4.7 Article

Kinetics and mechanism of corrosion of oxide coating fabricated on aluminum alloy by the plasma electrolytic oxidation in molten salt

期刊

CORROSION SCIENCE
卷 208, 期 -, 页码 -

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2022.110604

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A; Aluminum; B; Electrochemical calculation; Polarization; C; Kinetic parameters; Oxide coatings; EIS

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The kinetics and mechanism of degradation of oxide coatings obtained by Plasma Electrolytic Oxidation method on AA1050 aluminum alloy in molten salts were studied. The influence of the corrosive medium on the morphology and phase composition of the samples was investigated, as well as the effect of oxygen and chloride ion concentrations on the corrosion rate. It was demonstrated that samples with oxide coatings showed polarization resistance three orders of magnitude greater than the untreated alloy, and a proposed corrosion mechanism was discussed.
The kinetics and mechanism for the degradation of oxide coatings obtained by the Plasma Electrolytic Oxidation method in molten salts on AA1050 aluminum alloy were studied. The effect of the corrosive medium on the morphology and phase composition of the samples was investigated. The influence of the concentration of ox-ygen and chloride ions on the corrosion rate was studied. It is demonstrated that the polarization resistance of samples with oxide coatings is three orders of magnitude greater than that of the untreated alloy. The main features of the corrosion process are considered, and a corrosion mechanism is proposed.

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