期刊
CHINESE CHEMICAL LETTERS
卷 34, 期 5, 页码 -出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2022.107792
关键词
AIEgens; Structure -property relationship; Fluorescent chemosensor; Azine derivatives; Calculations
In the past twenty years, aggregation-induced emission (AIE) has gained widespread interest due to its promising applications. The development of novel and easily synthesized AIE luminogens (AIEgens) is a fascinating research topic. This study aims to investigate the structure-property relationship of AIEgens by using a series of azine derivatives (ADs) as models.
In recent twenty years, aggregation-induced emission (AIE), due to its excellent application prospect, has aroused widespread interests. The development of novel and easy to make AIE luminogens (AIEgens) is an attractive subject. For this purpose, it's very important to study the structure-property relationship of AIEgens. Because azine derivatives are easy to synthesis and some of them have nice AIE properties, herein, a series of azine derivatives (ADs) were employed as models to study the influence of differ-ent functional groups, electronic effects and structures on the AIE properties of azine derivatives. The AIE mechanism were studied by single crystal analysis, density functional theory (DFT) calculations and so on. The results indicated that the o-hydroxyl aryl substituted azine compounds could show good AIE proper-ties. Meanwhile, the AIE properties of o-hydroxyl aryl substituted azine compounds were also influenced by the electronic effects of the aryl groups in the azine compounds. The o-hydroxyl groups could form in-tramolecular hydrogen bond with imine group, which play key role to restrict the intramolecular rotation of the aryl groups and act as base stone for the AIE process of this kind compounds. The HOMO-LUMO energy gaps of o-hydroxyl substituted azine are smaller than other homologous compounds, which is agree with the proposed AIE mechanism. Finally, thanks to the AIE properties, the o-hydroxy-substituted azines could be used as efficient Al3 + and Cu2 + fluorescent chemosensors in different conditions. In ad-dition, test strips based on AD10 has been prepared, which can conveniently detect Cu2 + in industrial wastewater. This research supplied a way for the design of novel easy to make AIEgens through simple azine derivatives.(c) 2023 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据