4.4 Article

Study on the adhesion behaviour of oil droplets in water on solid surfaces with different wettability and inclination

期刊

CANADIAN JOURNAL OF CHEMICAL ENGINEERING
卷 101, 期 7, 页码 4170-4183

出版社

WILEY
DOI: 10.1002/cjce.24743

关键词

drainage time; inclination; oil droplet adhesion; oil droplet size; wettability

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Microscopic adhesion of oil droplets has been a popular research topic in the petrochemical field. This paper uses a high-speed camera to study the impact of oil droplets on different materials in water and analyzes the effects of material wettability, droplet size, and inclination on adhesion behavior. The experimental results show that enhancing material lipophilicity can prolong drainage time and inhibit adhesion, while excessive lipophilicity can shorten drainage time and lead to rapid adhesion. Increasing droplet size also prolongs drainage time, but excessive initial kinetic energy hinders adhesion. Additionally, increasing inclination inhibits droplet bounce but increases lateral and normal displacements, resulting in longer drainage time.
Microscopic adhesion of oil droplets is a hot research topic within multiphase flow systems in the petrochemical field in recent years, and it is also the key to revealing the mechanism of oil droplet-wall interaction. In this paper, a high-speed camera was used to capture the dynamic process of oil droplets impacting stainless steel, polyethylene, brass, and other materials in water, deeply analyze the influence mechanism of material wettability, droplet size, and inclination on adhesion behaviour in this process, and draw the Re similar to theta(eq) phase diagram. The experimental results show that properly enhancing the lipophilicity of the material can prolong the drainage time and effectively inhibit adhesion. Too much lipophilicity can dramatically shorten the drainage time instead, which easily leads to the rapid adhesion of oil droplets. An increase in droplet size can also prolong the drainage time; at Re >= 46.31, the excessive initial kinetic energy is consumed in the form of oil droplet rebound, which is not conducive to adhesion, and the more lipophilic the material is, the more significant the rebound effect. In addition, although an increase in the inclination can inhibit oil droplet bounce off, it also decreases the wall restraint to oil droplets, resulting in lateral and normal displacements, which greatly increases the drainage time. The findings can facilitate the understanding of oil droplet-wall interaction and provide a scientific basis for the design and development of efficient separation equipment and the optimization of the low-temperature gathering and transportation of high water-bearing crude oil.

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