期刊
CHEMCATCHEM
卷 14, 期 20, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.202200886
关键词
alkenes; alkynes; semi-hydrogenation; stereoselectivity; transition metals; hydrogen
资金
- Priority Research Program SPP 1708 of the Deutsche Forschungsgemeinschaft (DFG)
- European Research Council (ERC) [CoG 683150]
- Projekt DEAL
This article introduces the application of 3d metal catalysts in alkyne semi-hydrogenation, focusing on their groundbreaking advances in stereoselectivity.
The chemo- and stereoselective semi-hydrogenation of alkynes to alkenes is a fundamental transformation in synthetic chemistry, for which the use of precious 4d or 5d metal catalysts is well-established. In mankind's unwavering quest for sustainability, research focus has considerably veered towards the 3d metals. Given their high abundancy and availability as well as lower toxicity and noxiousness, they are undoubtedly attractive from both an economic and an environmental perspective. Herein, we wish to present noteworthy and groundbreaking examples for the use of 3d metal catalysts for diastereoselective alkyne semi-hydrogenation as we embark on a journey through the first-row transition metals.
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