Determination of Cetane Number from Fatty Acid Compositions and Structures of Biodiesel

Biodiesel, which possesses the dominant advantages of low emissions and environmental friendliness, is a competitive alternative fuel to petroleum-derived diesel. The cetane number, which indicates ignition delay characteristics, is considered the most significant fuel property of biodiesel. Determining the cetane number for biodiesel by general testing equipment is time-consuming and costly; hence, a simple and convenient predictive formula for the cetane number of biodiesel is a significant task to be carried out. A reliable and convenient predictive method for determining the cetane number is proposed in this study. The key parameters for the cetane number of biodiesel were first screened out. The analysis of multiple linear regressions using the available software SPSS for statistical analysis was carried out to obtain the regression coefficients of those key parameters and intercepts to establish the predictive model. Other available experimental data verified the validity of the proposed predictive equation. The determination coefficient of the formula reaches as high as 94.7%, and the standard error is 3.486. The key parameters, including the number of carbon atoms (NC), allylic position equivalent (APE), and double-bond equivalent (DBE), were more significant for influencing the cetane number of biodiesel. In addition, the increase of NC or the decrease of either APE or DBE results in the increase of the cetane number. Moreover, the present formula is found to obtain closer cetane numbers to those experimental data and features superior prediction capability.

Automated summary

This study proposed a reliable and convenient predictive method for determining the cetane number of biodiesel. Key parameters were screened out and a predictive model was established using multiple linear regressions. Experimental data verified the validity of the proposed predictive equation, with key parameters including the number of carbon atoms (NC), allylic position equivalent (APE), and double-bond equivalent (DBE) showing significant influence on the cetane number.