☆ 4.8 Review

Turning Waste into Wealth: Sustainable Production of High-Value-Added Chemicals from Catalytic Coupling of Carbon Dioxide and Nitrogenous Small Molecules

ACS NANO (2022)

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Article Chemistry, Multidisciplinary

Interfacial Microextraction Boosting Nitrogen Feed for Efficient Ambient Ammonia Synthesis in Aqueous Electrolyte

Xiaowei Shen et al.

Summary: This study reports an N-2 microextractor (NME) that can extract N-2 from water and supply it to catalysts on electrodes. By enhancing the supply of N-2 in the NRR process, the NME achieves efficient electrocatalytic N-2 reduction, which is of great significance to the sustainable development of the Ammonia Economy.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Solar Urea: Towards a Sustainable Fertilizer Industry

Meikun Xia et al.

Summary: This research presents an eco-friendly method for synthesizing urea from CO2 and NH3 using solar energy at room temperature, demonstrating the potential for utilizing solar energy in urea production and providing new insights for sustainable, modular plants for distributed urea production on farms.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Chemistry, Multidisciplinary

Double metal synergistic synthetic urea: an electrocatalytic study

Zhijia Zhang et al.

Summary: This paper focuses on the synthesis of urea under the synergistic effects of bimetallics in electrocatalysis. Heteronuclear diatomic molecular catalysts were designed and screened, and theoretical simulation provided detailed information about reaction mechanisms and energy. The NbVN6C catalyst was found to be the best catalyst, and heteronuclear diatomic molecular catalysts were demonstrated to be superior to homonuclear diatomic catalysts.

NEW JOURNAL OF CHEMISTRY (2022)

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Article Chemistry, Multidisciplinary

Non-metal boron atoms on a CuB12 monolayer as efficient catalytic sites for urea production

Changyan Zhu et al.

Summary: This study identified a highly stable global-minimum CuB12 monolayer as a promising non-metal catalytic site for urea production through first-principles computations. The research systematically investigated various reaction pathways and highlighted the significant role of non-metal B atoms as excellent catalytic sites in the formation of urea.

CHEMICAL SCIENCE (2022)

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Review Chemistry, Physical

Interfacial Electrolyte Effects on Electrocatalytic CO2 Reduction

Bangwei Deng et al.

Summary: This review focuses on discussing the role and effects of electrolytes on CO2RR, including their compositions and local chemical environment. In-depth investigations on the detection of intermediates during the catalytic reactions are also included. The fundamental understanding of interfacial electrolyte effects is emphasized for maximizing and balancing the catalytic performance of CO2RR.

ACS CATALYSIS (2022)

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Letter Chemistry, Applied

Cascade electrocatalytic reduction of carbon dioxide and nitrate to ethylamine

Zixu Tao et al.

JOURNAL OF ENERGY CHEMISTRY (2022)

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Article Chemistry, Physical

Direct Electrosynthesis of Urea from Carbon Dioxide and Nitric Oxide

Yanmei Huang et al.

Summary: Electrochemical synthesis of urea is a sustainable strategy that utilizes abundant and low-cost inorganic carbon and nitrogen sources through advanced electrocatalytic processes to achieve efficient urea generation.

ACS ENERGY LETTERS (2022)

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Article Chemistry, Multidisciplinary

A Defect Engineered Electrocatalyst that Promotes High-Efficiency Urea Synthesis under Ambient Conditions

Chade Lv et al.

Summary: Indium oxyhydroxide electrocatalyst with defect engineering has been developed for efficient synthesis of urea. By studying the catalytic mechanism, this design strategy may lead to the exploration of advanced catalysts for electrochemical urea synthesis and other sustainable applications.

ACS NANO (2022)

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Article Chemistry, Multidisciplinary

Understanding the Site-Selective Electrocatalytic Co-Reduction Mechanism for Green Urea Synthesis Using Copper Phthalocyanine Nanotubes

Jit Mukherjee et al.

Summary: This study reports the green synthesis of urea under ambient conditions by electrochemical co-reduction of N-2 and CO2 gases using copper phthalocyanine nanotubes (CuPc NTs) as an efficient electrocatalyst. The CuPc NTs have multiple active sites that can effectively reduce N-2 and CO2 gas molecules to urea. The findings provide new mechanistic insight for the development of efficient noble metal-free electrocatalysts for the synthesis of green urea.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Review Environmental Sciences

A review on sensing and catalytic activity of nano-catalyst for synthesis of one-step ammonia and urea: Challenges and perspectives

Saima Qureshi et al.

