Skillfully grafted C-O functional group to enhance the adsorption/photocatalytic mechanism of YMnO3/MgAl2O4 heterojunction photocatalysts

The YMnO3 with different manganese salts includes MnSO4 center dot H2O, MnCO3 and C4H6MnO4.4H(2)O and YMnO3/MgAl2O4 heterojunction photocatalysts (YMO/MAO) with different mass percentage of MgAl2O4 were synthesized by a simple wet chemistry method combined with low temperature sintering technology. The effects of manganese salts on the structure, functional groups, morphology, charge states and optical properties of YMnO3 phase were studied in detail. The pure YMnO3 with the uniformity of particles can be obtained when only C4H6MnO4 center dot 4H(2)O is used as manganese source. The results confirmed that the YMO/MAO heterojunction was constructed by one step low-temperature sintering technique. The YMnO3/wt 10 % MgAl2O4 photocatalyst exhibits high optical absorption coefficient and highest adsorption capacity of 122.86 mg/g and degradation percentage of 98.98 % for the degradation of Congo red (CR), 86.16 % for the degradation of tetracycline hydrochloride (TC) and 72.51 % for the degradation of tetrabromo bisphenol A (TBBPA). The hydroxyl and superoxide radicals dominated the photo -catalytic reaction process of YMO/MAO for the degradation of CR, TC and TBBPA. The present work pioneers the potential application of YMO/MAO grafted by C-O functional group as dyes, antibiotics and persistent organic pollutants (POPS) adsorption / degradation catalyst and further provides technical reference for the synthesis of others heterojunction photocatalysts. (C) 2022 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.

Automated summary

YMnO3 with different manganese salts were synthesized, and the effects of manganese salts on the structure and properties of YMnO3 were studied. Pure YMnO3 with uniform particles was obtained using C4H6MnO4·4H2O as the manganese source. The YMnO3/MgAl2O4 photocatalyst with 10% MgAl2O4 exhibited high optical absorption coefficient and degradation efficiency for various pollutants. Hydroxyl and superoxide radicals played a dominant role in the photocatalytic degradation process. This study explores the potential application of YMO/MAO as adsorption/degradation catalysts for dyes, antibiotics, and persistent organic pollutants, providing technical reference for the synthesis of other heterojunction photocatalysts.