期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 61, 期 47, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202209882
关键词
Arylthianthrenium Salts; Bromoarylation of Alkenes; Late-Stage Functionalization; Meerwein Arylation
资金
- MPI fur Kohlenforschung
- Max-Planck-Society
- Projekt DEAL
This study presents a photocatalyzed Meerwein-type bromoarylation of alkenes using stable arylthianthrenium salts, which are formed through site-selective C-H thianthrenation. This method allows for late-stage functionalization of biomolecules that are typically inaccessible with other aryl coupling reagents.
Herein, we report a photocatalyzed Meerwein-type bromoarylation of alkenes with stable arylthianthrenium salts, formed by site-selective C-H thianthrenation. This protocol can be applied to late-stage functionalization of a variety of biomolecules that are difficult to access by other aryl coupling reagents. Halogen introduction allows for a variety of follow-up transformations, affording numerous biologically active skeletons.
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