackish water desalination

Wei Zhang et al.

DESALINATION (2013)

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Article Electrochemistry

Long term stability of capacitive de-ionization processes for water desalination: The challenge of positive electrodes corrosion

Izaak Cohen et al.

ELECTROCHIMICA ACTA (2013)

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Desalination via a new membrane capacitive deionization process utilizing flow-electrodes

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ENERGY & ENVIRONMENTAL SCIENCE (2013)

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Energy Recovery in Membrane Capacitive Deionization

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ENVIRONMENTAL SCIENCE & TECHNOLOGY (2013)

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Highly Reversible Open Framework Nanoscale Electrodes for Divalent Ion Batteries

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NANO LETTERS (2013)

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Review Materials Science, Multidisciplinary

Review on the science and technology of water desalination by capacitive deionization

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PROGRESS IN MATERIALS SCIENCE (2013)

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Electrochemical Mg2+ intercalation into a bimetallic CuFe Prussian blue analog in aqueous electrolytes

Yoshifumi Mizuno et al.

JOURNAL OF MATERIALS CHEMISTRY A (2013)

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Proceedings Paper Energy & Fuels

Oxidative degradation of aqueous amine solutions of MEA, AMP, MDEA, Pz: A review

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GHGT-11 (2013)

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Energy consumption and constant current operation in membrane capacitive deionization

R. Zhao et al.

ENERGY & ENVIRONMENTAL SCIENCE (2012)

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Separation of low concentration of cesium ion from wastewater by electrochemically switched ion exchange method: Experimental adsorption kinetics analysis

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JOURNAL OF HAZARDOUS MATERIALS (2012)

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A Desalination Battery

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NANO LETTERS (2012)

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Thermal degradation of amines for CO2 capture

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CURRENT OPINION IN CHEMICAL ENGINEERING (2012)

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Use of mesoporous conductive carbon black to enhance performance of activated carbon electrodes in capacitive deionization technology

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Analysis and Status of Post-Combustion Carbon Dioxide Capture Technologies

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Theory of membrane capacitive deionization including the effect of the electrode pore space

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The Future of Seawater Desalination: Energy, Technology, and the Environment

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Selective Recovery Process of Lithium from Seawater Using Integrated Ion Exchange Methods

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Copper hexacyanoferrate battery electrodes with long cycle life and high power

Colin D. Wessells et al.

NATURE COMMUNICATIONS (2011)

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Electrode reactions and adsorption/desorption performance related to the applied potential in a capacitive deionization process

Jae-Hun Lee et al.

DESALINATION (2010)

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Electrosorption/Electrodesorption of Arsenic on a Granular Activated Carbon in the Presence of Other Heavy Metals

Euan J. Bain et al.

ENERGY & FUELS (2010)

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Removal of copper ions from wastewater by adsorption/electrosorption on modified activated carbon cloths

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JOURNAL OF HAZARDOUS MATERIALS (2010)

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Article Engineering, Environmental

Selective capture of cesium and thallium from natural waters and simulated wastes with copper ferrocyanide functionalized mesoporous silica

Thanapon Sangvanich et al.

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Improvement of desalination efficiency in capacitive deionization using a carbon electrode coated with an ion-exchange polymer

Yu-Jin Kim et al.

WATER RESEARCH (2010)

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Removal of total dissolved solids, nitrates and ammonium ions from drinking water using charge-barrier capacitive deionisation

Romain Broseus et al.

DESALINATION (2009)

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Capacitive delonization (CDI) for desalination and water treatment - past, present and future (a review)

Yoram Oren

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An Earth-system perspective of the global nitrogen cycle

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How a century of ammonia synthesis changed the world

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NATURE GEOSCIENCE (2008)

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Transformation of the nitrogen cycle: Recent trends, questions, and potential solutions

James N. Galloway et al.

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Recent advances in removing phosphorus from wastewater and its future use as fertilizer (1997-2003)

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Contribution to the lithium recovery from brine

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DESALINATION (2003)

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Mechanisms of chromium toxicity, carcinogenicity and allergenicity: Review of the literature from 1985 to 2000

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HUMAN & EXPERIMENTAL TOXICOLOGY (2001)

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Pressure driven membrane processes - the answer to the need of a growing world population for quality water supply and waste water disposal

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SEPARATION AND PURIFICATION TECHNOLOGY (2001)

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