Synthesis and Properties of Bio-Based Composites from Vegetable Oils and Starch

Natural polymers, such as starch, and polymers derived from renewable resources, such as vegetable oils, have been considered as alternatives to petroleum-based plastics during recent decades, due to environmental concerns. Indeed, these materials can offer a variety of advantages, such as low cost, wide availability, carbon neutrality, elevated thermal stability, and easily tunable mechanical properties. However, some of these polymers alone exhibit poor mechanical properties, making them not suitable for some applications. Hence, the reinforcement of these bio-based polymers with other materials is often considered to overcome this challenge. In this work, thermosetting composites based on tung and linseed oil resins were prepared using starch as reinforcement. Analyses from Soxhlet extractions showed that the higher the concentration of tung oil in comparison to linseed oil in the resins, the lower the mass of unreacted material, leading to an optimum resin entirely based on tung oil. Dielectric analysis (DEA), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA) indicated that the polymerization was completed in 3 h 20 min, at 140 degrees C, and that the composites were thermally stable until 270 degrees C. Finally, dynamic mechanical analysis (DMA) confirmed that the addition of starch to the resins increased the room temperature storage modulus (E '(25)) from 94 MPa to 893 MPa. Composites prepared with a resin formulation that did not contain a compatibilizer exhibited E '(25) of 441 MPa. The composites investigated in this work are promising candidates for applications that require improved mechanical properties.

Automated summary

Natural and renewable polymers have been considered as alternatives to petroleum-based plastics due to environmental concerns. However, some of these polymers exhibit poor mechanical properties. In this study, composites based on tung and linseed oil resins were prepared using starch as reinforcement. The addition of starch increased the room temperature storage modulus of the composites.