4.8 Review

Advances in two-dimensional materials for energy-efficient and molecular precise membranes for biohydrogen production

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Summary: This study successfully synthesized large-area and ultra-thin 2D COFs using a simple interfacial polymerization technique. The COFs demonstrated tunable properties, resulting in high solvent fluxes and sharp molecular weight cutoffs in COF membranes. The research also found that the pore passage resistance and membrane critical interfacial tension influence mass transport.

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Effect of light perturbation on the photo-fermentative hydrogen production of biomass from giant reed

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Superhydrophilic photocatalytic g-C3N4/SiO2 composite membranes for effective separation of oil-in-water emulsion and bacteria removal

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Microbiomes of biohydrogen production from dark fermentation of industrial wastes: current trends, advanced tools and future outlook

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Summary: Biohydrogen production through dark fermentation is an attractive solution for mitigating the effects of climate change. Understanding the microbial communities involved in the fermentation process and their interactions is crucial for process optimization. This review discusses the different systems and microbiomes used in dark fermentation, with a focus on palm oil mill effluent. The challenges and molecular biology tools used to study the microbial ecology associated with biohydrogen production are also summarized. The future outlook highlights the potential of microbiome-based technologies in maximizing biohydrogen production output.

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2D materials-based membranes for hydrogen purification: Current status and future prospects

Euntae Yang et al.

Summary: Hydrogen is the most viable energy carrier to replace fossil fuels and achieve zero emissions, and membrane separation is an important method to obtain high-purity hydrogen gas. However, the performance of commercial polymeric membranes has limited the development of membrane separation. Two-dimensional nanomaterials have the potential to improve membrane performance.

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A review on self-sustainable microbial electrolysis cells for electro-biohydrogen production via coupling with carbon-neutral renewable energy technologies

Euntae Yang et al.

Summary: MEC technology is a promising bioelectrochemical hydrogen production method, but sustainability is hindered by the need for external power input. Combining traditional MEC with advanced carbon-neutral technologies can lead to self-sustainable MEC systems. Overcoming thermodynamic barriers and discussing new approaches for achieving self-sustaining MECs will advance the practical application of this technology.

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MOF-in-COF molecular sieving membrane for selective hydrogen separation

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Summary: COFs are promising for separation membranes, but MOF-in-COF membranes show significant enhancement in hydrogen selectivity over other gases.

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2D boron nitride nanosheets in PIM-1 membranes for CO2/CH4 separation

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Summary: This article critically reviews various applications and prospects of graphitic carbon nitride (g-C3N4) nanomaterials in fields such as biomedicine, sensors, energy conversion and storage, hydrogen production, and photocatalytic degradation. It also discusses the theoretical aspects, attributes, current trends/challenges, and future considerations of g-C3N4 nanostructures in energy and environmental applications. It is believed that this review will provide readers and researchers with comprehensive knowledge and inspire the synthesis of novel g-C3N4-based materials for diverse fields.

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Green hydrogen enrichment with carbon membrane processes: Techno-economic feasibility and sensitivity analysis

Xuezhong He et al.

Summary: Biohydrogen production through dark fermentation from biomass has the potential to drive a green hydrogen economy, but the purification process often requires advanced separation technologies due to the high CO2 content. Carbon molecular sieving membranes are being explored as an alternative solution for biohydrogen enrichment. The study on techno-economic feasibility of H2-selective carbon membrane systems shows that high vacuum operation reduces specific costs, while feed gas compression enhances separation performance, with a minimum specific cost of $0.026/Nm3 at 6 bar for 90% hydrogen recovery. A two-stage carbon membrane system is technically feasible for >99.5% biohydrogen purity at $0.06/Nm3, lower than pressure swing adsorption, making it scalable and flexible without significant changes in production cost. Improving hydrogen permeance through submicrometer asymmetric carbon membranes is crucial for enhancing competitiveness in biohydrogen purification.

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Ultrafast Poly(sodium methacrylate)-Grafted UiO-66-Incorporated Nanocomposite Membranes Enable Excellent Active Pharmaceutical Ingredient Concentration

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Fluorine doped porous boron nitride for efficient CO2 capture and separation: A DFT study

Yan Liu et al.

Summary: This study explored the strong and selective CO2 adsorption ability of fluorine-doped porous BN through density functional theory investigation. The results showed that the introduction of fluorine atoms significantly reduced the work function and exhibited high adsorption selectivity. Additionally, the stability of the fluorine-doped porous BN for CO2 capture and separation was confirmed, indicating promising application potential in the field.

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Graphene oxide-modified g-C3N4 nanosheet membranes for efficient hydrogen purification

Yisa Zhou et al.

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Melamine-Doped Covalent Organic Framework Membranes for Enhanced Hydrogen Purification

Wei Zheng et al.

Summary: Melamine-doped COF membranes exhibit enhanced hydrogen purification performance with a separation factor of 12.7 and hydrogen permeance of 727 GPU. The introduction of melamine monomer alters both pore structure and pore surface, resulting in improved separation properties. Additionally, the TpPaMe COF membrane demonstrates excellent running stability and outperforms the Robeson 2008 upper bound in H-2/CO2 separation performance.

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Graphitic Carbon Nitride-Graphene Oxide Hybrid Membranes for Hydrogen Purification

Mingmin Jia et al.

Summary: Graphitic carbon nitride-graphene oxide composite membranes were prepared by filtrating g-C3N4 and a small amount of GO on a porous polymer support. Incorporation of GO nanosheets in g-C3N4 membranes prevented interedge defects or voids, leading to effective separation of H-2 molecules from larger gas molecules. At a GO weight loading of 5%, the composite membrane exhibited enhanced H-2/CO2 separation performance with a H-2 permeance of 3.66 X 10(-6) mol m(-2) s(-1) Pa-1 (H-2/CO2 ideal selectivity: 179.6).

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