☆ 4.8 Review

Luminescence thermometry with transition metal ions. A review

COORDINATION CHEMISTRY REVIEWS (2022)

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Article Engineering, Environmental

Efficient luminescence lifetime thermometry with enhanced Mn4+-activated BaLaCa1-xMgxSbO6 red phosphors

Guixian Li et al.

Summary: Introducing smaller Mg2+ ions to replace Ca2+ site in the BaLaCaSbO6 matrix leads to a significant enhancement in luminescence intensity, red-shift, and luminescence lifetime. These modulations are mainly attributed to the strengthen pressure on the local structure, superior lattice rigidity, and suppression of non-radiative transition after the substitution of smaller Mg2+. The effective lifetime-based luminescence thermometry is achieved due to thermal quenching behavior of Mn4+ ions in the matrix.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Lanthanide dopant stabilized Ti3+ state and supersensitive Ti3+-based multiparametric luminescent thermometer in SrTiO3:Ln3+ (Ln3+ = Lu3+, La3+, Tb3+) nanocrystals

W. Piotrowski et al.

Summary: The substitution of Sr2+ by trivalent lanthanide ions in SrTiO3 nanocrystals enhances Ti3+ near-infrared emission, leading to the development of highly sensitive luminescent nanothermometers with exceptional repeatability in measurements.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Chemistry, Inorganic & Nuclear

Synergistic luminescent thermometer using co-doped Ca2GdSbO6:Mn4+/(Eu3+ or Sm3+) phosphors

Guixian Li et al.

Summary: Luminescent thermometers provide a non-contact method of probing temperature with high sensitivity and response speed at the nanoscale. By co-doping the highly temperature-sensitive Mn4+ and less-sensitive Eu3+ (or Sm3+) activators into a Ca2GdSbO6 matrix, an effective thermometer is formed.

DALTON TRANSACTIONS (2022)

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Article Chemistry, Inorganic & Nuclear

Enhancing the temperature sensitivity of Cr3+ emissions by modification of the host's composition for fluorescence thermometry applications

Meiling Shi et al.

Summary: The LnAl(3)(BO3)(4):Cr3+ phosphors exhibit temperature sensitivity and improved relative sensitivity by tuning the energy gap between emitting levels and modifying the host's composition. This study provides insights into the development of novel FIR thermometric materials with high-sensitivity.

DALTON TRANSACTIONS (2022)

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Article Materials Science, Ceramics

Highly sensitive optical thermometer of Sm3+, Mn4+ activated LaGaO3 phosphor for the regulated thermal behavior

Ziyang Li et al.

Summary: This study investigated the luminescence properties and temperature sensing performance of Sm3+ and Mn4+ co-activated LaGaO3 phosphors, revealing their dependency on ambient temperature and optical behavior at different temperatures. The anti-thermal quenching performance of Sm3+ ions and emission declination of Mn4+ ions were observed, leading to a recorded temperature sensitivity of 4.19% K-1 and 2.09% K-1 based on the fluorescent intensity ratio (orange/red) of the phosphor. The explored film combined with LaGaO3: Sm3+, Mn4+ phosphor showed potential as a multi-color optical thermometer.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2022)

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Article Materials Science, Multidisciplinary

A parallel investigation of un-doped and manganese ion-doped zinc selenide quantum dots at cryogenic temperature and application as an optical temperature sensor

Vineet Sharma et al.

Summary: Un-doped and manganese ion doped zinc selenide quantum dots were investigated for their photoluminescence properties at different temperatures. The intensity of photoluminescence was found to be highly dependent on temperature, with the highest intensity at 77 K. The calculated activation energy values and lifetimes suggest potential applications for these quantum dots in optical temperature sensors.

MATERIALS CHEMISTRY AND PHYSICS (2022)

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Article Spectroscopy

Mn2+ ions substitution inducing improvement of optical performances in ZnAl2O4: Cr3+ phosphors: Energy transfer and ratiometric optical thermometry

Bingjun Zhu et al.