Summary: This article briefly discusses the development of ammonia synthesis and the latest advances in nanocatalyst development. New ammonia synthesis catalysts of different morphology and magnetic nanoparticles and nanowires show promise in replacing conventional catalysts and may serve as the basis for future green ammonia and urea synthesis processes.

CHEMOSPHERE (2022)

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Review Chemistry, Multidisciplinary

Construction of C-N bonds from small-molecule precursors through heterogeneous electrocatalysis

Junnan Li et al.

Summary: Energy-intensive thermochemical processes in chemical manufacturing contribute significantly to global CO2 emissions. To achieve sustainability, scientists are developing renewable energy-powered electrochemical technologies as alternatives. This review focuses on the emerging area of heterogeneous electrocatalysis for C-N bond formation.

NATURE REVIEWS CHEMISTRY (2022)

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Article Chemistry, Multidisciplinary

Oxygen Vacancy-Mediated Selective C-N Coupling toward Electrocatalytic Urea Synthesis

Xiaoxiao Wei et al.

Summary: This study proposes a new method for synthesizing urea at ambient conditions, which improves the efficiency of the C-N coupling reaction by stabilizing the crucial intermediate through the insertion of oxygen vacancies. The existence of oxygen vacancy-mediated selective C-N coupling reaction is verified through in situ spectroscopy techniques. The introduction of oxygen vacancies transforms the common catalyst carrier into an efficient electrocatalyst, with a higher urea yield rate compared to partial noble-metal-based electrocatalysts.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

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Article Chemistry, Physical

Tuning the Coordination Structure of Cu-N-C Single Atom Catalysts for Simultaneous Electrochemical Reduction of CO2 and NO3- to Urea

Josh Leverett et al.

Summary: Closing the carbon and nitrogen loops is crucial for establishing a circular economy with zero carbon emissions. Copper single atom catalysts have shown high activity in electrochemical reduction reactions of carbon dioxide and nitrate, making them suitable for urea synthesis.

ADVANCED ENERGY MATERIALS (2022)

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Review Chemistry, Multidisciplinary

Advancing the Electrochemistry of Gas-Involved Reactions through Theoretical Calculations and Simulations from Microscopic to Macroscopic

Yanzheng He et al.

Summary: This paper reviews the progress and application of density functional theory (DFT), molecular dynamics (MD) simulations, and finite element simulation (FES) in gas-involved electrochemical reactions. It emphasizes the significance of theoretical calculations and simulations in understanding reaction mechanisms, establishing composition-structure-activity relationships, and predicting prospective electrocatalysts and systems. The paper also highlights notable work in utilizing DFT, MD, and FES to investigate catalyst properties and restore reaction systems from different temporal and spatial scales.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Article Chemistry, Physical

Carbon nanotubes with fluorine-rich surface as metal-free electrocatalyst for effective synthesis of urea from nitrate and CO2

Xiaowen Liu et al.

Summary: In this study, carbon nanotubes with fluorine-rich surface were developed as advanced metal-free catalysts for the electrocatalytic synthesis of urea via co-activation of CO2 and NO3-. The formation of *CO and *NH2 intermediates on F-doped C active sites (C-F2 moieties) was found to facilitate the CN coupling reaction for urea formation.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

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Article Engineering, Environmental

Distorted spinel ferrite heterostructure triggered by alkaline earth metal substitution facilitates nitrogen localization and electrocatalytic reduction to ammonia

Yuzhuo Jiang et al.

Summary: In this study, a distorted spinel ferrite heterostructure was designed to achieve efficient electrocatalytic nitrogen reduction reaction (NRR). By optimizing the structural/electronic configurations, the activity and selectivity of NRR were greatly enhanced, leading to outstanding NRR performance.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Chemistry, Physical

Artificial frustrated Lewis pairs facilitating the electrochemical N2 and CO2 conversion to urea

Menglei Yuan et al.

Summary: Frustrated Lewis pairs (FLPs) coupled with rice-like InOOH nanoparticles provide a new strategy for urea electrosynthesis by achieving targeted chemisorption of N-2 and CO2 through electronic interaction, generating intermediates for urea synthesis.

