Construction of a 3D Metal-Organic Framework and Its Composite for Water Remediation via Selective Adsorption and Photocatalytic Degradation of Hazardous Dye

In this work, a new bimetallic Na(I)-Zn(II) metal- H2O)8]n (1) (H3btc = benzene tricarboxylic acid), and its composite (ZnO@1) have been successfully synthesized using solvothermal and mechanochemical solid grinding methods. 1 and ZnO@1 were characterized by diffraction [single-crystal X-ray diffraction (XRD) and powder XRD], spectroscopic (ultraviolet-visible diffuse reflectance spectroscopy and Fourier transform infrared spectroscopy), microscopic analysis) methods. The surface area and porosity of 1 were determined using a Brunauer-Emmett-Teller analyzer. Single-crystal diffraction of 1 confirms that Na1 and Zn2 have octahedral coordination environments, whereas Zn1 has a tetrahedral coordination geometry. Topological simplification of 1 shows a 3,6-connected kgd net. Na(I)-Zn(II) MOF (1) is crystallized with slight porosity and exhibits good tendency toward the encapsulation of zinc oxide nanoparticles (ZnO NPs). The photocatalytic behaviors of 1 and its composite (ZnO@1) were investigated over MB dye under sunlight illumination with promising degradation efficiencies of 93.69% for 1 and 97.53% for ZnO@1 in 80 min.

Automated summary

A new bimetallic Na(I)-Zn(II) metal-organic framework material and its composite have been successfully synthesized. The materials exhibit good porosity and a tendency towards the encapsulation of zinc oxide nanoparticles. They also show high photocatalytic degradation efficiency under sunlight illumination.