期刊
ADVANCED FUNCTIONAL MATERIALS
卷 33, 期 1, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202209837
关键词
gel polymer electrolytes; Li dendrites; Li metal batteries; Li; (+) ions transport; multiscale structures
A novel gel polymer electrolyte is fabricated to enhance the performance of Li metal batteries by accelerating Li+ ions transport and suppressing Li dendrite growth. The designed electrolyte achieves high capacity retention in carbonate electrolyte.
Li metal batteries (LMBs) are considered as promising candidates for future rechargeable batteries with high energy density. However, Li metal anode (LMA) is extensively sensitive to general liquid electrolytes, leading to unstable interphase and dendrites growth. Herein, a novel gel polymer electrolyte consisting of a micro-nanostructured poly(vinylidene fluoride-co-hexafluoropropylene) matrix and inorganic fillers of Zeolite Socony Mobil-5 (ZSM-5) and SiO2 nanoparticles, is fabricated to expedite Li+ ions transport and suppress Li dendrite growth. Due to the Lewis acid interaction, SiO2 can absorb amounts of PF6- and promote the dissociation of LiPF6. The specific sub-nanometer pore structure of ZSM-5 greatly enhances the Li+ ion transference number. These structures can restrain the decomposition of electrolytes and build stable interphase on LMA. Therefore, the Li||Ni0.8Co0.1Mn0.1O2 full cell maintains 92% capacity retention after 300 cycles at 1 C (1 C approximate to 190 mAh g(-1)) in carbonate electrolyte. This multiscale design provides an effective strategy for electrolyte exploration in high-performance LMBs.
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