☆ 4.8 Article

Stimuli Responsive Silylene: Electromerism Induced Reversible Switching Between Mono- and Bis-Silylene

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Inorganic & Nuclear

Valence Tautomerism of p-Block Element Compounds - An Eligible Phenomenon for Main Group Catalysis?

Lutz Greb

Summary: Valence tautomerism has a significant impact on transition metal chemistry, and its applicability to p-block elements is still at an early stage. However, considering the substantial disparity in the properties of p-block elements in different redox states, this concept may offer a valid extension for future developments in main group catalysis.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Physical

LModeA-nano: A PyMOL Plugin for Calculating Bond Strength in Solids, Surfaces, and Molecules via Local Vibrational Mode Analysis

Yunwen Tao et al.

Summary: This article introduces a PyMOL plugin called LModeA-nano, which assesses bond strength in periodic systems and allows for comparison across different dimensions.

JOURNAL OF CHEMICAL THEORY AND COMPUTATION (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

An Isolable 2,5-Disila-3,4-Diphosphapyrrole and a Conjugated Si=P-Si=P-Si=N Chain Through Degradation of White Phosphorus with a N,N-Bis(Silylenyl)Aniline

Yun Xiong et al.

Summary: White phosphorus (P-4) undergoes degradation to produce 2,5-disila-3,4-diphosphapyrrole 2 and two novel functionalized Si=P doubly bonded compounds 3 and 4 when exposed to the new N,N-bis(silylenyl)aniline PhNSi2 1. The transformation of compound 2 into compounds 3 and 4 can be achieved depending on the molar ratio of 1 and P-4 as well as the reaction conditions. These compounds can interconvert through reactions with 1 and P-4.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Conformationally Switchable Silylone: Electron Redistribution Accompanied by Ligand Reorientation around a Monatomic Silicon

Taichi Koike et al.

Summary: This study reports a silicon(0) complex that can exhibit a reversible switch between pi-localized and pi-delocalized ylidene structures in the solid state and solution. The difference in physical properties between the two isomers is attributed to the balanced steric demand and redox noninnocent character of the CAASi ligand, altered by the orientation of the terminal ligands with respect to the Si-Si-Si plane.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Thermally Stable Rare-Earth Metal Complexes Supported by Chelating Silylene Ligands

Xiaofei Sun et al.

Summary: The study reports the synthesis and characterization of a series of thermally stable rare-earth metal complexes bearing bis(silylene) and mono(silylene) ligands. Different thermal stabilities were observed among complexes with different silylene ligands, indicating the importance of ligand structure in determining complex stability.

ORGANOMETALLICS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Entering new chemical space with isolable complexes of single, zero-valent silicon and germanium atoms

Shenglai Yao et al.

Summary: Monatomic zero-valent silicon and germanium complexes, stabilized by neutral donating ligands, have emerged as a new class of low-valent group 14 element compounds, featuring four valence electrons in the form of two lone pairs at a single site. These species are capable of transferring single Si and Ge atoms and acting as building blocks for novel group 14 species. The characteristic behavior of these compounds includes coordination to Lewis acids, oxidation with elemental chalcogens, and bond activation of common organic substrates and inert small molecules.

CHEMICAL COMMUNICATIONS (2021)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

N-Heterocyclic silylenes in coinage metal chemistry: an account of recent advances

Moushakhi Ghosh et al.

Summary: This article highlights the recent developments in silylene-coinage metal chemistry, focusing on synthetic approaches, unusual properties, and catalytic efficiency of these complexes. Further research is needed to explore the potential of silylene-coinage metal complexes in various chemical reactions.

DALTON TRANSACTIONS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Boosting homogeneous chemoselective hydrogenation of olefins mediated by a bis(silylenyl)terphenyl-nickel(0) pre-catalyst

Marcel-Philip Luecke et al.

Summary: Two new ligands were synthesized and studied, one of which demonstrated high catalytic activity in the hydrogenation of olefins under mild conditions, achieving the highest performance of a homogeneous nickel-based catalyst. The coordination mode of the Ni(0) site by the intramolecular phenylene was found to play a crucial role in the catalytic activity, as revealed by kinetic measurements and correlation experiments.

CHEMICAL SCIENCE (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis and Structure of Uranium-Silylene Complexes

I. Joseph Brackbill et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Highly Selective Substitution and Insertion Reactions of Silylenes in a Metal-Coordinated Polyphosphide

Ravi Yadav et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

A silicon-carbonyl complex stable at room temperature

Chelladurai Ganesamoorthy et al.

NATURE CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis and Reactivity of Bis(silylene)-Coordinated Calcium and Divalent Lanthanide Complexes

Xiaofei Sun et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Redox Noninnocent Monoatomic Silicon(0) Complex (Silylone): Its One-Electron-Reduction Induces an Intramolecular One-Electron-Oxidation of Silicon(0) to Silicon(I)

Shenglai Yao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

A bis(silylene)-stabilized diphosphorus compound and its reactivity as a monophosphorus anion transfer reagent

Yuwen Wang et al.

Nature Chemistry (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Where silylene-silicon centres matter in the activation of small molecules

Changkai Shan et al.

CHEMICAL SOCIETY REVIEWS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

N-heterocyclic silylene stabilized monocordinated copper(i)-arene cationic complexes and their application in click chemistry

Nasrina Parvin et al.

CHEMICAL COMMUNICATIONS (2020)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Side-Arm Functionalized Silylene Copper(I) Complexes in Catalysis

Alexander N. Paesch et al.

