4.7 Article

Metal-Organic Framework Seeding to Drive Phase Selection and Overcome Synthesis Limitations

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Summary: The synthesis of MOF-74 proceeds through the generation of distinct carboxylate coordinating phases, followed by deprotonation and formation of MOF-74. Stabilization and characterization of exclusively carboxylate coordinating phases can be achieved at high concentrations of linker and metal. The study suggests dissolution and redeposition as the mechanism of MOF-74 formation and provides insights into the formation mechanism of MOFs with multiple linker coordination types.

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