期刊
PHYSICAL SCIENCES REVIEWS
卷 -, 期 -, 页码 -出版社
WALTER DE GRUYTER GMBH
DOI: 10.1515/psr-2019-0073
关键词
crystals; framework compounds; metal-organic frameworks; nets; reticular chemistry; topology
This chapter provides an overview of how framework-like crystalline compounds can be considered as nets, and how this topological approach helps to categorize and develop new framework structures.
In this chapter an overview is given in which way framework-like crystalline compounds can be regarded as nets, how a net is derived out of a particular crystal structure, what nets actually are, how they can be appropriately described, what the characteristics of nets are, and how this topological approach helps to categorize framework compounds. Finally the term reticular chemistry is explained and a number of examples are given how the topology-guided approach opens up new possibilities to intentionally develop new framework structures on a rational basis.
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