Insights on ball milling enhanced iron magnesium layered double oxides bagasse biochar composite for ciprofloxacin adsorptive removal from water

Both ciprofloxacin (CIP) and sugarcane bagasse have brought enormous pressure on environmental safety. Here, an innovative technique combining Fe-Mg-layered double oxides and ball milling was presented for the first time to convert bagasse-waste into a new biochar adsorbent (BM-LDOs-BC) for aqueous CIP removal. The maximum theoretical adsorption capacity of BM-LDOs-BC reached up to 213.1 mg g(-1) due to abundant adsorption sites provided by well-developed pores characteristics and enhanced functional groups. The results of characterization, data fitting and environmental parameter revealed that pore filling, electrostatic interactions, H-bonding, complexation and pi-pi conjugation were the key mechanisms for CIP adsorptive removal. BM-LDOs-BC exhibited satisfactory environmental safety and outstanding adsorption capacity under various environmental situations (pH, inorganic salts, humic acid). Moreover, BM-LDOs-BC possessed excellent reusability. These superiorities illustrated that BM-LDOs-BC was a promising adsorbent and created a new avenue for rational placement of biowaste and high-efficiency synthesis of biochar for antibiotic removal.

Automated summary

This study presents an innovative technique to convert sugarcane bagasse into a new biochar adsorbent for the removal of ciprofloxacin (CIP) from water. The biochar adsorbent exhibited excellent environmental safety and outstanding adsorption capacity, and it was also reusable. The study provides a promising solution for the rational placement of biowaste and the high-efficiency synthesis of biochar for antibiotic removal.