4.6 Review

Enantioselective C-H Bond Functionalization Involving Arene Ruthenium(II) Catalysis

期刊

CHEMISTRY-A EUROPEAN JOURNAL
卷 29, 期 7, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202202461

关键词

asymmetric C-H activation; chiral arene ligands; chiral transient directing groups; relay catalysis; ruthenium

向作者/读者索取更多资源

The p-Cymene ruthenium(II) complex is widely used in C-H activation, but enantioselective C-H activation promoted by arene ruthenium(II) complexes has only recently been achieved. Various strategies including nitrene C-H insertion, chiral transient directing groups, chiral carboxylic acid, relay catalysis, and chiral arene ligands are summarized and discussed in this minireview, with the aim of inspiring further developments.
The p-Cymene ruthenium(II) complex is one of the most widely used catalysts in C-H activation. However, enantioselective C-H activation promoted by arene ruthenium(II) complexes has not been realized until recently. The revealed strategies include intramolecular nitrene C-H insertion, the use of chiral transient directing groups, chiral carboxylic acid, relay catalysis, and chiral arene ligands. In this minireview, these advances are summarized and discussed in the hope of spurring further developments.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据