CHEM CATALYSIS (2022)

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Article Chemistry, Multidisciplinary

AuCu nanofibers for electrosynthesis of urea from carbon dioxide and nitrite

Songliang Liu et al.

Summary: This study reports self-assembled nanofibers that can couple CO2RR with NO2-RR to electrosynthesize urea. The rich structural defects and AuCu bimetallic composition provide highly catalytically active sites, and the constructed AuCu nanofibers display excellent urea synthesis performance.

CELL REPORTS PHYSICAL SCIENCE (2022)

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Article Chemistry, Multidisciplinary

Host-guest molecular interaction promoted urea electrosynthesis over a precisely designed conductive metal-organic framework

Menglei Yuan et al.

Summary: Through the design of a novel conductive metal-organic framework, the highly selective electrocatalytic activation of N-2 and CO2 to synthesize urea has been achieved, demonstrating record-high urea yield rate and high selectivity.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

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Article Chemistry, Multidisciplinary

Electrochemically driven C-N bond formation from CO2 and ammonia at the triple-phase boundary

Junnan Li et al.

Summary: This study developed a synthetic scheme that couples CO2 and NH3 at a gas-liquid-solid boundary to produce species with C-N bonds. By using electrochemical analysis and operando spectroelectrochemical method, the reaction pathways and limitations of the current system were analyzed.

CHEMICAL SCIENCE (2022)

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Article Multidisciplinary Sciences

Altering the rate-determining step over cobalt single clusters leading to highly efficient ammonia synthesis

Sisi Liu et al.

Summary: This study successfully altered the rate-determining step of ammonia synthesis by introducing cobalt single clusters into the catalyst, overcoming the energy barrier of N-2 dissociation, and achieving high ammonia yield rate and superior Faradaic efficiency.

NATIONAL SCIENCE REVIEW (2021)

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Article Nanoscience & Nanotechnology

An industrial perspective on catalysts for low-temperature CO2 electrolysis

Richard I. Masel et al.

Summary: This Perspective discusses the key advances in nanocatalysts that have led to significant progress in the electrochemical conversion of CO2 to useful products, providing benchmarks for comparison and highlighting the need for further research.

NATURE NANOTECHNOLOGY (2021)

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Article Chemistry, Multidisciplinary

Unveiling Electrochemical Urea Synthesis by Co-Activation of CO2 and N2 with Mott-Schottky Heterostructure Catalysts

Menglei Yuan et al.

Summary: The novel Mott-Schottky Bi-BiVO4 heterostructures exhibit remarkable urea yield rate and Faradaic efficiency by facilitating targeted activation of CO2 and N-2 molecules, effectively suppressing CO poisoning and endothermic intermediates, ensuring the desired exothermic coupling reaction.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

Dual-Silicon-Doped Graphitic Carbon Nitride Sheet: An Efficient Metal-Free Electrocatalyst for Urea Synthesis

Prodyut Roy et al.

Summary: This study presents a novel non-metal catalyst for direct urea synthesis, which can efficiently promote the reaction process with lower onset potential and higher faradaic efficiency, leading to the suppression of ammonia synthesis and exclusive electrocatalytic urea production.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2021)

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Article Chemistry, Multidisciplinary

Accessing Organonitrogen Compounds via C-N Coupling in Electrocatalytic CO2 Reduction

Zixu Tao et al.

Summary: This research aims to broaden the product scope of electrocatalytic CO2 reduction reactions by introducing additional reactants containing inorganic heteroatoms, enabling the sustainable synthesis of valuable products such as organonitrogen compounds.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Review Chemistry, Multidisciplinary

Architectural Design for Enhanced C2 Product Selectivity in Electrochemical CO2 Reduction Using Cu-Based Catalysts: A Review

Changlong Xiao et al.

Summary: Electrochemical conversion of CO2 to value-added chemicals and fuels using Cu catalysts has shown promising potential, but poor product selectivity remains a major technical challenge for global applications. Tailoring the electrocatalyst architecture through nanotechnology principles can significantly impact the adsorption energetics of key intermediates and reaction pathways.

ACS NANO (2021)

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Article Chemistry, Multidisciplinary

Reversed Charge Transfer and Enhanced Hydrogen Spillover in Platinum Nanoclusters Anchored on Titanium Oxide with Rich Oxygen Vacancies Boost Hydrogen Evolution Reaction

Zhen-Wei Wei et al.

