4.4 Article

Selenylation of Guar Gum Mediated by N-Methyl-2-pyrrolidone Hydrosulfate: Insights into Regulation of Selenium Content and Molecular Weight

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CHEMISTRYSELECT
卷 7, 期 27, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.202201325

关键词

acidic ionic liquid; guar gum; homogeneous catalysis; selenized polysaccharide

资金

  1. Science Fund for Distinguished Young Scholars of Gansu Province [17JR5RA067]
  2. Gansu Education Department (CN) [2020C-21]
  3. Gansu Science and Technology Department (CN) [2019ZX-05]

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Selenylation is an important modification strategy for polysaccharides, and the use of [HNMP]HSO4 as an acid catalyst has been shown to efficiently synthesize Se-GGs with increased selenium content and molecular weight. The selenite groups were found to be located at the C6 position in Se-GGs. The results demonstrate a new synthetic method for preparing functional polysaccharides with a wide range of potential applications.
Selenylation is an important modification strategy of polysaccharide, however, one of the main obstacles is that the weak esterification ability of selenide reagent, which leads to the low Se conversion efficiency during reaction. Here, we used N-methyl-2-pyrrolidone hydrosulfate ([HNMP]HSO4) as acid catalyst efficiently synthesized selenized guar gum (Se-GGs) to improve the activity of selenide reagent. The chemical structure of GG and selenized derivatives was investigated using FT-IR, 1D/2D NMR spectrometry and atomic force microscopy (AFM). The results indicated that selenite groups existed in Se-GGs and the substitution position was at C6. Furthermore, it was also demonstrated that [HNMP]HSO4 had a dual influence on GG by increasing the Se content (from 181.3 to 9072.8 mu g/g) and regulating the molecular weight, which was due to strong Bronsted acidic proton (H+). These results illustrated a new synthetic method for preparing functional polysaccharides with a broad range of potential applications.

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