A Highly Dynamic Covalent Polymer Network without Creep: Mission Impossible?

Dynamic covalent polymer networks provide an interesting solution to the challenging recyclability of thermosets and elastomers. One of the remaining design constraints, however, is balancing thermal reprocessability in the form of material flow with dimensional stability during use. As a result, many chemistries are being investigated in order to improve bond reactivity control and material robustness. This Minireview highlights a number of promising concepts, with a particular emphasis on disconnecting chemical reactivity in low and high temperature regimes to obtain creep resistant, yet highly dynamic polymer networks. In addition, we will highlight the impact of sharp reactivity changes when applying extrapolation-based approaches during rheological analysis. As a result, we are confident that abandoning the myth of permanent reactivity will aid in the development of sustainable polymeric materials that can truly combine the benefits of thermoplastic and thermoset behaviour.

Automated summary

Dynamic covalent polymer networks are an interesting solution for the recyclability of thermosets and elastomers, but balancing thermal reprocessability and dimensional stability remains a challenge. Disconnecting chemical reactivity at low and high temperatures can achieve creep resistance and high dynamism in polymer networks.