Summary: The study demonstrates that Pt nanoclusters supported on porous TiO2 nanosheets with rich oxygen vacancies exhibit significantly higher catalytic activity for the HER compared to those supported on TiO2 with deficient oxygen vacancies. This is attributed to the ability of the TiO2 support with rich oxygen vacancies to facilitate reversed charge transfer and enhanced hydrogen spillover, promoting proton reduction and hydrogen desorption at Pt catalytic sites. This work provides a new strategy for the rational design of highly efficient HER catalysts.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

Methanol-Mediated Electrosynthesis of Ammonia

Yongwen Ren et al.

Summary: This study demonstrates an innovative alcohol-water electrolyte system to modulate local proton concentration and the microenvironment at the electrode-electrolyte interface, boosting the selectivity of NRR. The methanol-enabled electrolyte shows record high NRR FE and ammonia yield rate, with significant enhancements compared to conventional aqueous electrolytes.

ACS ENERGY LETTERS (2021)

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Article Chemistry, Multidisciplinary

Photocatalytic Synthesis of Urea (CO2/N2/H2O) on Coal-Based Carbon Nanotubes with the Fe-Core-Supported Ti3+-TiO2 Composite Catalyst

Halidan Maimaiti et al.

Summary: In this study, Fe-core carbon nanotubes (Fe-CNTs) were prepared using raw coal as a carbon source, and Ti3+ doped TiO2 (Ti3+-TiO2) was loaded onto Fe-CNTs to form Ti3+-TiO2/Fe-CNTs. The photocatalytic co-reduction of N-2/CO2 in H2O was performed, with results showing that the performance was related to the arrangement of Ti3+ sites and oxygen vacancies on the Ti3+-TiO2 surface. The composite catalyst showed significantly increased CO(NH2)2 yield compared to single Ti3+-TiO2, indicating the beneficial role of Fe-CNT support in the photocatalysis.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

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Article Chemistry, Physical

Proton-filtering covalent organic frameworks with superior nitrogen penetration flux promote ambient ammonia synthesis

Sisi Liu et al.

Summary: By controlling the diffusion of reactants and using proton-filtering covalent organic frameworks, a highly selective and active nitrogen reduction was achieved in electrochemical ammonia synthesis. This strategy optimizes mass transfer and provides guidelines for practical green ammonia production.

NATURE CATALYSIS (2021)

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Article Green & Sustainable Science & Technology

Direct electrosynthesis of methylamine from carbon dioxide and nitrate

Yueshen Wu et al.

Summary: This study presents a new method for converting carbon dioxide and nitrate into methylamine through electrochemical reactions, contributing to a carbon-neutral future. The technology offers a sustainable pathway to produce value-added fuels and chemicals.

NATURE SUSTAINABILITY (2021)

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Article Chemistry, Multidisciplinary

Electrochemical Synthesis of Glycine from Oxalic Acid and Nitrate

Jeong Eun Kim et al.

Summary: This study developed an electrochemical method to synthesize C-N bond-containing molecules by utilizing nitrate and oxalic acid as nitrogen and carbon sources, respectively, avoiding the use of cyanides and amines. Through carefully controlling the multireduction process of anthropogenic CO2 and nitrate wastes, efficient production of glycine was demonstrated with a high faradaic efficiency.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Multidisciplinary Sciences

Electrochemical synthesis of urea on MBenes

Xiaorong Zhu et al.

Summary: The study systematically investigates the catalytic activity of three experimental two-dimensional metal borides (MBenes) for urea synthesis, demonstrating the potential of Mo2B2 and Cr2B2 as effective electrocatalysts for urea production.

NATURE COMMUNICATIONS (2021)

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Article Multidisciplinary Sciences

Salting-out effect promoting highly efficient ambient ammonia synthesis

Mengfan Wang et al.

Summary: The electroreduction of nitrogen to ammonia offers a promising alternative to the energy-intensive Haber-Bosch process but suffers from low activity and selectivity. Here, authors demonstrate that triggering a salting-out effect in a highly concentrated electrolyte can achieve highly efficient ammonia synthesis.

NATURE COMMUNICATIONS (2021)

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Review Chemistry, Physical

Electrocatalytic nitrate/nitrite reduction to ammonia synthesis using metal nanocatalysts and bio-inspired metalloenzymes

Jing Wang et al.

