期刊
CANADIAN JOURNAL OF CHEMICAL ENGINEERING
卷 101, 期 6, 页码 3522-3531出版社
WILEY
DOI: 10.1002/cjce.24711
关键词
acetic acid; cyclopentyl methyl ether; liquid membrane; tributyl phosphate
In this investigation, cyclopentyl methyl ether (CMPE) was explored as a new membrane solvent for the removal of acetic acid from an aqueous medium using facilitated bulk liquid membrane (BLM). Tributyl phosphate (TBP) was used as a carrier in CMPE to enhance the transport of acetic acid. The effects of various operating factors such as carrier concentration, receiving phase type, and receiving phase concentration on the removal were analyzed. The uptake was evaluated through extraction and receiving yields. A mass transfer modeling was established, and the mass transfer coefficients were determined. The highest yields were achieved with 95.4% extraction and 78.01% receiving yields at a carrier concentration of 2 mol/L in the membrane solvent and a receiving phase concentration of 4 mol/L NaOH.
In current investigation, cyclopentyl methyl ether (CMPE) was tested as a novel membrane solvent for acetic acid removal from an aqueous medium in the facilitated bulk liquid membrane (BLM). Tributyl phosphate (TBP) has been utilized as a carrier in CMPE to facilitate acetic acid transport. The influences of various operating factors like carrier concentration in the membrane solvent, receiving phase type, and receiving phase concentration on removal, were analyzed. The uptake was evaluated by means of feed (extraction) and receiving yields. Following this, a mass transfer modelling was established and the mass transfer coefficients were determined. The maximum yields were recorded as 95.4% for extraction and 78.01% for receiving yields at 2 mol & BULL; L-1 carrier concentration in membrane solvent, and 4 mol & BULL; L-1 NaOH of receiving phase concentration.
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