4.8 Article

A solar tower fuel plant for the thermochemical production of kerosene from H2O and CO2

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JOULE
卷 6, 期 7, 页码 1606-1616

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CELL PRESS
DOI: 10.1016/j.joule.2022.06.012

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This article reports on an experimental demonstration of producing kerosene from H2O and CO2 using concentrated solar energy, with a setup relevant to industrial implementation. This is a significant milestone towards the production of sustainable aviation fuels.
Developing solar technologies for producing carbon-neutral aviation fuels has become a global energy challenge, but their readiness level has largely been limited to laboratory-scale studies. Here, we report on the experimental demonstration of a fully integrated thermochemical production chain from H2O and CO2 to kerosene using concentrated solar energy in a solar tower configuration. The cosplitting of H2O and CO2 was performed via a ceria-based thermochemical redox cycle to produce a tailored mixture of H-2 and CO (syngas) with full selectivity, which was further processed to kerosene. The 50-kW solar reactor consisted of a cavity-receiver containing a reticulated porous structure directly exposed to a mean solar flux concentration of 2,500 suns. A solar-to-syngas energy conversion efficiency of 4.1% was achieved without applying heat recovery. This solar tower fuel plant was operated with a setup relevant to industrial implementation, setting a technological milestone toward the production of sustainable aviation fuels.

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