Summary: Zn1-xMnxAl2O4:0.1 mol% Cr3+ (0.04 <= x <= 0.16) phosphors with single spinel phase were synthesized using sol-gel method. The Mn2+/Cr3+ co-doped ZnAl2O4 nanophosphors show green and red emission bands, with an energy transfer efficiency of 83% confirmed between Mn2+ and Cr3+. The temperature-sensitive properties show a relative sensitivity change from 3.7 %K-1 to 0.25 %K-1 over a temperature range from 80 K to 310 K.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2022)

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Article Chemistry, Physical

Modification of the thermometric performance of the lifetime-based luminescent thermometer exploiting Ti3+ emission in SrTiO3 and CaTiO3 by doping with lanthanide ions

W. M. Piotrowski et al.

Summary: In this work, a strategy to modulate the thermometric parameters of luminescent thermometers based on the lifetime of Ti3+ ions by introducing lanthanide (Ln(3+)) doping in SrTiO3 and CaTiO3 is presented. The mutual effect of the distortion of the local symmetry of the Ti3+ ions associated with the introduction of Ln3+ ions and/or the Ti3+-> Ln(3+) energy transfer enabled high relative sensitivities and expanded temperature range.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

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Article Materials Science, Multidisciplinary

Highly sensitive temperature reading from intensity ratio of Eu3+ And Mn4+emissions in Y3Al5O12 nanocrystals

Jovana Peris et al.

Summary: The potential of Eu3+, Mn4+ co-doped YAG for dual-activated luminescence intensity ratio thermometry is investigated. The samples were prepared and characterized, and the optimal concentrations of Mn4+ and Eu3+ were determined. Sensitivities were calculated using luminescence intensity ratio as the indicator of temperature.

MATERIALS RESEARCH BULLETIN (2022)

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Article Engineering, Electrical & Electronic

Near-Infrared Luminescent Lifetime-Based Thermometry with Mn5+-Activated Sr3(PO4)2 and Ba3(PO4)2 Phosphors

Zoran Ristic et al.

Summary: This paper describes Mn5+-activated Sr-3(PO4)(2) and Ba-3(PO4)(2) phosphors as near-infrared lifetime-based luminescence thermometry probes. The materials were prepared by a solid-state method and their structures were confirmed by X-ray diffraction analysis. The study found that the materials showed broad and strong absorption in the range of 650 to 950 nm, with a red shift in the emission maximum. The temperature properties of the phosphors were evaluated by measuring the temperature dependence of the Mn5+ excited-state lifetime.

ACS APPLIED ELECTRONIC MATERIALS (2022)

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Article Chemistry, Inorganic & Nuclear

Compensation effect of electron traps for enhanced fluorescence intensity ratio thermometry performance

Zhi-Han Zuo et al.

Summary: This work thoroughly investigates the impact of electron traps in a Mn-doped ZnGa2O4 spinel system on the fluorescence intensity ratio (FIR) thermometry performance. The results reveal that a higher concentration of electron traps contributes to a higher thermometry sensitivity by compensating for the intensity decline in the green channel. This study provides a novel strategy for enhancing thermometry performance through the manipulation of traps.

INORGANIC CHEMISTRY FRONTIERS (2022)

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Article Engineering, Multidisciplinary

Rise time-based phosphor thermometry using Mg4FGeO6:Mn4+

Tao Cai et al.

Summary: The rise time method, based on phosphorescence, has been used for temperature measurement with a long-term excitation approach, leading to low uncertainty in phosphor thermometry. Mg4FGeO6:Mn4+ exhibited a long rise time directly related to temperature, with high sensitivity and low uncertainty, making it suitable for temperature measurements.

MEASUREMENT SCIENCE AND TECHNOLOGY (2021)

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Article Materials Science, Ceramics

MgAl2O4:Cr3+ luminescence thermometry probe in the physiological temperatures range

Aleksandar Ciric et al.

Summary: Temperature sensing using photoluminescence of MgAl2O4:Cr3+ ceramic powder was investigated, showing high relative sensitivity in the physiological range. The intensity of emissions changes with temperature, allowing for temperature measurement.

CERAMICS INTERNATIONAL (2021)

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Review Chemistry, Physical

A review on fluorescence intensity ratio thermometer based on rare-earth and transition metal ions doped inorganic luminescent materials

Qiang Wang et al.

