4.8 Review

When MOFs meet wood: From opportunities toward applications

期刊

CHEM
卷 8, 期 9, 页码 2342-2361

出版社

CELL PRESS
DOI: 10.1016/j.chempr.2022.06.016

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资金

  1. National Natural Science Foundation of China [51903123]
  2. Natural Science Foundation of Jiangsu Province [BK20190760]
  3. China Scholarship Council
  4. University of Go?
  5. Zhejiang Provincial Natural Science Founda- tion of China [LQ22E030016]

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Metal-organic frameworks (MOFs) have attracted widespread attention due to their structural diversity and multifunctionality, but their further practical applications are limited by their powdered crystalline state. However, compounding MOFs with self-supporting porous materials with good processibility can effectively stabilize the powdered MOFs. Wood, with its natural multidimensional channel structure and excellent mechanical stability, is highly compatible with MOFs. MOF particles can be uniformly loaded onto the wood channel through physical adsorption, hydrogen bonding, or reaction with hydroxyl and carboxyl groups in the fibers. Ultimately, synthesis of MOF@wood composites with new functions shows great potential in interdisciplinary research.
Metal-organic frameworks (MOFs) have drawn widespread atten-tion owing to their structural diversity and multifunctionality. How-ever, further practical applications of MOFs are limited by their powdered crystalline state. Compounding with self-supporting porous materials with good processibility can effectively fix the powdered MOFs. Wood is highly compatible with MOFs because of its natural multidimensional channel structure and excellent me-chanical stability. MOF particles can be uniformly loaded onto the wood channel via physical adsorption, hydrogen bonding, or react-ing with hydroxyl and carboxyl groups in the fibers. Ultimately, MOF@wood composites with new functions are synthesized, showing great potential in the direction of interdisciplinary research. This review summarizes the fabrication strategies and functional applications of representative MOF@wood composites and discusses their development prospects and potential advan-tages. In conclusion, it is expected to provide systematic research ideas for the future development of MOF@wood composites.

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