Facile Synthesis of ZnO-CeO2 Heterojunction by Mixture Design and Its Application in Triclosan Degradation: Effect of Urea

In this study, simplex centroid mixture design was employed to determine the effect of urea on ZnO-CeO. The heterojunction materials were synthesized using a solid-state combustion method, and the physicochemical properties were evaluated using X-ray diffraction, nitrogen adsorption/desorption, and UV-Vis spectroscopy. Photocatalytic activity was determined by a triclosan degradation reaction under UV irradiation. According to the results, the crystal size of zinc oxide decreases in the presence of urea, whereas a reverse effect was observed for cerium oxide. A similar trend was observed for ternary samples, i.e., the higher the proportion of urea, the larger the crystallite cerium size. In brief, urea facilitated the co-existence of crystallites of CeO and ZnO. On the other hand, UV spectra indicate that urea shifts the absorption edge to a longer wavelength. Studies of the photocatalytic activity of TCS degradation show that the increase in the proportion of urea favorably influenced the percentage of mineralization.

Automated summary

In this study, the effect of urea on ZnO-CeO was investigated using a simplex centroid mixture design. The presence of urea was found to decrease the crystal size of zinc oxide and increase the crystal size of cerium oxide. Additionally, the increase in urea proportion was favorable for the percentage of mineralization in photocatalytic degradation.