期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 61, 期 48, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202212473
关键词
Catalytic Machinery; Double Catalysis; Kinetics; Multicomponent Device; Synchronized Motion
资金
- Deutsche Forschungsgemeinschaft [SCHM 647/22-1, 491092614]
- University of Siegen
The heteroleptic multi-component double slider-on-deck system DS3 demonstrates a tight coupling of the motional speed of two distinct nano-circular sliders, despite a 2.2 nm separation. Synchronization of the motions in DS3 remains even when the faster slider is slowed down using small molecular brake pads. In contrast to the individual DS1 and DS2 systems, DS3 utilizes the motion of both sliders to drive two catalytic processes.
The heteroleptic multi-component double slider-on-deck system DS3 exhibits tight coupling of motional speed of two distinct nano-circular sliders (k(298)=77 and 41 kHz) despite a 2.2 nm separation. In comparison, the single sliders in DS1 and DS2 move at vastly different speed (k(298)=1.1 vs. 350 kHz). Synchronization of the motions in DS3 remains even when one slows the movement of the faster slider using small molecular brake pads. In contrast to the individual DS1 and DS2 systems, DS3 is a powerful catalyst for a two-step reaction by using the motion of both sliders to drive two catalytic processes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据