Summary: Ammonia (NH3) is considered a potential carbon-free energy carrier and a crucial feedstock for various industries. Electrochemical N2 reduction to NH3 has emerged as an alternative method, utilizing nitrate/nitrite as nitrogen sources to mitigate environmental concerns. Challenges remain in achieving high NH3 yield and efficiency, highlighting the need for further research into metal nanocatalysts and cycles stability.

NANO ENERGY (2021)

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Article Green & Sustainable Science & Technology

Techno-economic assessment of low-temperature carbon dioxide electrolysis

Haeun Shin et al.

Summary: This work provides a comprehensive techno-economic assessment of four major products of low-temperature CO2 electrolysis and prioritizes technological development with systematic guidelines to facilitate market deployment.

NATURE SUSTAINABILITY (2021)

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Article Green & Sustainable Science & Technology

Selective electrocatalytic synthesis of urea with nitrate and carbon dioxide

Chade Lv et al.

Summary: This study presents a more sustainable approach to directly and selectively synthesize urea using an indium hydroxide catalyst under ambient conditions.

NATURE SUSTAINABILITY (2021)

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Article Chemistry, Multidisciplinary

Highly selective electroreduction of N2 and CO2 to urea over artificial frustrated Lewis pairs

Menglei Yuan et al.

Summary: The study achieved efficient conversion of CO2 and N-2 into urea by precisely designing unique frustrated Lewis pairs in flower-like nickel borate crystals. Through the synergistic action of Lewis acidic and basic sites, inert gases were captured and activated, ultimately achieving high urea yield rates.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Review Nanoscience & Nanotechnology

Electrocatalytic C-N Coupling for Urea Synthesis

Chen Chen et al.

Summary: The development of green urea synthesis focuses on the direct urea synthesis through electrocatalytic coupling of carbon and nitrogen sources, providing a new pathway to improve resource utilization efficiency. The future direction of electrocatalytic urea synthesis should continue to optimize the synthesis mechanism to achieve higher efficiency and more environmentally friendly synthesis processes.

SMALL SCIENCE (2021)

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Article Materials Science, Multidisciplinary

Dual-Sites Tandem Catalysts for C-N Bond Formation via Electrocatalytic Coupling of CO2 and Nitrogenous Small Molecules

Jiaju Fu et al.

Summary: This perspective discusses the potential strategies and challenges of enhancing the efficiency of C-N coupling in electrocatalytic carbon dioxide reduction (ECR) by constructing heterogeneous dual-active site catalysts (DACs), providing opportunities for developing high-efficiency DACs and advancing the field of electrocatalysis.

ACS MATERIALS LETTERS (2021)

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Article Chemistry, Multidisciplinary

Confinement Strategies for Precise Synthesis of Efficient Electrocatalysts from the Macroscopic to the Atomic Level

Lu-Pan Yuan et al.

Summary: The precise control of the electrocatalyst structure and morphology is crucial for boosting their catalytic performance, which can be achieved through various confinement strategies at different scales from macroscopic to atomic level. Precursor self-confinement, nanospace confinement, and chemical binding atomic confinement are common strategies that can guide the design of efficient electrocatalysts.

ACCOUNTS OF MATERIALS RESEARCH (2021)

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Article Multidisciplinary Sciences

Methods for nitrogen activation by reduction and oxidation

Haldrian Iriawan et al.

Summary: The article introduces the importance of the industrial Haber-Bosch process for producing ammonia in modern society, discusses the challenges of N-2 activation and the drawbacks of the Haber-Bosch process, proposes new strategies for sustainable N-2 activation, compares the latest research results from different catalytic reactions, and discusses best practices for improving reproducibility and cost-effective methods for rigorous experimentation.

NATURE REVIEWS METHODS PRIMERS (2021)

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Well-defined heteronuclear bimetallic atomic clusters: Emerging electrocatalysts

Hai-Rui Pan et al.

FUNDAMENTAL RESEARCH (2021)

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Electrochemical reduction of CO2 and N2 to synthesize urea on metal-nitrogen-doped carbon catalysts: a theoretical study

Zhijia Zhang et al.

