4.8 Review

Recent Advances in Luminescent Hydrogen-Bonded Organic Frameworks: Structures, Photophysical Properties, Applications

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Article Chemistry, Multidisciplinary

Achieving Bright Mechanoluminescence in a Hydrogen-Bonded Organic Framework by Polar Molecular Rotor Incorporation

Qiuyi Huang et al.

Summary: This study reports a flexible HOF with mechanoluminescence (ML) property, which is assembled from polar molecular rotors with aggregation-induced emission. Reversible structural transformations between ML-active and -inactive frameworks can be observed when responding to different solvent vapors. This work provides insights into the gas response properties of HOFs containing fluorinated compounds.

CCS CHEMISTRY (2022)

Article Chemistry, Physical

Framework-Shrinkage-Induced Wavelength-Switchable Lasing from a Single Hydrogen-Bonded Organic Framework Microcrystal

Yuanchao Lv et al.

Summary: By constructing a flexible HOF with reversible framework shrinkage, in situ wavelength-switchable lasing was achieved based on distinct energy-level structures with blue/green-color gain emissions. This approach offers a new insight into the use of flexible HOFs for exploiting miniaturized lasers with on-demand nanophotonics performance.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2022)

Review Chemistry, Multidisciplinary

Luminescent Covalent Organic Frameworks for Biosensing and Bioimaging Applications

Jianxin Ma et al.

Summary: Luminescent covalent organic frameworks (LCOFs) have garnered significant attention for their tunable structures and photophysical properties at the molecular level. They offer advantages such as predesigned structure properties, unique photoluminescence, low toxicity, good biocompatibility, and tumor penetration, expanding their applications in biosensing and bioimaging. The key role of chemical linkages in the synthetic chemistry of LCOFs affects their optical properties and potential sensing applications, while structure management determines their brightness and potential applications in biosensing and bioimaging. Challenges and opportunities in LCOFs development are discussed in terms of their current progress in chemistry, physics, and applications.
Article Materials Science, Multidisciplinary

Dual-emission ratiometric fluorescent probe-based lanthanide-functionalized hydrogen-bonded organic framework for the visual detection of methylamine

Yanhong Liu et al.

Summary: A Eu3+-functionalized hydrogen-bonded organic framework (HOF) named Eu@Tt-TPA was developed for ratiometric fluorescence detection of methylamine (MA) with high sensitivity and selectivity. The dual emission property of the material enables visual ratio detection of MA in aqueous solution and solidified into a hydrogel sensor for distinct color change response to MA vapor concentration, suitable for wastewater treatment applications.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

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Robust Mesoporous Functional Hydrogen-Bonded Organic Framework for Hypochlorite Detection

Zu-Jin Lin et al.

Summary: A novel stable mesoporous HOF with a high density of hydroxy moieties (HOF-FAFU-1) was designed and synthesized, which could be used as a fluorescent sensor for hypochlorite detection in water media.

ACS APPLIED MATERIALS & INTERFACES (2022)

Article Nanoscience & Nanotechnology

Tunable Fluorescence in Two-Component Hydrogen-Bonded Organic Frameworks Based on Energy Transfer

Qiao Chen et al.

Summary: A dumbbell-shaped compound was found to form hydrogen-bonded organic frameworks with strong cyan fluorescence. Nonradiative energy transfer between two molecules with the same molecular skeleton was observed within the framework, and the emission wavelengths and colors could be continuously modulated by adjusting the content of the acceptor.

ACS APPLIED MATERIALS & INTERFACES (2022)

Article Materials Science, Multidisciplinary

Base-Tuning HOF-Based Host-Guest Ultralong Organic Phosphorescence Systems with Phosphorescent Thermochromism Using for Information Security and Thermometer

Xin Xu et al.

Summary: Hydrogen-bonded organic framework-based host-guest ultralong organic phosphorescence (HOF-based HGUOP) materials with phosphorescent thermochromism property have been successfully prepared and their thermochromism mechanism has been explored. Among them, one co-crystal material shows efficient photoluminescence and phosphorescence effects, demonstrating promising applications. Furthermore, these materials can be used for information security and phosphorescent thermometer.

ADVANCED OPTICAL MATERIALS (2022)

Article Materials Science, Multidisciplinary

Eu(III)-Functionalized HOFs based on machine learning-assisted fluorescence sensing: discrimination of quinolones via PCA and BPNN models

Kai Zhu et al.

Summary: By manufacturing a functionalized hydrogen-bonded organic framework and analyzing the fluorescence response patterns, the precise distinction of eight different QNs has been achieved, and measuring QN concentration with deep learning technology has been realized.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

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An anthracene-based hydrogen-bonded organic framework as a bifunctional fluorescent sensor for the detection of γ-aminobutyric acid and nitrofurazone

Yanhong Liu et al.