Summary: This review examines the current research status of all inorganic thermometers based on fluorescence intensity ratio (FIR) technology, categorizing and analyzing the thermometers in detail, discussing performance parameters, and looking forward to the future development.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Optics

Multifunctional optical thermometry based on the transition metal ions doped down-conversion Gd2ZnTiO6: Bi3+, Mn4+ phosphors

Mingxuan Zhang et al.

Summary: Researchers have designed a novel ratio-metric luminescent thermometer GZTO:Bi3+, Mn4+ with excellent thermal sensitivity and a wide temperature measurement range, suitable for high-precision temperature measurement, and with a potential application prospect as a plant growth lamp.

JOURNAL OF LUMINESCENCE (2021)

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Article Materials Science, Ceramics

Selective enrichment of Ln3+ (Ln = Yb; Er) and Cr3+ into SrF2 and ZnAl2O4 nanocrystals precipitated in fluorosilicate glass-ceramics: A dual mode optical temperature sensing study

Abhishek Wadhwa et al.

Summary: Dual-mode optical thermometry provides precise temperature sensing through the use of a semi-transparent glass-ceramic containing SrF2:Yb3+/Er3+ and ZnAl2O4:Cr3+ phases. The intense green up-conversion and enhanced red down-conversion luminescence of erbium and chromium, respectively, showed high temperature sensitivity. This study demonstrates the potential for accurate temperature measurements using fluorescence intensity and lifetime changes in the dual-mode optical thermometry system.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2021)

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Article Engineering, Multidisciplinary

Triple-temperature readout in luminescence thermometry with Cr3+-doped Mg2SiO4 operating from cryogenic to physiologically relevant temperatures

Zoran Ristic et al.

Summary: Cr3+-doped Mg2SiO4 orthorhombic nanoparticles were synthesized using a combustion method, showing deep-red emission due to the 3d(3) electron configuration of the Cr3+ ion. The temperature-induced changes in emission from Cr3+-doped Mg2SiO4 were tested for ratiometric luminescence thermometry from cryogenic to physiologically relevant temperatures, with relative sensitivities of 0.7% K-1 for emission intensity, 0.8% K-1 for lifetime, and 0.85% K-1 for band position at 310 K.

MEASUREMENT SCIENCE AND TECHNOLOGY (2021)

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Article Optics

Multiparametric luminescence thermometry from Dy3+, Cr3+ double activated YAG

Jovana Perisa et al.

Summary: This study demonstrates the multiparametric luminescence thermometry using Dy3+, Cr3+ double activated YAG. By analyzing the structure and emission spectra of the phosphors, changes in luminescence intensity at different temperatures were observed, providing a good foundation for temperature readings. By testing the luminescence intensity ratios using different methods, the relative sensitivities of temperature were determined.

JOURNAL OF LUMINESCENCE (2021)

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Article Optics

Tb3+,Mn3+ co-doped La2Zr2O7 nanoparticles for self-referencing optical thermometry

Forough Jahanbazi et al.

Summary: By combining Tb3+ and Mn3+ ions with different thermal behaviors, La2Zr2O7:Tb3+,Mn3+ nanoparticles achieved high thermometric sensitivity for optical thermometry. The emission intensity ratio of Tb3+ to Mn3+ over a temperature range showed maximum relative sensitivity of 1.82%·K-1 with minimal uncertainty, proving the promising potential of these dual activators for ratiometric optical thermometry.

JOURNAL OF LUMINESCENCE (2021)

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Article Chemistry, Physical

A high-sensitivity dual-mode optical thermometry based on one-step synthesis of Mn2+:BaAl12O19-Mn4+:SrAl12O19 solid solution phosphors

Yanting Zhu et al.

Summary: A series of Mn2+:BaAl12O19-Mn4+:SrAl12O19 solid solutions were synthesized and researched in this study, achieving thermometry based on the fluorescence intensity ratio by co-doping Mn2+/Mn4+. The material shows excellent temperature sensing properties and is suitable for high temperature measurement.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Materials Science, Multidisciplinary

Temperature dependence of the Cr3+-DOPED Mg2TiO4 near-infrared emission

Zoran Ristic et al.

Summary: This paper investigates the temperature dependence of near infrared luminescence of Cr3+-activated Mg2TiO4 phosphor and its potential applications in optical thermometry. It explores the temperature dependences of three emission features and finds that the luminescence intensity ratio, emission lifetime, and emission band shift all exhibit sensitivity to temperature changes.

