期刊
CHEMISTRY LETTERS
卷 51, 期 10, 页码 1015-1017出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.220334
关键词
Ag(I) complex; Photoluminescence; Crystal structure
资金
- JSPS KAKENHI [17K05816]
- Seikei University
We synthesized a new type of asymmetric binuclear Ag(I) complex, which showed relatively strong green luminescence in the solid state.
We synthesized a new type of asymmetric binuclear Ag(I) complex, [Ag-2(dppaO(2))(2)(dppbz)] (1), consisting of two chelating dppaO(2)(-) ligands (dppaO(2)(-) = N,N-bis(diphenylphosphino)-amide-dioxide) and one bridging dppbz ligand (dppbz = 1,2-bis(diphenylphosphino)-benzene). According to X-ray crystal structure analysis, the two Ag(I) ions were adjacent to each other and were bridged by both the dppbz ligands and one of the oxygen atoms in the dppaO(2)(-) ligands. Complex 1 showed relatively strong green luminescence in the solid state.
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