Addressing Electron Spins Embedded in Metallic Graphene Nanoribbons

Spin-hosting graphene nanostructures are promising metal-free systems for elementary quantum spintronic devices. Conventionally, spins are protected from quenching by electronic band gaps, which also hinder electronic access to their quantum state. Here, we present a narrow graphene nanoribbon substitutionally doped with boron heteroatoms t h a t combines a metallic character with the presence of localized spin 1/2 states in its interior. The ribbon was fabricated by on-surface synthesis on a Au(111) substrate. Transport measurements through ribbons suspended between the tip and the sample of a scanning tunneling microscope revealed their ballistic behavior, characteristic of metallic nanowires. Conductance spectra show fingerprints of localized spin states in the form of Kondo resonances and inelastic tunneling excitations. Density functional theory rationalizes the metallic character of the graphene nanoribbon due to the partial depopulation of the valence band induced by the boron atoms. The transferred charge builds localized magnetic moments around the boron atoms. The orthogonal symmetry of the spin-hosting state's and the valence band's wave functions protects them from mixing, maintaining the spin states localized. The combination of ballistic transport and spin localization into a single graphene nanoribbon offers the perspective of electronically addressing and controlling carbon spins in real device architectures.

Automated summary

Spin-hosting graphene nanostructures offer potential for metal-free elementary quantum spintronic devices. In this study, a narrow graphene nanoribbon doped with boron heteroatoms was fabricated and exhibited metallic behavior with localized spin 1/2 states. The transport measurements and conductance spectra confirmed the presence of localized spin states in the nanoribbon. Density functional theory analysis explained the metallic character and spin localization due to the boron atoms. This research opens up possibilities for electronic addressing and controlling carbon spins in real device architectures.