OPTICAL MATERIALS (2021)

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Article Optics

Multimode luminescence thermometry based on emission and excitation spectra

Ilya E. Kolesnikov et al.

Summary: Luminescence thermometers are widely used for contactless and noninvasive temperature sensing, with most known sensors using a single parameter to define temperature. YVO4:Er3+ 0.1 at.% sample was reported as a thermal sensor in the 299-466 K range, utilizing multiple sensing techniques such as luminescence intensity ratio and spectral line position. Sub-degree temperature resolution was provided by all studied sensing methods.

JOURNAL OF LUMINESCENCE (2021)

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Article Chemistry, Physical

Effect of Temperature and High Pressure on Luminescence Properties of Mn3+ Ions in Ca3Ga2Ge3O12 Single Crystals

Yongjie Wang et al.

Summary: In this study, the temperature and high-pressure behaviors of Mn3+-doped garnet-type Ca3Ga2Ge3O12 single crystals were investigated. Various interesting optical properties and behaviors were discovered, including thermalization between different energy levels and blue shift induced by high pressure. The experimental data were found to be in perfect agreement with theoretical calculations.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

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Article Engineering, Electrical & Electronic

Temperature sensing using ruby coatings created by plasma electrolytic oxidation

Aleksandar Ciric et al.

Summary: The thermographic properties of Cr3+-doped Al2O3 coatings created by plasma electrolytic oxidation were investigated. The coatings were found to be dense and uniformly distributed over the aluminum surface, with room-temperature photoluminescent measurements revealing specific emissions typical for Cr3+ in Al2O3 octahedral configuration. Temperature information was obtained from the coating's emission, with maximal sensitivities observed for different temperature-induced changes in the emissions.

SENSORS AND ACTUATORS A-PHYSICAL (2021)

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Article Materials Science, Multidisciplinary

Boltzmann Thermometry in Cr3+-Doped Ga2O3 Polymorphs: The Structure Matters!

Michele Back et al.

Summary: The electronic structures and thermometric performances of Cr3+-doped alpha-Ga2O3 and beta-Ga2O3 polymorphs were compared, revealing a linear relationship between the T-4(2)-E-2 energy gap and the CF strength Dq. This trend could provide guiding principles for designing effective Cr3+-based Boltzmann thermometers. Additionally, beta-Ga2O3:Cr3+ particles were demonstrated to locally measure thermal variations during a catalytic reaction, showcasing their potential for real-world applications.

ADVANCED OPTICAL MATERIALS (2021)

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Review Physics, Applied

Luminescence based temperature bio-imaging: Status, challenges, and perspectives

A. Bednarkiewicz et al.

Summary: The article discusses the importance of using luminescent probes to obtain thermal images of living organisms, and the current focus on the development and optimization of luminescent reporters. It also points out the lack of attention to the methods and technologies required to image temperature distribution at both in vitro or in vivo levels.

APPLIED PHYSICS REVIEWS (2021)

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Article Engineering, Environmental

Unraveling the valence states of manganese ions and the effects of composition variation and post-processing in YGG1-x-LuGGx:Mn garnet optical sensor

Jinpu Zhang et al.

Summary: The study investigated the valence states of manganese ions, the effects of composition variation, and post-processing on YGG(1-x)LuGG(x):Mn garnet phosphors. It was found that co-doping of Zr4+ ions and reduction processing can enhance and weaken the emissions of Mn3+ and Mn4+, respectively.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Engineering, Environmental

Site preference and the optical thermometry strategy by different temperature response from two sites environment of Mn2+ in K7ZnSc2B15O30

Ying Fu et al.

Summary: A novel optical thermometry strategy based on the different temperature response of Mn2+ in the two sites environment of K7ZnSc2B15O30:Mn2+ was reported. The color-tunable Mn2+ doped K7ZnSc2B15O30 luminescence materials were successfully prepared, and the photoluminescence properties were studied. The results showed that the thermal quenching properties of Mn2+ at the two kinds of lattice sites are different, leading to a significant change in the intensity ratio of the two emission bands.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Physical

Investigation of a phosphor mixture of LiAl5O8: Cr3+ and LuPO4: Tb3+ as a dual-mode temperature sensor with high sensitivity

Liting Qiu et al.

