Status and future trends of hollow fiber biogas separation membrane fabrication and modification techniques

With the increasing global demand for energy, renewable and sustainable biogas has attracted considerable attention. However, the presence of various gases such as methane, carbon dioxide (CO2), nitrogen, and hydrogen sulfide in biogas, and the potential emission of acid gases, which may adversely influence the environment, limits the efficient application of biogas in many fields. Consequently, researchers have focused on the upgrade and purification of biogas to eliminate impurities and obtain high-quality and high-purity biomethane with an increased combustion efficiency. In this context, the removal of CO2 gas, which is the most abundant contaminant in biogas, is of significance. Compared to conventional biogas purification processes such as water scrubbing, chemical absorption, pressure swing adsorption, and cryogenic separation, advanced membrane separation technologies are simpler to implement, easier to scale, and incur lower costs. Notably, hollow fiber membranes enhance the gas separation efficiency and decrease costs because their large specific surface area provides a greater range of gas transport. Several reviews have described biogas upgrading technologies and gas separation membranes composed of different materials. In this review, five commonly used commercial biogas upgrading technologies, as well as biological microalgae-based techniques are compared, the advantages and limitations of polymeric and mixed matrix hollow fiber membranes are highlighted, and methods to fabricate and

Automated summary

With the increasing global demand for energy, the upgrade and purification of biogas become essential to eliminate impurities and enhance combustion efficiency. Among different biogas purification processes, advanced membrane separation technologies, particularly hollow fiber membranes, have been highlighted for their simplicity, scalability, and cost-effectiveness in removing CO2, the most abundant contaminant in biogas.