期刊
CHINESE JOURNAL OF CHEMISTRY
卷 41, 期 6, 页码 725-740出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.202200583
关键词
Electrocyclization; Five-membered Rings; Heterocyclic Compounds; Pericyclic Reaction
This article reviews the development of 1,5-electrocyclizations, including stepwise, stoichiometric, or catalytic approaches. It also discusses 1,5-electrocyclizations involving heteroatoms (N, O, P, S) and provides a summary of related mechanistic studies.
Comprehensive SummaryAs an important part of pericyclic reaction, 6 pi 1,5-electrocyclization plays an important role in organic synthesis and chemical theory. Many types of five-membered rings could be constructed via 1,5-electrocyclization with high atom economy. Some elegant works have been reported in this field in the past few decades. However, it still needs a lot of effort in further advancements of 1,5-electrocyclization. This review summarized the development of 1,5-electrocyclization relying on stepwise, stoichiometric, or catalytic approaches. The 1,5-electrocyclization reaction will be divided into three categories: aza 1,5-electrocyclization, all-carbon 1,5-electrocyclization and other heteroatoms (O, P, S) involved 1,5-electrocyclization, and related mechanistic studies will also be involved in this review.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据