Spin-Selective Charge Transport in Lead-Free Chiral Perovskites: The Key towards High-Anisotropy in Circularly-Polarized Light Detection

Article Chemistry, Multidisciplinary

High Responsivity Circular Polarized Light Detectors based on Quasi Two-Dimensional Chiral Perovskite Films

Tianjun Liu et al.

Summary: A CPL detector based on quasi-2D chiral perovskite films is reported, which exhibits both a high dissymmetry factor and responsivity, showcasing the potential of chiral perovskites in CPL-dependent photonic technologies.

ACS NANO (2022)

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Review Chemistry, Multidisciplinary

Theory of Chirality Induced Spin Selectivity: Progress and Challenges

Ferdinand Evers et al.

Summary: This article provides a critical overview of the theory of the chirality-induced spin selectivity (CISS) effect and reviews its applications in electron processes. It discusses the latest developments in the understanding of the CISS effects in electron transmission, electron transport, and chemical reactions, and identifies the remaining challenges and research opportunities.

ADVANCED MATERIALS (2022)

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Article Chemistry, Physical

Chiral Methylbenzylammonium Bismuth Iodide with Zero-Dimensional Perovskite Derivative Structure

Parikshit Kumar Rajput et al.

Summary: Chiral hybrid metal halide perovskites combine chirality induced by the organic sublattice with optoelectronic properties from the inorganic sublattice. In this study, a zero-dimensional Pb-free perovskite derivative structure was reported, showing enantiomerically pure organic molecules inducing chirality in the inorganic sublattice. The material exhibited chiroptical properties, excitonic and shallow-defect emissions, and ultrafast exciton many-body interactions. These findings contribute to the development of next-generation Pb-free perovskites for chiral optoelectronics.

JOURNAL OF PHYSICAL CHEMISTRY C (2022)

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Article Chemistry, Multidisciplinary

Spin-Dependent Photovoltaic and Photogalvanic Responses of Optoelectronic Devices Based on Chiral Two-Dimensional Hybrid Organic-Inorganic Perovskites

Jingying Wang et al.

Summary: Research has shown that integrating chiral organic ligands into two-dimensional hybrid organic-inorganic perovskites can introduce spintronics applications, leading to spin-dependent photovoltaic and photogalvanic responses. This discovery may have potential applications in optoelectronic devices sensitive to light helicity.

ACS NANO (2021)

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Article Chemistry, Multidisciplinary

Chiral Lead-Free Hybrid Perovskites for Self-Powered Circularly Polarized Light Detection

Dong Li et al.

Summary: Metal-halide perovskites have emerged as promising alternatives for CPL detection due to their CPL-sensitive property induced by chiral organics and efficient charge transport of inorganic frameworks. This study successfully developed lead-free halide double perovskites, demonstrating significant chirality and self-powered CPL detection capabilities. The research suggests that hybrid double perovskites can be promising photoelectronic candidates for exploring new green circularly polarized light-sensitive materials with high performance.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Strong Second- and Third-Harmonic Generation in 1D Chiral Hybrid Bismuth Halides

Li Yao et al.

Summary: Breaking the symmetry of crystal structures can enable even-order nonlinear activities, such as second-harmonic generation. The designed chiral hybrid bismuth halides with naturally nonsymmetrical structure exhibit superior effective second-harmonic generation and third-harmonic generation performances compared to traditional nonlinear crystals, showcasing promising potential for nonlinear optical applications.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Direct Detection of Circularly Polarized Light Using Chiral Copper Chloride-Carbon Nanotube Heterostructures

Ji Hao et al.

Summary: The study demonstrates high-performance circularly polarized light detectors by synthesizing 0D chiral copper chloride hybrids, showing superior optoelectronic properties. Results show that through the design of chiral heterostructures, high responsivity, competitive anisotropy factor, and low working voltage can be achieved for CPL detection.

ACS NANO (2021)

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Article Materials Science, Multidisciplinary

Perspectives of Organic and Perovskite-Based Spintronics

Alberto Privitera et al.

Summary: Spin-related phenomena in optoelectronic materials have promising applications in various technological areas, with organic semiconductors and halide perovskites playing a key role in driving forward this field. The development of organic- and perovskite-based spintronics enables control over spin, charges, and photons in devices, with potential applications in new multifunctional spintronic devices.

ADVANCED OPTICAL MATERIALS (2021)

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Review Chemistry, Multidisciplinary

Recent Progress of Chiral Perovskites: Materials, Synthesis, and Properties

Jiaqi Ma et al.

Summary: The combination of chiral materials and halide perovskites provides an ideal platform for designing optoelectronic and spintronic devices, with recent studies demonstrating the transfer of chirality into halide perovskites and creating chiral perovskites with various exceptional properties.

ADVANCED MATERIALS (2021)

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Article Materials Science, Multidisciplinary

Spectral characterization of the Rashba spin-split band in a lead halide perovskite single crystal by photocurrent heterodyne interference spectroscopy

Yoshihiro Ogawa et al.

Summary: Utilizing heterodyne interference spectroscopy, we investigated the temperature dependence of the complex dielectric susceptibility spectrum of a perovskite CH3NH3PbBr3 single crystal. We observed two peaks below the exciton transition at the R point in the imaginary part of the spectrum, with different temperature dependences compared to the direct-transition exciton energy. The trends in both splitting width and peak intensities can be explained by the presence of a Rashba spin-split band.

