期刊
JOURNAL OF ENVIRONMENTAL MANAGEMENT
卷 181, 期 -, 页码 237-248出版社
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jenvman.2016.06.027
关键词
Sugarcane vinasse; Anaerobic effluent biodegradability; Toxicity; Coagulation/flocculation; Fenton's reaction; Economic analysis
资金
- FEDER funds through Programa Operacional Competitividade e Internacionalizacao - COMPETE
- national funds through FCT - Fundacao para a Ciencia e a Tecnologia
- FEDER funds through Programa Operacional Factores de Competitividade - COMPETE
- Programa Operacional do Norte (ON2) program
- FEDER/ON2
- Ministry of Education - Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior - (CAPES) [PNPD-3137/2010]
- Ministry of Science and Technology - Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq) [483118/2011-7]
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP)
- [UID/EQU/00511/2013-LEPABE]
- [NORTE-07-0124-FEDER-000025 - RL2_ EnvironmentHealth]
The efficiency of individual and integrated processes applied to organic matter reduction and biodegradability improvement of a biodigested sugarcane vinasse wastewater was assessed. Strategies considered were Fenton's oxidation (Strategy 1), coagulation/flocculation (Strategy 2) and the combination of both processes (coagulation/flocculation followed by Fenton's reaction) - Strategy 3. It was found that Fenton's oxidation per se allowed reducing the organic matter, increasing the wastewater biodegradability and a non-toxic effluent was generated; however the cost of treatment was very high (86.6 R$/m(3) 21.2(sic)/m(3)). Under optimized conditions, coagulation/flocculation provided a slight increase in effluent's biodegradability, toxicity towards Vibrio fischeri was also eliminated and moderate removals of total organic carbon - TOC - (30.5%), biological oxygen demand - BOD5 - (27.9%) and chemical oxygen demand - COD - (43.6%) were achieved; however, the operating costs are much smaller. The use of dissolved iron resulting from coagulation/flocculation (270 mg/L) as catalyst in the second stage Fenton's oxidation was shown to be an innovative and economically attractive strategy. Under optimal conditions overall removals of 51.6% for TOC, 45.7% for BOD5 and 69.2% for COD were achieved, and a biodegradable (BOD5:COD ratio = 0.54) and non-toxic effluent was obtained. In order to increase the efficiency of the process but using less hydrogen peroxide, the Fenton's oxidation was performed by gradually adding the oxidant. This procedure allowed to obtain the highest organic matter removal efficiency (as compared with the addition of all hydrogen peroxide at the beginning of the reaction). This way it was possible to minimize the reagent consumption and, consequently, reduce the treatment cost. (C) 2016 Elsevier Ltd. All rights reserved.
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