Summary: This paper focuses on the combination of utilizing carbon dioxide as a feedstock for chemical production with the natural benefits of crops brought by thunderstorms to produce urea. DFT calculations were used to investigate a series of catalysts supported on substituted corrole substrates in the form of a double transition metal, with the best catalyst being selected and further explored for its catalytic performance in urea synthesis. The study revealed the potential of a synergistic catalytic strategy with double active sites in urea synthesis, as well as in the design of other efficient molecular catalysts.

DALTON TRANSACTIONS (2021)

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Article Chemistry, Multidisciplinary

Cooperativity of Cu and Pd active sites in CuPd aerogels enhances nitrate electroreduction to ammonia

You Xu et al.

Summary: By rationally choosing Pd as an active metal and Cu as a promoting metal, Cu-rich CuPd bimetallic aerogels were developed as a self-supported electrocatalyst for nitrate electroreduction. The spongy aerogel structure provides abundant catalytically active sites, and the synergistic benefit of the CuPd binary composition increases their reactivity, aiding in efficient nitrate-to-ammonia conversion.

CHEMICAL COMMUNICATIONS (2021)

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Article Chemistry, Multidisciplinary

Electrochemical C-N coupling with perovskite hybrids toward efficient urea synthesis

Menglei Yuan et al.

Summary: The study demonstrates the efficient electrocatalytic C-N coupling reaction by using BiFeO3/BiVO4 heterojunction to synthesize urea under ambient conditions, achieving high efficiency and high Faradaic efficiency. The research shows that the local charge redistribution in the heterojunction effectively suppresses CO poisoning and the formation of the endothermic *NNH intermediate.

CHEMICAL SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Electrosynthesis of urea from nitrite and CO2 over oxygen vacancy-rich ZnO porous nanosheets

Nannan Meng et al.

Summary: Urea electrosynthesis under mild conditions has great potential to revolutionize the traditional manufacturing industry with huge energy consumption. This study demonstrates that using self-supported oxygen vacancy-rich ZnO nanosheets as catalysts for urea electrosynthesis with CO2 and nitrite as feedstocks achieves higher efficiency compared to conventional ZnO. Additionally, the research reveals a possible coupling pathway of intermediate NH2* and COOH* for urea formation.

CELL REPORTS PHYSICAL SCIENCE (2021)

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A Zn-CO2 Flow Battery Generating Electricity and Methane

Kai Wang et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Potential Link between Cu Surface and Selective CO2 Electroreduction: Perspective on Future Electrocatalyst Designs

Gracita M. Tomboc et al.

ADVANCED MATERIALS (2020)

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Nanoporous Palladium Hydride for Electrocatalytic N2 Reduction under Ambient Conditions

Wence Xu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Highly Selective Reduction of CO2 to C2+ Hydrocarbons at Copper/Polyaniline Interfaces

Xing Wei et al.

ACS CATALYSIS (2020)

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A Disquisition on the Active Sites of Heterogeneous Catalysts for Electrochemical Reduction of CO2 to Value-Added Chemicals and Fuel

Rahman Daiyan et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Physical

Cooperative CO2-to-ethanol conversion via enriched intermediates at molecule-metal catalyst interfaces

Fengwang Li et al.

NATURE CATALYSIS (2020)

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Unveiling the Essential Nature of Lewis Basicity in Thermodynamically and Dynamically Promoted Nitrogen Fixation

Mengfan Wang et al.

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Mesoporous PdAg Nanospheres for Stable Electrochemical CO2 Reduction to Formate

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Coupling N2 and CO2 in H2O to synthesize urea under ambient conditions

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Activating Copper for Electrocatalytic CO2 Reduction to Formate via Molecular Interactions

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Surfactant Perturbation of Cation Interactions at the Electrode-Electrolyte Interface in Carbon Dioxide Reduction

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Oxygen vacancies enhanced cooperative electrocatalytic reduction of carbon dioxide and nitrite ions to urea

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Te-Doped Pd Nanocrystal for Electrochemical Urea Production by Efficiently Coupling Carbon Dioxide Reduction with Nitrite Reduction

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Industrial carbon dioxide capture and utilization: state of the art and future challenges

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NATURE COMMUNICATIONS (2019)

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Over 56.55% Faradaic efficiency of ambient ammonia synthesis enabled by positively shifting the reaction potential

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JOULE (2019)

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Challenges and opportunities for adsorption-based CO2 capture from natural gas combined cycle emissions

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