PHYSICAL REVIEW B (2021)

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Review Chemistry, Multidisciplinary

Perovskite-Based Phototransistors and Hybrid Photodetectors

Chao Xie et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Room-Temperature Operation of a p-Type Molecular Spin Photovoltaic Device on a Transparent Substrate

Kaushik Bairagi et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Physical

Exploring Orbit-Orbit Interaction in Relationship to Photoluminescence Quantum Efficiency in Perovskite Quantum Dots through Rashba Effect

Hengxing Xu et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2020)

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Article Chemistry, Multidisciplinary

Chiral 2D Organic Inorganic Hybrid Perovskite with Circular Dichroism Tunable Over Wide Wavelength Range

Jihoon Ahn et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Physical

Strong Spin-Selective Optical Stark Effect in Lead Halide Perovskite Quantum Dots

Yulu Li et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2020)

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Review Nanoscience & Nanotechnology

Chiral-perovskite optoelectronics

Guankui Long et al.

NATURE REVIEWS MATERIALS (2020)

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Article Physics, Multidisciplinary

Ultrafast Control of Excitonic Rashba Fine Structure by Phonon Coherence in the Metal Halide Perovskite CH3NH3PbI3

Z. Liu et al.

PHYSICAL REVIEW LETTERS (2020)

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Article Chemistry, Multidisciplinary

Blinking Mechanisms and Intrinsic Quantum-Confined Stark Effect in Single Methylammonium Lead Bromide Perovskite Quantum Dots

Xue Han et al.

SMALL (2020)

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Article Multidisciplinary Sciences

Direct detection of circular polarized light in helical 1D perovskite-based photodiode

A. Ishii et al.

SCIENCE ADVANCES (2020)

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Article Multidisciplinary Sciences

Circularly polarized light detection using chiral hybrid perovskite

Chao Chen et al.

NATURE COMMUNICATIONS (2019)

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Review Chemistry, Multidisciplinary

Chiral Perovskites: Promising Materials toward Next-Generation Optoelectronics

Yuze Dong et al.

SMALL (2019)

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Article Multidisciplinary Sciences

Spin-optoelectronic devices based on hybrid organic-inorganic trihalide perovskites

Jingying Wang et al.

NATURE COMMUNICATIONS (2019)

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Article Chemistry, Multidisciplinary

Chiral 2D Perovskites with a High Degree of Circularly Polarized Photoluminescence

Jiaqi Ma et al.

ACS NANO (2019)

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Article Multidisciplinary Sciences

Spin-dependent charge transport through 2D chiral hybrid lead-iodide perovskites

Haipeng Lu et al.

SCIENCE ADVANCES (2019)

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Article Multidisciplinary Sciences

Bright triplet excitons in caesium lead halide perovskites

Michael A. Becker et al.

NATURE (2018)

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Article Chemistry, Physical

Spin-Orbit Interactions Greatly Accelerate Nonradiative Dynamics in Lead Halide Perovskites

Wei Li et al.

ACS ENERGY LETTERS (2018)

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Article Materials Science, Multidisciplinary

Structural dynamics in hybrid halide perovskites: Bulk Rashba splitting, spin texture, and carrier localization

Chao Zheng et al.

PHYSICAL REVIEW MATERIALS (2018)

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Article Chemistry, Multidisciplinary

[((R)-C8H12N)4][Bi2Br10] and [((S)-C8H12N)4][Bi2Br10]: Chiral Hybrid Bismuth Bromides Templated by Chiral Organic Cations

Tae Hwan Moon et al.

ACS OMEGA (2018)

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Article Chemistry, Multidisciplinary

Electric-Magneto-Optical Kerr Effect in a Hybrid Organic-Inorganic Perovskite

Feng-Ren Fan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Article Multidisciplinary Sciences

A molecular spin-photovoltaic device

Xiangnan Sun et al.

SCIENCE (2017)

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Review Chemistry, Multidisciplinary

Photogating in Low Dimensional Photodetectors

Hehai Fang et al.

ADVANCED SCIENCE (2017)

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Review Chemistry, Multidisciplinary

Spin-Dependent Transport through Chiral Molecules Studied by Spin-Dependent Electrochemistry

Prakash Chandra Mondal et al.

ACCOUNTS OF CHEMICAL RESEARCH (2016)

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Article Chemistry, Multidisciplinary

Spin Selective Charge Transport through Cysteine Capped CdSe Quantum Dots

Brian P. Bloom et al.

NANO LETTERS (2016)

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Article Physics, Multidisciplinary

Giant Rashba Splitting in CH3NH3PbBr3 Organic-Inorganic Perovskite

Daniel Niesner et al.

PHYSICAL REVIEW LETTERS (2016)

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Article Energy & Fuels

Defects in perovskite-halides and their effects in solar cells

James M. Ball et al.

NATURE ENERGY (2016)

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Article Chemistry, Physical

Current-driven dynamics of chiral ferromagnetic domain walls

Satoru Emori et al.

NATURE MATERIALS (2013)

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Spin-Selective Charge Transport in Lead-Free Chiral Perovskites: The Key towards High-Anisotropy in Circularly-Polarized Light Detection

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