Summary: SAMIX phosphor, a mixture of Cr3+-doped and Tb3+-doped phosphors, demonstrates temperature-dependent luminescence properties for Tb3+ and Cr3+, with a strong influence of temperature on the lifetime of Cr3+. The fluorescence intensity ratio technique based on Tb3+ and Cr3+ exhibits high sensitivity for temperature sensing.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Optics

Energy transfer and ratiometric Temperature sensing based on the dual-emitting NaMgBO3:Ce3+, Mn2+ phosphor

Jingzhou Song et al.

Summary: A series of dual-emitting phosphors NaMgBO3: Ce3+, Mn2+ were synthesized and characterized, demonstrating potential application in optical thermometry with excellent temperature sensitivity and resolution.

JOURNAL OF LUMINESCENCE (2021)

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Article Chemistry, Analytical

Research of Fluorescent Properties of a New Type of Phosphor with Mn2+-Doped Ca2SiO4

Xiaozhou Fan et al.

Summary: This study synthesized a new fluorescent material CSO:Mn2+ to improve the temperature measurement effect of the sensor, making a significant contribution to the development of fluorescent optical fiber temperature sensors.

SENSORS (2021)

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Article Materials Science, Ceramics

Sensitive temperature reading from intensity ratio of Cr3+ and defects' emissions in MgTiO3:Cr3+

Aleksandar Ciric et al.

Summary: The luminescence thermometry based on the intensity ratio of Cr3+ and host emissions in the Cr3+ activated MgTiO3 phosphor powder shows good temperature sensing properties over the 100-350 K range. The powder prepared using sol-gel and molten salt methods has a small crystallite size and exhibits strong temperature-dependent emission spectra. This method demonstrates high sensitivity, temperature resolution, and repeatability for luminescence temperature sensing applications.

CERAMICS INTERNATIONAL (2021)

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Article Chemistry, Physical

Highly sensitive multiparametric luminescent thermometer for biologically-relevant temperatures based on Mn4+, Ln3+ co-doped SrTiO3 nanocrystals

Karolina Trejgis et al.

Summary: This paper reports the novel SrTiO3:Mn4+ nanocrystals as a thermographic phosphor with extraordinary thermometric properties in biologically relevant temperatures. This material shows high relative sensitivity to temperature changes in each of the three temperature readout modes presented, making it one of the most promising candidates for highly sensitive temperature imaging.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Optics

High-sensitivity based on Eu2+/Cr3+ co-doped BaAl12O19 phosphors for dual-mode optical thermometry

Yanting Zhu et al.

Summary: A series of Eu2+/Cr3+ co-doped BaAl12O19 phosphor was synthesized via traditional high temperature solid stated method, with research on its temperature-sensitive characteristic. The phosphor can be used for thermometry based on fluorescence intensity ratio, utilizing the emissions of Eu2+ ion and Cr3+ ion separated well. Its dual-mode optical thermometry has potential application prospects in the field of optical thermometry.

JOURNAL OF LUMINESCENCE (2021)

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Article Materials Science, Multidisciplinary

Excitation selective thermal characteristics of Mg28Ge7.55-xGaxO32F15.04: Mn4+ and application in single/dual-mode optical thermometry

Zhibin Yang et al.

Summary: Transition metal ions Mn4+ are currently of interest for their potential in diverse luminescence applications. In this study, Mg28Ge7.55-xGaxO32F15.04: Mn4+ phosphors with optical thermometry capabilities were synthesized, showing promising applications in single-mode and dual-mode optical thermometers.

MATERIALS TODAY COMMUNICATIONS (2021)

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Article Chemistry, Inorganic & Nuclear

Dual-phase glass ceramics for dual-modal optical thermometry through a spatial isolation strategy

Xinyue Li et al.

Summary: This study proposes a spatial isolation strategy using dual-phase glass ceramics to prevent adverse energy transfer processes. Through structural characterization and optical thermometry, it was found that this method has potential practical applications in optical thermometry.

