期刊
CHEMELECTROCHEM
卷 9, 期 16, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.202200462
关键词
controllable synthesis; NiO; porous structure; supercapacitors; ultrathin nanosheets
资金
- Project of Science and Technology Department of Liaoning Province of China [2019-ZD-0509]
- Project of Education Department of Liaoning Province of China [LJKZ1010, LQ2019004]
- Key Research and Development Plan of Liaoning Science and Technology Department [2020JH2/10200007]
- Doctoral Start-up Foundation of Liaoning Province [2020-BS-237]
Precisely controlling the calcination temperature to adjust the porous architectures of ultrathin NiO nanosheets can significantly enhance the performance of supercapacitors.
The rational tailoring of micro- and mesoporous distribution for porous transition metal oxide-based nanomaterials is an important factor to control their electrochemistry performances. Herein, flower-like hierarchical microspheres assembled by ultrathin nickel oxide (NiO) nanosheets were synthesized by a facile solvothermal route and subsequent annealing process. Theoretical analysis and experimental results demonstrate that NiO ultrathin nanosheets prepared by calcination at 450 degrees C (N-450) have the optimal micro- and mesoporous distribution. The optimal microstructure provides plenty of ion transport channels and abundant active sites. As expected, the N-450 electrode delivers an ultrahigh specific capacity of 546.53 F g(-1) at a current density of 2 A g(-1), which is greater than other electrodes. Remarkably, the assembled N-450//AC asymmetric supercapacitor (ASC) achieves a high energy density of 29.7 Wh kg(-1) (at a power density of 800 W kg(-1)) and exhibits an excellent cycling stability. This work demonstrates an available avenue to enhance the performance of supercapacitor by accurately controlling calcination temperature to adjust the porous architectures of ultrathin NiO nanosheets.
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