Plasma-engraved Co3O4 nanostructure toward improved formaldehyde oxidation performance: Insight into the structure-activity relationship

Improving the surface area and the number of oxygen vacancy are vital for superior catalytic oxidation performance. Here, plasma-engraved technique was used for surface modification of Co3O4 nanostructure (cube and sphere morphology), which was applied to formaldehyde oxidation reaction. It was found that the formaldehyde oxidation can be boosted over plasma-engraved Co3O4 nanostructure, and efficiently realized at room temperature. Based on varied characterizations, it revealed that the plasma-treatment endowed the Co3O4 nanostructure with surface reconstruction (notches and broken fragments on surface), along with high surface area and rich oxygen vacancies. These factors contribute very important effort for improved activity. Besides, surface reaction mechanism was also proposed based on the in-situ DRIFTs, during which the CHOH was transformed to key intermediates (DOM, formate and/or carbonate), and finally to CO2 and H2O. This study also provides a very efficient strategy for surface modification of heterogeneous solid catalyst and their expand application in environmental catalysis.

Automated summary

Improving surface area and the number of oxygen vacancy is crucial for enhancing catalytic oxidation performance. In this study, a plasma-engraved technique was used to modify the surface of Co3O4 nanostructures (with cube and sphere morphology), and applied to the oxidation reaction of formaldehyde. It was observed that the plasma-engraved Co3O4 nanostructures exhibited enhanced efficiency for formaldehyde oxidation at room temperature. The plasma treatment resulted in surface reconstruction, increased surface area, and rich oxygen vacancies, which greatly contributed to the improved catalytic activity. Additionally, the surface reaction mechanism was proposed based on in-situ DRIFTs, showing the transformation of CHOH to key intermediates before eventually forming CO2 and H2O. This study also provides an efficient strategy for surface modification of solid catalysts and expands their application in environmental catalysis.