Catalytic Performance of Bimetallic Systems (Cu-Fe, Cu-Mn, Fe-Mn) Based on Spherical MCM-41 Modified by Template Ion-Exchange in NH3-SCR Process

Mesoporous silica of MCM-41 type with spherical morphology was modified with copper, iron, or manganese as well as pairs of these metals by template ion-exchange (TIE) method. The obtained samples were characterized with respect to their structure (XRD), morphology (SEM-EDS), textural parameters (low-temperature N-2 sorption), surface acidity (NH3-TPD), transition metal loadings (ICP-OES), their deposited forms (UV-vis DRS) and reducibility (H-2-TPR). The catalytic performance of monometallic and bimetallic samples in the selective catalytic reduction of NO with ammonia (NH3-SCR) was tested. The best catalytic results presented a bimetallic copper-manganese sample, which was significantly more active than the mechanical mixture of monometallic copper and manganese catalysts. The synergistic cooperation of manganese and copper species is possibly related to charge relocation between them, resulting in activation of the catalyst in oxidation of NO to NO2, which is necessary for the fast NH3-SCR reaction.

Automated summary

Mesoporous silica material of MCM-41 type with spherical morphology was modified with copper, iron, or manganese as well as combinations of these metals. The modified samples were characterized for their structure, morphology, surface acidity, transition metal loadings, and reducibility. The catalytic performance of monometallic and bimetallic samples in the selective catalytic reduction of NO with ammonia was tested, and the bimetallic copper-manganese sample showed the best catalytic activity. The synergistic cooperation between manganese and copper species may be attributed to charge relocation, resulting in improved activation of the catalyst for the desired reaction.