Summary: This study successfully prepared HOF-DBA with good luminescence properties and used it as a sensor to quantitatively identify the concentrations of nitrofurazone and gamma-aminobutyric acid (GABA). A back-propagation neural network (BPNN) model based on HOF-DBA and GABA was also constructed for intelligent fluorescence detection of GABA.

INORGANIC CHEMISTRY FRONTIERS (2022)

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Multidimensional Structure Conformation of Persulfurated Benzene for Highly Efficient Phosphorescence

Hongwei Wu et al.

Summary: Enhancing phosphorescence efficiency can be achieved by modifying molecular conformation and crystal growth conditions, with symmetric 3,3 conformers showing higher efficiency compared to unsymmetrical 2,4 conformers. The crystal protection effect and conformation impact play crucial roles in the phosphorescence performance of the molecules.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Multidisciplinary

Robust Biological Hydrogen-Bonded Organic Framework with Post-Functionalized Rhenium(I) Sites for Efficient Heterogeneous Visible-Light-Driven CO2 Reduction

Baoqiu Yu et al.

Summary: A robust biological hydrogen-bonded framework (HOF-25) derived from 2,2'-bipyridine (bpy) was utilized to covalently attach Re(bpy)(CO)(3)Cl segments, showing good heterogeneous catalytic activity for carbon dioxide photoreduction with high CO production rate and selectivity.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Robust Supramolecular Nano-Tunnels Built from Molecular Bricks**

Peifa Wei et al.

Summary: The linear ionic molecule reported in this study assembles into a supramolecular nano-tunnel structure through ionic and pi-pi stacking interactions, exhibiting anisotropic guest adsorption behavior. The material shows good thermal and chemical stability, undergoes phase transformations, and displays high CO2/CH4 selectivity. Additionally, the bulk crystals have vapochromic properties due to aggregation-induced emission.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Physical

Hot-electron leading-out strategy for constructing photostable HOF catalysts with outstanding H2 evolution activity

Nan Zhang et al.

Summary: By introducing Pt nanoparticles as electron sinks into high crystalline nano-HOFs, this study successfully improved the photochemical stability of HOFs and demonstrated the synthesis of Pt@nano-HOF with high hydrogen evolution activity. The optimized hot-electron transfer also led to efficient hydrogen evolution rates, highlighting a new insight for enhancing the stability of catalysts.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Multidisciplinary

Wide-Gap 1D-, 2D-, and 3D-Hydrogen-Bonded Organic Frameworks Hierarchically Weaved by Macrocyclic Supramolecular Multifluorine Tectons

Bai Chen et al.

Summary: A series of 1D-, 2D-, and 3D-hydrogen-bonded organic frameworks, driven by macrocyclic multifluorine tectons, were constructed based on burgeoning multifluorinated diaminoterephthalates. Different crystalline structures exhibited ladder-shaped 1D-HOFs, layer-by-layer translational 2D-HOFs, and 2-fold interpenetrated 3D-HOFs, showing a trend of deeper HOMO/LUMO energy levels with more F atoms. Additionally, the multifluorination effect caused optical blue shifts and wide optical energy gaps in solution.

CRYSTAL GROWTH & DESIGN (2021)

Review Materials Science, Multidisciplinary

Luminescent Metal-Organic Frameworks for White LEDs

Ying Tang et al.

Summary: The review focuses on the design strategies of achieving high-performance phosphors using MOFs, highlighting the doping of luminescent lanthanide ions, organic ligands, and diverse luminescent guest species. The representative advances in the development of MOF phosphors are presented, offering guidance and reference for future research in this field.

ADVANCED OPTICAL MATERIALS (2021)

Review Chemistry, Multidisciplinary

Applications of MOFs as Luminescent Sensors for Environmental Pollutants

Guo-Li Yang et al.

Summary: Environmental pollution poses serious health risks and requires the urgent detection of pollutants for protection. Luminescent metal-organic frameworks (LMOFs) with tunable structures have shown excellent performance as sensors for detecting various environmental pollutants.
Article Chemistry, Multidisciplinary

Dual-functional hydrogen-bonded organic frameworks for aniline and ultraviolet sensitive detection

Zhijun Ke et al.

Summary: FJU-200, a novel hydrogen-bonded organic framework, has dual functions for aniline and ultraviolet detection with a low detection limit. It undergoes color changes under ultraviolet light, allowing for minute-level detection, and test papers prepared from FJU-200 enable convenient and fast detection for aniline or ultraviolet light.

