期刊
COMPOSITES SCIENCE AND TECHNOLOGY
卷 229, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.compscitech.2022.109678
关键词
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资金
- Key Laboratory Stabilization Support Research Projects [HTKJ2021KL703001]
- Sichuan Science and Technology Program [2022YFG0362, 2022YFG0111]
- Zigong Science and Technology Program [2021CDZG-12-SCU]
This study successfully synthesized high-purity polar epoxy resins by improving the interactions between resin molecules and reducing chain motility. The complex process of group changes as a function of temperature was investigated using in-situ IR. The compression properties of the composites made with the newly synthesized resins were significantly improved.
The performance of carbon fiber reinforced composites has been shown to be constrained by the low compression to tensile strength ratio, which blocks its light-weight application. Designing and preparing high-strength, high-modulus resins has become a popular direction in the field of synthetic materials and increasing resin modulus has become one of the key goals for improving composite compression properties. This study improves the interactions between molecular segments and reduces chain motility by introducing polar groups into resin molecules and increasing the reactive functionality. Four typical polar epoxy resins with high purity were synthesized, with a modulus of 6500 MPa and a tensile strength of 86 MPa when cured. Hydrogen bonds are detected and the complex process of group changes as a function of temperature is investigated using in-situ IR. The compression properties of the composites made with the newly synthesized resins were significantly improved, which suggests the significance of high-performance resin design in lightweight carbon fiber composite materials.
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