期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 61, 期 40, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202208660
关键词
Atmospheric Water Harvesting; Crystal Growth; Crystalline Porous Organic Salts; Multistep Sorption
资金
- National Key R&D Program of China [2021YFA1200400]
- National Natural Science Foundation of China [91956108, 21871103]
- Natural Science Foundation of Zhejiang Province [LZ22B010001]
In this study, a new crystalline porous organic salt material (CPOS-6) possessing a dual hydrogen bond system was synthesized and its applicability in atmospheric water harvesting (AWH) was verified for the first time. Unlike other reported CPOSs, CPOS-6 exhibits an S-shaped water sorption isotherm due to the presence of the dual hydrogen bond system. Under simulated drought conditions in Xinjiang Uygur Autonomous Region, CPOS-6 demonstrates long-term water adsorption-desorption cycling stability, low water desorption temperature, and ultrarapid adsorption-desorption kinetics. The results confirm that CPOS-6 is an effective sorbent material for AWH.
In recent years, the porous sorbent-assisted atmospheric water harvesting (AWH) method has emerged as an effective approach for solving water crises without geographical restrictions. However, there is a limited array of porous adsorbent materials that can be used for AWH, which are inadequate to meet the needs under different climatic conditions. In light of this, herein, we synthesize a new crystalline porous organic salt (CPOS; denoted as CPOS-6) possessing a dual hydrogen bond system and verify its applicability toward AWH for the first time. Unlike other reported CPOSs, CPOS-6 displays an S-shaped water sorption isotherm owing to the presence of the dual hydrogen bond system. Under simulated drought conditions in Xinjiang Uygur Autonomous Region, CPOS-6 exhibits long-term water adsorption-desorption cycling stability, low water desorption temperature, and ultrarapid adsorption-desorption kinetics. The results confirm that CPOS-6 is an effective sorbent material for AWH.
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