期刊
COORDINATION CHEMISTRY REVIEWS
卷 471, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2022.214744
关键词
C-H functionalization; [2+2+2] Cycloaddition; Cyclopentadienyl complexes; Homogeneous catalysis; Natural products; Total synthesis; Transfer hydrogenation
资金
- Russian Science Foundation
- Ministry of Science and Higher Educa- tion of the Russian Federation
- [19-73-20212]
This review comprehensively summarizes the use of cyclopentadienyl complexes of Group 9 metals in the total synthesis of natural compounds, including catalyzing cycloaddition, transfer hydrogenation, and C-H activation reactions.
Organic transformations catalyzed by cyclopentadienyl complexes of Group 9 metals (cobalt, rhodium and iridium) are the key steps of the total synthesis of various natural products. These complexes efficiently catalyze [2 + 2 + 2] cycloaddition, asymmetric transfer hydrogenation, C-H activation reactions, including annulation, alkylation, olefination and amidation processes. The advantages and drawbacks of these transformations, as well as the reaction mechanisms, are discussed. The review is comprehensive and summarizes the information on the use of cyclopentadienyl complexes of Group 9 metals in the total synthesis of natural compounds, published in the literature up to 2021.(c) 2022 Elsevier B.V. All rights reserved.
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