DALTON TRANSACTIONS (2021)

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Article Chemistry, Inorganic & Nuclear

Al2O3 co-doped with Cr3+ and Mn4+, a dual-emitter probe for multimodal non-contact luminescence thermometry

V. B. Mykhaylyk et al.

Summary: Utilizing luminescence probes for multimodal non-contact temperature measurements allows for cross-referencing results across different readout techniques, enhancing accuracy and reliability. By using two independent emitters as luminescent ions, sensor performance can be further enhanced with built-in redundancy for non-contact temperature sensing. Measurement accuracy can be improved over a broad temperature range using Al2O3-Cr,Mn spectroscopic methods.

DALTON TRANSACTIONS (2021)

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Article Materials Science, Multidisciplinary

The role of Cr3+ and Cr4+ in emission brightness enhancement and sensitivity improvement of NIR-emitting Nd3+/Er3+ ratiometric luminescent thermometers

W. Piotrowski et al.

Summary: This paper proposes co-doping with Cr3+/4+ as a strategy to enhance the near-infrared luminescence emission of Nd3+/Er3+-based luminescent thermometers and modulate the temperature sensitivity of the ratio of Nd3+ to Er3+ in YAG microcrystals. The study shows that increasing the Cr3+ concentration leads to enhanced emission intensity and significant improvement in temperature sensitivity.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Article Materials Science, Multidisciplinary

Strong sensitivity enhancement in lifetime-based luminescence thermometry by co-doping of SrTiO3:Mn4+ nanocrystals with trivalent lanthanide ions

W. M. Piotrowski et al.

Summary: The co-doping of trivalent lanthanide ions with SrTiO3:Mn4+ luminescent nanocrystals significantly improves the sensitivity of lifetime-based luminescent thermometers, with a maximum increase of 145%. The altered temperature dependence of Mn4+ emission in SrTiO3 due to the co-doping of Ln(3+) demonstrates the success of this approach. The maximal relative sensitivity values for different Ln(3+) co-dopants range from 3.87% K-1 to 5.10% K-1.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Article Chemistry, Inorganic & Nuclear

Improving the temperature-dependent sensitivity of Ca9Y(PO4)7:Ce3+,Mn2+ and g-C3N4 composite phosphors by mechanical mixing

Yuming Gong et al.

Summary: The study focused on developing composite phosphors of CYPO:Ce3+,Mn2+/g-C3N4 with different proportions for highly sensitive optical-temperature measurement. Through X-ray powder diffraction and fluorescence spectroscopy, it was found that the composite phosphors exhibited better temperature-dependent properties compared to pure CYPO:Ce3+,Mn2+. The maximum absolute and relative sensitivities of the designed composite phosphors were determined based on FIR technology, providing a feasible idea for versatile applications in optical-temperature measurement.

INORGANIC CHEMISTRY FRONTIERS (2021)

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Article Chemistry, Inorganic & Nuclear

High-sensitivity and wide-temperature-range dual-mode optical thermometry under dual-wavelength excitation in a novel double perovskite tellurate oxide

Zhaojie Wu et al.

Summary: The novel double perovskite SrLaLiTeO6 phosphors, doped with Mn4+ and Dy3+, exhibit distinct dual-emission properties. High-sensitivity and wide-temperature-range dual-mode optical thermometry is achieved by leveraging the diverse thermal quenching and decay lifetime of Mn4+ and Dy3+. The thermometric properties show potential for optical thermometry applications, with the ability to manipulate sensitivity values through different excitation wavelengths and multi-modal optical thermometry techniques.

DALTON TRANSACTIONS (2021)

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Article Materials Science, Multidisciplinary

From quencher to potent activator - Multimodal luminescence thermometry with Fe3+ in the oxides MAl4O7 (M = Ca, Sr, Ba)

K. Kniec et al.

Summary: This study demonstrates the potential of Fe3+ ion as a sensitive luminescence thermometry in aluminate hosts and proposes different modes of luminescence thermometry. By selectively changing the Fe-O bond distances, the relative sensitivity in CaAl4O7:Fe3+,Tb3+ can be modulated to values as high as around 2% K-1, with connected relative temperature uncertainties of around 0.3%.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Article Chemistry, Inorganic & Nuclear

Mn2+/Mn4+ co-doped LaM1-xAl11-yO19 (M = Mg, Zn) luminescent materials: electronic structure, energy transfer and optical thermometric properties

Dayu Huang et al.