CHINESE CHEMICAL LETTERS (2021)

Article Chemistry, Multidisciplinary

A Permanent Porous Hydrogen-Bonded Framework with Room-Temperature Phosphorescence

Hui Xiao et al.

Summary: In this study, a pure organic phosphor BPMCz was utilized as a building block to construct HOF materials, displaying high CO2 adsorption and room-temperature phosphorescence with good thermal stability. The introduction of carbonyl groups in BPMCz successfully enabled the construction of a metal-free porous framework with long-lived phosphorescence emission, expanding the scope of organic room-temperature phosphorescent materials and their applications.

CRYSTAL GROWTH & DESIGN (2021)

Article Chemistry, Multidisciplinary

Dynamic molecular weaving in a two-dimensional hydrogen-bonded organic framework

Qiuyi Huang et al.

Summary: The article reports a molecular woven structure of an organic framework with permanent porosity. This structure demonstrates exceptional dynamics in response to different gases and exhibits large-scale elasticity switching and multimode stimuli-responsive luminescence behaviors during reversible structural transformations.
Article Nanoscience & Nanotechnology

Hydrogen-Bonded Organic Framework Microlasers with Conformation-Induced Color-Tunable Output

Yuanchao Lv et al.

Summary: Two types of HOF microcrystals were synthesized with the same gain lumogen as the building block using a temperature-controlled self-assembly method, leading to blue and green emission colors. These results offer a deep insight into the exploitation of HOF-based miniaturized lasers with desired nanophotonics performances.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Nanoscience & Nanotechnology

Guest-Regulated Luminescence and Force-Stimuli Response of a Hydrogen-Bonded Organic Framework

Yanning Han et al.

Summary: Guest molecules can regulate the luminescence properties of porous materials and trigger responses to force stimuli. In this study, acetic acid as a guest was found to induce longer emission wavelengths in the material and trigger mechanical force response.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Multidisciplinary

Facile Fabrication of Luminescent Eu(III) Functionalized HOF Hydrogel Film with Multifunctionailities: Quinolones Fluorescent Sensor and Anticounterfeiting Platform

Xin Xu et al.

Summary: This study successfully fabricated a multifunctional dual-emitting Eu3+-functionalized HOF hydrogel film, which shows high selectivity and sensitivity towards ofloxacin and flumequine drugs. By investigating the fluorescent response mechanisms in depth, a high-level security anticounterfeiting platform was developed.

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Article Chemistry, Multidisciplinary

A Single-Component Supramolecular Organic Framework with Efficient Ultralong Phosphorescence

Lulu Song et al.

Summary: The newly reported organic compound DCzPO forms a SOF structure with ultralong phosphorescence, exhibiting high phosphorescence efficiency and extended emission lifetime. This single-component SOF provides a new research platform for the rational combination of UOP and porous materials.

CCS CHEMISTRY (2021)

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Fluorescent Supramolecular Organic Frameworks Constructed by Amidinium-Carboxylate Salt Bridges

Hongqin Jiang et al.

Summary: Fluorescent supramolecular organic frameworks (SOFs) incorporating aggregation-induced emission (AIE) units were constructed by linking tetraphenylethylene (TPE)-based tetra(amidinium) cation TPE4+ and aromatic dicarboxylate anions. The structures displayed fluorescence quantum yields in the range of 4.6% to 14%, attributed to electrostatic interactions and hydrogen bonds. All prepared SOFs exhibited emissive features characteristic of TPE-based AIE luminogens with little dependence on specific structural details.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Ethylene/ethane separation in a stable hydrogen-bonded organic framework through a gating mechanism

Yisi Yang et al.

Summary: Porous materials show great potential for cost- and energy-efficient separation processes, with a microporous hydrogen-bonded organic framework demonstrated to have good ethylene selectivity over ethane through a gating mechanism. The material exhibited stable performance under harsh conditions and validated high purity ethylene separation through breakthrough experiments.

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An electrodeposited nano-porous and neural network-like Ln@HOF film for SO2 gas quantitative detection via fluorescent sensing and machine learning

Xin Xu et al.

Summary: A nano-porous and neural network-like Tb3+-functionalized HOF film has been successfully manufactured for intelligent fluorescence detection of SO2 gas, which can quantitatively distinguish SO2 concentration and is combined with deep machine learning for accurate discrimination.

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Yuto Suzuki et al.

Summary: The study presents a rule-of-thumb for developing isostructural hydrogen-bonded organic frameworks by considering three important structural factors. The construction and characterization of new HOFs are demonstrated, and their properties are compared with other isostructural frameworks. Molecular dynamics simulation is shown to be effective in evaluating the stability of isostructural HOFs, which can accelerate the development of various molecular porous materials.

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