Development of stable porous silica-coated Ca(OH)2/γ-Al2O3 pellets for dehydration/hydration cycles with application in thermochemical heat storage

Thermochemical heat storage based on the CaO + H2O <-> Ca(OH)(2) system is extremely promising in CSP plants that can reach medium to high temperatures, such as those equipped with tower and heliostats. However, the attrition of pure CaO pellets is a major drawback that hampers an actual commercial development. This work proposes the dip-coating of mixed Ca(OH)(2)/gamma-Al2O3 spherical and cylindrical pellets with dense silica and Al-MCM-41 (mesoporous silica) gels. The original hardness of pure Ca(OH)(2) pellets (< 2 N) can be increased up to 31 N using 40 wt% alumina as binder and applying a silica coating. Both gels formed a hard calcium silicate layer upon calcination that helped keeping the structural integrity of the samples after dehydration/hydration cycles. The samples were tested in 10 consecutive cycles at dehydration and hydration temperatures of 600 degrees C and 250-425 degrees C, respectively. Cylindrical pieces displayed higher hardness values and hydration yields compared to the spherical counterparts. Interestingly, porous silica-coated cylindrical pellets achieved a remarkable hydration yield of 85% and presented a hardness value of 8 N after cycling. This was due to its porous nature and the composition of the coating, formed by thin sheets and small grains, which allowed preserving the outer porous structure of the pellet.

Automated summary

This study proposes a method of dip-coating mixed Ca(OH)(2)/gamma-Al2O3 pellets with silica and Al-MCM-41 gels to improve the hardness and structural integrity of pure Ca(OH)(2) pellets in the CaO + H2O <-> Ca(OH)(2) system. The results show that this method can increase the hardness of the pellets and preserve the structural integrity after dehydration/hydration cycles.