Summary: Dual-emitting manganese ion doped LaMAl11O19 phosphors were prepared, showing potential as optical thermometers with unique optical thermometric features. The response of Mn2+ and Mn4+ to temperature was studied, with maximum relative sensitivities calculated as 3.22% K-1 and 3.13% K-1, respectively.

DALTON TRANSACTIONS (2021)

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Article Chemistry, Multidisciplinary

Experimental measurement of local high temperature at the surface of gold nanorods using doped ZnGa2O4 as a nanothermometer

Estelle Glais et al.

Summary: Heat measurement induced by photoexcitation of plasmonic metal nanoparticle assembly is essential for various applications. Luminescence nanothermometers provide an alternative solution for precise temperature control, with high spatial resolution and wide temperature range sensitivity. The study demonstrates the potential of optical nanosensors for local temperature measurement at the nanoscale, expanding the applications in catalysis and nanoelectronics.

NANOSCALE ADVANCES (2021)

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Article Chemistry, Inorganic & Nuclear

Red-tunable LuAG garnet phosphors via Eu3+→Mn4+ energy transfer for optical thermometry sensor application

Bing Yan et al.

Summary: This study has successfully achieved narrow red emission modulation and thermal quenching improvement by designing Eu3+-> Mn4+ energy transfer in LuAG host, showing promising potential in optical thermometry sensors.

INORGANIC CHEMISTRY FRONTIERS (2021)

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Article Materials Science, Multidisciplinary

Spectral and thermometric properties altering through crystal field strength modification and host material composition in luminescence thermometers based on Fe3+ doped AB2O4 type nanocrystals (A = Mg, Ca; B = Al, Ga)

K. Kniec et al.

Summary: This article presents an approach to modulate the luminescence parameters of Fe3+ ions in nanocrystals by modifying the host material composition and crystal field strength, demonstrating the ability to easily adjust the emission spectral range, thermal sensitivity, and operating temperature range. The proposed method is a step towards intentionally designing a highly sensitive luminescence thermometer.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Article Materials Science, Ceramics

Ratiometric optical thermometer with high sensitivity based on dual far-red emission of Cr3+ in Sr2MgAl22O36

Qiang Wang et al.

CERAMICS INTERNATIONAL (2020)

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Article Engineering, Environmental

Highly thermal-sensitive robust LaTiSbO6:Mn4+ with a single-band emission and its topological architecture for single/dual-mode optical thermometry

Haoyang Luo et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Optics

Optical thermometry properties of silicate glass ceramics with dual-phase for spatial isolation of Er3+ and Cr3+

Zhaohui Fang et al.

JOURNAL OF LUMINESCENCE (2020)

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Article Chemistry, Inorganic & Nuclear

Dual-Mode Optical Thermometry Design in Lu3Al5O12:Ce3+/Mn4+ Phosphor

Yibo Chen et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Physical

Ratiometric Optical Thermometer with High Sensitivity Based on Site-Selective Occupancy of Mn2+ Ions in Li5Zn8Al5Ge9O36 under Controllable Synthesis Atmosphere

Qiang Wang et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

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Article Spectroscopy

Photoluminescence properties of Ca9La(PO4)5SiO4F2:Ce3+/Tb3+/Mn2+ phosphors for applications in white light-emitting diodes and optical thermometers

Jia Zhang et al.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2020)

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Article Materials Science, Ceramics

Photoluminescence and temperature sensing of lanthanide Eu3+ and transition metal Mn4+ dual-doped antimoniate phosphor through site-beneficial occupation

Yueyue Song et al.

CERAMICS INTERNATIONAL (2020)

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Article Chemistry, Multidisciplinary

LiAl5O8:Fe3+ and LiAl5O8:Fe3+, Nd3+ as a New Luminescent Nanothermometer Operating in 1st Biological Optical Window

Karolina Kniec et al.

NANOMATERIALS (2020)

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Article Chemistry, Multidisciplinary

Synthesis, Cytotoxicity Assessment and Optical Properties Characterization of Colloidal GdPO4:Mn2+, Eu3+ for High Sensitivity Luminescent Nanothermometers Operating in the Physiological Temperature Range

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