期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 312, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2022.121373
关键词
Bulk RP; RP nanosheet; Multiple interfacial effects; Impurity energy; Hydrogen generation; Oxide layer
资金
- Natural Science Foundation of China [22076082, 21872102, 21874099, 22176140]
- Natural Science Foundation of Tianjin City of China [19YFZCSF00740, 20YFZCSN01070]
- Frontiers Science Center for New Organic Matter [63181206]
- Tianjin Research Innovation Project for Postgraduate Students [2020YJSB050]
Red phosphorus (RP) has been attracting attention in photocatalysis due to its low cost, environmental friendliness, and optical properties. A combination of RP nanosheet (NS) and bulk RP structure (RP-S-12 h) was prepared and demonstrated to have higher charge density and efficient carrier transport, resulting in improved photocatalytic activity and stability. The optimized hydrogen evolution rate was 0.33 mmol g-1 h-1 and the quantum efficiency at 420 nm was 0.45%. RP-S-12 h also showed complete degradation of 50 ppm MO in 12 minutes, highlighting its potential in environmental remediation.
Red phosphorus (RP) has recently attracted much attention in photocatalysis for its low cost, environmental benign and optical properties. However, its photocatalytic activity is still restricted since the low-charge carrier mobility and the high water-solubility. Herein, RP-S-12 h (Combination of RP nanosheet (NS) and bulk RP structure) was prepared by hydrothermal method. Results showed that the multiple reactive active sites, the energy level matching, the emergence of intermediate state and the internal unequal potential for RP-S-12 h ensured higher charge density and efficient carrier transport, improving the photocatalytic activity and stability, emphasizing the role of multiple interfacial effects. The optimum hydrogen evolution rate was 0.33 mmol g-1 h-1, and the quantum efficiency at 420 nm is 0.45%. In addition, RP-S-12 h could completely degrade 50 ppm MO in 12 min. This study provides a novel insight into the interface design of metal-free photocatalyst for environmental remediation.
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