期刊
CHINESE JOURNAL OF CHEMISTRY
卷 41, 期 3, 页码 273-279出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.202200549
关键词
Surface wrinkling; Azo compounds; Polymers; Isomerization; Information storage; Azo films
A cost-effective strategy was proposed to fabricate stimulus-sensitive surfaces with tunable morphologies using photo-induced stress relaxation, which can be used as rewritable information storage media for non-ink printing.
Stimulus-sensitive surfaces with tunable morphologies exhibit a wide range of applications in the fields of surface science and engineering. Herein, a cost-effective yet practical strategy is proposed to fabricate photo-sensitive patterning surface on film/substrate wrinkle system based on an azo-containing polyblend. By manipulating the stress field of the bilayer system globally and/or locally upon the stress relaxation triggered by the reversible cis-trans isomerization of the azobenzene, heating/cooling triggered surface wrinkles on the polyblend films could be tailor-made with visible-light-irradiation. Notably, upon selective photo-irradiation, bespoke surface patterns may be cyclically generated or eliminated, allowing these reconfigurable patterned polyblend surfaces to be used as rewritable information storage media for non-ink printing. The as-prepared photo-printed information patterns with high-resolution are shown to be rewritable for multiple cycles and legible for over 90 d in dark ambient conditions. This study not only provides a versatile strategy for flourishing the stimulus-sensitive systems, but also sheds light on the stress relaxation-triggered morphological evolution of the wrinkling polyblend films.
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