INORGANIC CHEMISTRY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Disilene-Silylene Interconversion: A Synthetically Accessible Acyclic Bis(silyl)silylene

Dominik Reiter et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

添加到收藏夹

Article Chemistry, Physical

Calculation of Magnetic Shielding Constants with meta-GGA Functionals Employing the Multipole-Accelerated Resolution of the Identity: Implementation and Assessment of Accuracy and Efficiency

Kevin Reiter et al.

JOURNAL OF CHEMICAL THEORY AND COMPUTATION (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Taming a monomeric [Cu(h 6-C6H6)]+ complex with silylene

Nasrina Parvin et al.

CHEMICAL SCIENCE (2018)

添加到收藏夹

Review Chemistry, Multidisciplinary

A New Area in Main-Group Chemistry: Zerovalent Monoatomic Silicon Compounds and Their Analogues

Shenglai Yao et al.

ACCOUNTS OF CHEMICAL RESEARCH (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Bis(silylene)-Substituted ortho-Carborane as a Superior Ligand in the Nickel-Catalyzed Amination of Arenes

Yu-Peng Zhou et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

添加到收藏夹

Review Chemistry, Multidisciplinary

Functional Short-Bite Ligands: Synthesis, Coordination Chemistry, and Applications of N-Functionalized Bis(diaryl/dialkylphosphino)amine-type Ligands

Christophe Fliedel et al.

CHEMICAL REVIEWS (2016)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Silylated Group 14 Ylenes: An Emerging Class of Reactive Compounds

Christoph Marschner

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Crystal structure refinement with SHELXL

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY (2015)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Facile Access to Mono- and Dinuclear Heteroleptic N-Heterocyclic Silylene Copper Complexes

Gengwen Tan et al.

ORGANOMETALLICS (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

From Bis(silylene) and Bis(germylene) Pincer-Type Nickel(II) Complexes to Isolable Intermediates of the Nickel-Catalyzed Sonogashira Cross-Coupling Reaction

Daniel Gallego et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis and Unexpected Coordination of a Silicon(II)-Based SiCSi Pincerlike Arene to Palladium

Wenyuan Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis and Characterization of a Singlet Delocalized 2,4-Diimino-1,3-disilacyclobutanediyl and a Silylenylsilaimine

Shu-Hua Zhang et al.

CHEMISTRY-A EUROPEAN JOURNAL (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Multiwfn: A multifunctional wavefunction analyzer

Tian Lu et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2012)

添加到收藏夹

News Item Chemistry, Multidisciplinary

MAIN GROUP CHEMISTRY Breaking the limits with silylenes

Matthias Driess

NATURE CHEMISTRY (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Chemistry of functionalized silylenes

Sakya S. Sen et al.

CHEMICAL SCIENCE (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Striking Stability of a Substituted Silicon(II) Bis(trimethylsilyl)amide and the Facile Si-Me Bond Cleavage without a Transition Metal Catalyst

Sakya S. Sen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

High Yield Access to Silylene RSiCl (R = PhC(NtBu)2) and Its Reactivity toward Alkyne: Synthesis of Stable Disilacyclobutene

Sakya S. Sen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

添加到收藏夹

Review Chemistry, Multidisciplinary

Stable Heavier Carbene Analogues

Yoshiyuki Mizuhata et al.

CHEMICAL REVIEWS (2009)

添加到收藏夹

Review Chemistry, Multidisciplinary

Valence tautomerism: More actors than just electroactive ligands and metal ions

Emi Evangelio et al.

COMPTES RENDUS CHIMIE (2008)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Synthesis and characterization of the unstable primary amido tin(II) dimer Sn-2{N(H)Dipp}(4) (Dipp = C6H3-2,6-Pr-2(i)) and the first sesqui-amido hemi-chloride derivative Sn-2{N(H)Dipp}(3)Cl: facile conversion of a primary amide to the imide (SnNDipp)(4)

W. Alexander Merrill et al.

DALTON TRANSACTIONS (2008)

添加到收藏夹

Review Chemistry, Multidisciplinary

Synthetic development and chemical reactivity of transition-metal silylene complexes

Rory Waterman et al.

ACCOUNTS OF CHEMICAL RESEARCH (2007)

添加到收藏夹

Article Chemistry, Multidisciplinary

Reversible oxidation state change in germanium(tetraphenylporphyrin) induced by a dative ligand:: Aromatic GeII(TPP) and antiaromatic GeIV(TPP)(pyridine)2

Julie A. Cissell et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)

添加到收藏夹

Review Chemistry, Multidisciplinary

Control of magnetic properties through external stimuli

Osamu Sato et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis and characterization of [PhC(NtBu)(2)]SiCl: A stable monomeric chlorosilylene

Cheuk-Wai So et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Valence tautomerism: New challenges for electroactive ligands

E Evangelio et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2005)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Studies on charge distribution and valence tautomerism in transition metal complexes of catecholate and semiquinonate ligands

CG Pierpont

COORDINATION CHEMISTRY REVIEWS (2001)

添加到收藏夹

Review Chemistry, Multidisciplinary

Stable silylenes

M Haaf et al.

ACCOUNTS OF CHEMICAL RESEARCH (2000)

添加到收藏夹

Article Chemistry, Physical

COSMO Implementation in TURBOMOLE: Extension of an efficient quantum chemical code towards liquid systems

A Schafer et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2000)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.